FI114629B - Förfarande för framställning av syntesgas genom partiell oxidation av flytande kolvätehaltigt bränsle medelst en brännare med flera munstycken (koannulan) - Google Patents

Förfarande för framställning av syntesgas genom partiell oxidation av flytande kolvätehaltigt bränsle medelst en brännare med flera munstycken (koannulan) Download PDF

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Publication number
FI114629B
FI114629B FI964588A FI964588A FI114629B FI 114629 B FI114629 B FI 114629B FI 964588 A FI964588 A FI 964588A FI 964588 A FI964588 A FI 964588A FI 114629 B FI114629 B FI 114629B
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channel
gas
burner
fuel
oxidant
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FI964588A
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English (en)
Finnish (fi)
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FI964588A (sv
FI964588A0 (sv
Inventor
Johannes Hermanus Disselhorst
Frits Eulderink
Peter Oortwijn
Jacobus Antonius Jozef Smit
Hendrik Martinus Wentinck
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Shell Int Research
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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/36Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using oxygen or mixtures containing oxygen as gasifying agents
    • C01B3/363Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using oxygen or mixtures containing oxygen as gasifying agents characterised by the burner used
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/36Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using oxygen or mixtures containing oxygen as gasifying agents
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46Gasification of granular or pulverulent flues in suspension
    • C10J3/466Entrained flow processes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46Gasification of granular or pulverulent flues in suspension
    • C10J3/48Apparatus; Plants
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/025Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/84Energy production
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2200/00Details of gasification apparatus
    • C10J2200/15Details of feeding means
    • C10J2200/152Nozzles or lances for introducing gas, liquids or suspensions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953Gasifying agents
    • C10J2300/0959Oxygen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/12Heating the gasifier
    • C10J2300/1223Heating the gasifier by burners
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/18Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1846Partial oxidation, i.e. injection of air or oxygen only

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Claims (13)

1. Förfarande för framställning av syntesgas genom att läta en syrehaltig gas, som används som oxidator och 5 som härefter betecknas "X", en moderatorgas, som härefter betecknas "M", och ett flytande kolvätehaltigt bränsle, som härefter betecknas "F", reagera i reaktionszonen i en väsentligen icke-katalytisk gasgenerator, kännetecknat av att förfarandet omfattar injektion av nämnda bränsle 10 och nämnda oxidator i reaktionszonen via en (samringfor-mig) brännare med flera mynningar, vilken brännare omfattar en sammansättning med n separata passager eller kana-ler vilka är koaxiala med brännarens längdaxel, varvid n är ett heltal >3 (3, 4, 5...) och (n-1) :e kanalen är den 15 inre kanalen i förhällande tili den n:e kanalen mätt frän brännarens längdaxel och varvid F leds via en eller flera kanaler och minst 2 kanaler blir kvar, X leds via en eller flera av de kvarvarande kanalerna och minst 1 kanal blir kvar och M leds via en eller flera av de kvarvarande kana-20 lerna sä att vilka som heist tvä kanaler, genom vilka F respektive X leds, är ätskilda frän varandra av minst en * · ''** kanal genom vilken M leds.
2. Förfarande enligt patentkrav 1, kännetecknat t av att det flytande kolvätehaltiga bränslets viskositet är I1 25 inom omrädet 1 - 1000 cSt.
’.· 3. Förfarande enligt patentkrav 1 eller 2, kän- netecknat av att det flytande kolvätehaltiga bränslet leds med en eller flera hastigheter inom omrädet 2 - 40 m/s. !f 30
4. Förfarande enligt nägot av patentkraven 1-3, :kännetecknat av att den syrehaltiga gasen (oxidatorn) , · leds med en eller flera hastigheter inom omrädet 20 - 140 m/s.
5. Förfarande enligt nägot av patentkraven 1-4, 35 kännetecknat av att moderatorgasen leds med en eller i flera hastigheter inom omrädet 5 - 140 m/s. 114629 12
6. Förfarande enligt nägot av patentkraven 1-5, kännetecknat av att processens absoluta tryck är 0,1 - 12 Mpa.
7. Förfarande enligt nägot av patentkraven 1-6, 5 kännetecknat av att nämnda bränsle är en oljerest.
8. Förfarande enligt nägot av patentkraven 1-7, kännetecknat av att den syrehaltiga gasen (oxidatorn) innehäller minst 90 % rent syre.
9. Förfarande enligt nägot av patentkraven 1-8, 10 kännetecknat av att de respektive hastigheterna upp- mäts eller beräknas vid utgängen för de respektive kon-centriska kanalerna tili begasningszonen.
10. Förfarande enligt nägot av patentkraven 1-9, kännetecknat av att moderatorgasen är vattenänga, vat- 15 ten, koldioxid eller en kombination därav.
11. Förfarande enligt nägot av patentkraven 1 - 10, kännetecknat av att antingen X eller M leds genom den yttersta kanalen.
12. Förfarande enligt nägot av patentkraven 20 1-11, kännetecknat av att n är minst 4, varvid M leds genom den yttersta kanalen.
13. Förfarande enligt nägot av patentkraven 1 - 11, kännetecknat av att n är minst 4, varvid X el- • ler M leds genom den innersta kanalen. 1 » »
FI964588A 1994-05-19 1996-11-15 Förfarande för framställning av syntesgas genom partiell oxidation av flytande kolvätehaltigt bränsle medelst en brännare med flera munstycken (koannulan) FI114629B (sv)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
EP94201428 1994-05-19
EP94201428 1994-05-19
PCT/EP1995/001891 WO1995032148A1 (en) 1994-05-19 1995-05-16 A process for the manufacture of synthesis gas by partial oxidation of a liquid hydrocarbon-containing fuel using a multi-orifice (co-annular) burner
EP9501891 1995-05-16

