ES8801893A1 - Phenylene mixed diester peracid precursors. - Google Patents

Phenylene mixed diester peracid precursors.

Info

Publication number
ES8801893A1
ES8801893A1 ES550880A ES550880A ES8801893A1 ES 8801893 A1 ES8801893 A1 ES 8801893A1 ES 550880 A ES550880 A ES 550880A ES 550880 A ES550880 A ES 550880A ES 8801893 A1 ES8801893 A1 ES 8801893A1
Authority
ES
Spain
Prior art keywords
carbon atoms
alkyl
mixed
peracid precursors
diester
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES550880A
Other languages
Spanish (es)
Other versions
ES550880A0 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Clorox Co
Original Assignee
Clorox Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Clorox Co filed Critical Clorox Co
Publication of ES550880A0 publication Critical patent/ES550880A0/en
Publication of ES8801893A1 publication Critical patent/ES8801893A1/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905—Bleach activators or bleach catalysts
    • C11D3/3907—Organic compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The invention provides novel peracid precursors representative of which is the structure: <CHEM contiene="yes"> wherein R<1> is alkyl of 1 to 20 carbon atoms R<2> is OH, -O-R<3>, or -O-@-R<4> and X<1>, X<2>, Y and Z are individually selected from H, SO3, CO2, NO2, NR5_4 halogen, R<6> and mixtures thereof: wherein R<3> of-O-R<3> is alkyl of 1 to 20 carbon atoms R<4> of -O-@-R<4> is alkyl of 1 to 20 carbon atoms R<5> of NR5_4<+> is selected from H, alkyl of 1 to 24 carbon atoms and mixtures thereof and R<6> is alkyl of 1 to 20 carbon atoms. In one embodiment of the invention, the novel peracid precursors are combined with a source of hydrogen peroxide and sufficient quantities of buffer to impart an alkaline pH when the composition is placed in aqueous solution. Preferred embodiments of the invention include wherein R<2> is hydroxy, and R<1> is alkyl of 1 to 20 carbon atoms (monoester) and wherein R<2> is -O-@-R<4>, and R<1> and R<4> are alkyls of 1 to 20 carbon atoms (diester) and may be either symmetrical (i.e., R<1>=R<4>) or mixed (i.e., R<1> NOTEQUAL R<4>). The mixed diester embodiment appears to provide benefits of mixed hydrophobic-hydrophilic peracid generation to oxidize both hydrophobic and hydrophilic soils. Various detergent adjuncts known to those skilled in the art may be added, such as surfactants, builders, fragrances, antimicrobial compounds and the like.
ES550880A 1984-12-14 1985-12-13 Phenylene mixed diester peracid precursors. Expired ES8801893A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US68198384A 1984-12-14 1984-12-14

Publications (2)

Publication Number Publication Date
ES550880A0 ES550880A0 (en) 1988-03-01
ES8801893A1 true ES8801893A1 (en) 1988-03-01

Family

ID=24737696

Family Applications (2)

Application Number Title Priority Date Filing Date
ES550880A Expired ES8801893A1 (en) 1984-12-14 1985-12-13 Phenylene mixed diester peracid precursors.
ES557775A Expired ES8802581A1 (en) 1984-12-14 1987-10-16 Phenylene mixed diester peracid precursors.

Family Applications After (1)

Application Number Title Priority Date Filing Date
ES557775A Expired ES8802581A1 (en) 1984-12-14 1987-10-16 Phenylene mixed diester peracid precursors.

Country Status (5)

Country Link
EP (1) EP0185522B1 (en)
CA (1) CA1270717A (en)
DE (1) DE3580460D1 (en)
ES (2) ES8801893A1 (en)
TR (1) TR22733A (en)

Families Citing this family (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4814110A (en) * 1984-12-14 1989-03-21 The Clorox Company Method for esterifying dihydroxybenzenes
US5364554A (en) * 1986-06-09 1994-11-15 The Clorox Company Proteolytic perhydrolysis system and method of use for bleaching
US5296161A (en) 1986-06-09 1994-03-22 The Clorox Company Enzymatic perhydrolysis system and method of use for bleaching
US4790952A (en) * 1986-08-14 1988-12-13 The Clorox Company Alkyl monoperoxysuccinic acid precursors and method of synthesis
FI874163A (en) * 1986-09-26 1988-03-27 Mitsui Toatsu Chemicals KATEKOLDERIVAT SAMT PREPARAT INNEHAOLLANDE DESAMMA FOER HAEMMANDE OCH BOTANDE AV REGRESSIVA SJUKDOMAR I DET CENTRALA NERVSYSTEMET.
US5214034A (en) * 1986-09-26 1993-05-25 Mitsui Toatsu Chemicals, Incorporated Catechol derivatives, and preventive and remedial preparations for regressive disorders in the central nervous system containing the same
US4818426A (en) * 1987-03-17 1989-04-04 Lever Brothers Company Quaternary ammonium or phosphonium substituted peroxy carbonic acid precursors and their use in detergent bleach compositions
US4751015A (en) * 1987-03-17 1988-06-14 Lever Brothers Company Quaternary ammonium or phosphonium substituted peroxy carbonic acid precursors and their use in detergent bleach compositions
US5234616A (en) * 1987-10-30 1993-08-10 The Clorox Company Method of laundering clothes using a delayed onset active oxygen bleach composition
US5130045A (en) * 1987-10-30 1992-07-14 The Clorox Company Delayed onset active oxygen bleach composition
EP0333248A3 (en) * 1988-03-17 1990-08-29 Unilever N.V. Bleach precursors and their use in bleaching and/or detergent composition
GB8815841D0 (en) * 1988-07-04 1988-08-10 Unilever Plc Bleaching detergent compositions
US5290793A (en) * 1989-09-12 1994-03-01 Mitsui Toatsu Chemicals, Incorporated Dihydrocaffeic acid derivatives and pharmaceutical preparation containing same
US5078907A (en) * 1989-11-01 1992-01-07 Lever Brothers Company, Division Of Conopco, Inc. Unsymmetrical dicarboxylic esters as bleach precursors
US5688757A (en) * 1990-01-22 1997-11-18 Novo Nordisk A/S The Procter & Gamble Co. Sugar derivatives containing both long and short chain acyl groups as bleach activators
GB9003741D0 (en) * 1990-02-19 1990-04-18 Unilever Plc Bleach activation
JP3099455B2 (en) * 1990-10-08 2000-10-16 住友化学工業株式会社 Aromatic polyester and method for producing the same
WO1992006064A1 (en) * 1990-10-08 1992-04-16 Sumitomo Chemical Company, Limited Process for producing highly pure phenyl carboxylate
US5055217A (en) * 1990-11-20 1991-10-08 Lever Brothers Company, Division Of Conopco, Inc. Polymer protected bleach precursors
SK278833B6 (en) * 1992-01-17 1998-03-04 Unilever Nv Detergent whitening mixture containing particles
SK278834B6 (en) * 1992-01-17 1998-03-04 Unilever Nv Detergent whitening mixture containing particles
DE19600159A1 (en) 1996-01-04 1997-07-10 Hoechst Ag Bleaching agent systems containing bis- and tris (mu-oxo) -di-manganese complex salts
DE19606343A1 (en) 1996-02-21 1997-08-28 Hoechst Ag Bleach
US5850086A (en) * 1996-06-21 1998-12-15 Regents Of The University Of Minnesota Iron complexes for bleach activation and stereospecific oxidation
EP0937772A1 (en) * 1998-02-23 1999-08-25 The Procter & Gamble Company Bleaching compositions
GB0011527D0 (en) 2000-05-12 2000-06-28 Unilever Plc Bleach catalyst and composition and method for bleaching a substrate
JP5795254B2 (en) 2008-04-09 2015-10-14 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ Use of metal hydrazide complex compounds as oxidation catalysts
MX2012015285A (en) 2010-06-28 2013-02-07 Basf Se Metal free bleaching composition.
US9051285B2 (en) 2010-12-13 2015-06-09 Basf Se Bleach catalysts
CN105473700B (en) 2013-06-20 2021-11-02 切姆森蒂有限公司 Bleaching and oxidation catalyst
EP3033409B1 (en) 2013-08-16 2021-09-22 Catexel Technologies Limited Composition
WO2017076771A1 (en) 2015-11-03 2017-05-11 Basf Se Bleach catalysts
EP3176157A1 (en) 2015-12-01 2017-06-07 Basf Se Bleach catalysts
WO2017182295A1 (en) 2016-04-18 2017-10-26 Basf Se Liquid cleaning compositions
WO2017186480A1 (en) 2016-04-26 2017-11-02 Basf Se Metal free bleaching composition
EP3372663A1 (en) 2017-03-10 2018-09-12 Basf Se Bleach catalysts
EP4110831B1 (en) 2020-02-28 2024-02-21 Catexel Technologies Limited Degradative method
EP3967742A1 (en) 2020-09-15 2022-03-16 WeylChem Performance Products GmbH Compositions comprising bleaching catalyst, manufacturing process thereof, and bleaching and cleaning agent comprising same
EP4008765A1 (en) 2020-12-07 2022-06-08 WeylChem Performance Products GmbH Compositions comprising protonated triazacyclic compounds and bleaching agent and cleaning agent comprising same
EP4296343A1 (en) 2022-06-24 2023-12-27 WeylChem Performance Products GmbH Compositions comprising protonated triazacyclic compounds and manganese(ii) acetate, manufacturing thereof, and bleaching and cleaning agent comprising same