Publications (3)

Publication Number Publication Date
FI964588A FI964588A (sv) 1996-11-15
FI964588A0 FI964588A0 (sv) 1996-11-15
FI114629B true FI114629B (sv) 2004-11-30

Family

ID=8216891

Family Applications (1)

Application Number Title Priority Date Filing Date
FI964588A FI114629B (sv) 1994-05-19 1996-11-15 Förfarande för framställning av syntesgas genom partiell oxidation av flytande kolvätehaltigt bränsle medelst en brännare med flera munstycken (koannulan)

Country Status (14)

Country Link
EP (1) EP0759886B1 (sv)
KR (1) KR100374753B1 (sv)
CN (1) CN1043028C (sv)
AU (1) AU692262B2 (sv)
BR (1) BR9507652A (sv)
CA (1) CA2190514C (sv)
DE (1) DE69503781T2 (sv)
DK (1) DK0759886T3 (sv)
ES (1) ES2120207T3 (sv)
FI (1) FI114629B (sv)
MY (1) MY114520A (sv)
NO (1) NO315267B1 (sv)
WO (1) WO1995032148A1 (sv)
ZA (1) ZA954001B (sv)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101027378B (zh) 2004-10-08 2011-01-19 国际壳牌研究有限公司 由费-托合成产物制备低级烯烃的方法
BRPI0712890A2 (pt) 2006-07-14 2012-10-09 Shell Int Research processo para preparar uma mistura de hidrogênio e monóxido de carbono
US20080190026A1 (en) * 2006-12-01 2008-08-14 De Jong Johannes Cornelis Process to prepare a mixture of hydrogen and carbon monoxide from a liquid hydrocarbon feedstock containing a certain amount of ash
US8052864B2 (en) 2006-12-01 2011-11-08 Shell Oil Company Process to prepare a sweet crude
US9051522B2 (en) 2006-12-01 2015-06-09 Shell Oil Company Gasification reactor
US8475546B2 (en) 2008-12-04 2013-07-02 Shell Oil Company Reactor for preparing syngas
US8960651B2 (en) 2008-12-04 2015-02-24 Shell Oil Company Vessel for cooling syngas
DE102010004787B4 (de) 2010-01-16 2014-02-13 Lurgi Gmbh Verfahren und Brenner zur Herstellung von Synthesegas
US10066832B2 (en) 2010-10-01 2018-09-04 Air Products And Chemicals, Inc. Burner for the gasification of a solid fuel
CN104254489B (zh) * 2011-10-18 2017-09-15 国际壳牌研究有限公司 合成气的生产
CN105555921B (zh) 2013-09-18 2018-05-22 国际壳牌研究有限公司 向加氢催化反应供应氢的方法和系统
KR102093052B1 (ko) 2015-12-16 2020-03-25 에어 프로덕츠 앤드 케미칼스, 인코오포레이티드 가스화 시스템 및 가스화 방법
US10760017B2 (en) 2015-12-16 2020-09-01 Air Products & Chemicals, Inc. Gasification system and process
CN110114446B (zh) 2016-12-14 2022-04-26 气体产品与化学公司 在合成气生产中控制烟灰制造物的方法和系统
DE202018101400U1 (de) 2017-05-11 2018-04-12 L'Air Liquide Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Brenner zur Synthesegaserzeugung

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CA1218903A (en) * 1982-10-19 1987-03-10 Ian Poll Process and burner for the partial combustion of solid fuel
GB2151348B (en) * 1983-12-09 1986-08-06 Shell Int Research Burner and process for producing synthesis gas from hydrocarbon fuel
GB8711156D0 (en) * 1987-05-12 1987-06-17 Shell Int Research Partial oxidation of hydrocarbon-containing fuel
US4888031A (en) * 1988-05-26 1989-12-19 Shell Oil Company Process for partial oxidation of a liquid or solid and/or a gaseous hydrocarbon-containing fuel
DE4140063A1 (de) * 1991-12-05 1993-06-09 Hoechst Ag, 6230 Frankfurt, De Brenner zur herstellung von synthesegas

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Publication number Publication date
AU692262B2 (en) 1998-06-04
BR9507652A (pt) 1997-09-09
DE69503781D1 (de) 1998-09-03
ES2120207T3 (es) 1998-10-16
WO1995032148A1 (en) 1995-11-30
NO964860L (no) 1996-11-15
FI964588A (sv) 1996-11-15
MY114520A (en) 2002-11-30
JPH10500388A (ja) 1998-01-13
FI964588A0 (sv) 1996-11-15
CN1043028C (zh) 1999-04-21
CN1148841A (zh) 1997-04-30
DK0759886T3 (da) 1999-05-03
CA2190514C (en) 2007-04-03
NO964860D0 (no) 1996-11-15
DE69503781T2 (de) 1999-02-11
NO315267B1 (no) 2003-08-11
KR970703274A (ko) 1997-07-03
AU2565695A (en) 1995-12-18
ZA954001B (en) 1996-01-17
EP0759886B1 (en) 1998-07-29
CA2190514A1 (en) 1995-11-30
JP3863916B2 (ja) 2006-12-27
EP0759886A1 (en) 1997-03-05
KR100374753B1 (ko) 2003-06-09

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