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1375960A (en) * 1963-09-16 1964-10-23 Geigy Ag J R Stabilization of organic matter, in particular polypropylene, by means of certain alkanoic derivatives, in particular hydroquinone esters
US3462468A (en) * 1964-10-22 1969-08-19 Celanese Corp Resorcinol esters of alpha,alpha-dimethyl aliphatic acids
DE2038522A1 (en) * 1969-08-04 1971-02-18 Geigy Ag J R Esters of fatty acids and tertiary-lower-alkyl-substituted hydroquinones and their use for stabilizing fat compositions
US3624135A (en) * 1970-02-27 1971-11-30 Texaco Inc Preparation of benzene diacetates
US3624136A (en) * 1970-02-27 1971-11-30 Texaco Inc Method of preparing catechol diacetates
GB1316739A (en) * 1971-10-20 1973-05-16 Texaco Development Corp Preparation of acetates of monohydric and dihydric phenols
US3969383A (en) * 1974-01-07 1976-07-13 Ciba-Geigy Corporation Fat compositions stabilized with esters of fatty acids and tertiary lower alkyl substituted hydroquinones and method therefrom
US4036773A (en) * 1974-12-27 1977-07-19 Mobil Oil Corporation Lubricant compositions containing carboxylic acid esters of hindered hydroquinones
CA1175058A (en) * 1980-04-07 1984-09-25 James E. Lyons Selective production of phenylene diacetate
JPS57145803A (en) * 1981-03-05 1982-09-09 Sunstar Inc External decoloring agent for skin
DE3266352D1 (en) * 1981-06-22 1985-10-24 Procter & Gamble Mixed peroxyacid bleaches having improved bleaching power
US4412934A (en) * 1982-06-30 1983-11-01 The Procter & Gamble Company Bleaching compositions

Also Published As

Publication number Publication date
ES8802581A1 (en) 1988-09-01
TR22733A (en) 1988-05-24
EP0185522A2 (en) 1986-06-25
DE3580460D1 (en) 1990-12-13
ES550880A0 (en) 1988-03-01
EP0185522B1 (en) 1990-11-07
CA1270717A (en) 1990-06-26
EP0185522A3 (en) 1987-07-01
ES557775A0 (en) 1988-09-01

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Legal Events

Date Code Title Description
FD1A Patent lapsed

Effective date: 19970401