ES8601873A1 - Un metodo de preparar un haluro de lactama-magnesio - Google Patents
Un metodo de preparar un haluro de lactama-magnesioInfo
- Publication number
- ES8601873A1 ES8601873A1 ES528705A ES528705A ES8601873A1 ES 8601873 A1 ES8601873 A1 ES 8601873A1 ES 528705 A ES528705 A ES 528705A ES 528705 A ES528705 A ES 528705A ES 8601873 A1 ES8601873 A1 ES 8601873A1
- Authority
- ES
- Spain
- Prior art keywords
- lactam
- hydrocarbon
- halide
- magnesium
- tetrahydrofuran
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 lactam magnesium halides Chemical class 0.000 title abstract 8
- 229910052749 magnesium Inorganic materials 0.000 title abstract 7
- 239000011777 magnesium Substances 0.000 title abstract 7
- 238000004519 manufacturing process Methods 0.000 title 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 abstract 10
- 239000004215 Carbon black (E152) Substances 0.000 abstract 5
- 229930195733 hydrocarbon Natural products 0.000 abstract 5
- 150000003951 lactams Chemical class 0.000 abstract 5
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 abstract 4
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 abstract 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 3
- 150000004292 cyclic ethers Chemical class 0.000 abstract 3
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 3
- 238000000034 method Methods 0.000 abstract 3
- 239000002904 solvent Substances 0.000 abstract 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 2
- 239000004677 Nylon Substances 0.000 abstract 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical group O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 abstract 2
- 150000004820 halides Chemical class 0.000 abstract 2
- 150000002430 hydrocarbons Chemical class 0.000 abstract 2
- 229920001778 nylon Polymers 0.000 abstract 2
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 125000000129 anionic group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 229920001400 block copolymer Polymers 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D201/00—Preparation, separation, purification or stabilisation of unsubstituted lactams
- C07D201/14—Preparation of salts or adducts of lactams
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/003—Compounds containing elements of Groups 2 or 12 of the Periodic Table without C-Metal linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Polyamides (AREA)
- Cephalosporin Compounds (AREA)
- Hydrogenated Pyridines (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
METODO DE PREPARAR UN HALURO DE LACTAMA-MAGNESIO. COMPRENDE: A) HACER REACCIONAR, A UNA TEMPERATURA INFERIOR A LA DE EBULLICION DEL HALURO, MAGNESIO, UN HALURO HIDROCARBONADO, ELEGIDO ENTRE HALUROS ALIFATICOS, DIHALUROS ALIFATICOS, POLIHALUROS ALIFATICOS, HALUROS, DIHALUROS Y POLIHALUROS AROMATICOS, Y EL HALURO ES BROMURO O CLORURO, UNA LACTAMA, COMO CAPROLACTAMA, Y UN DISOLVENTE DE ETER CICLICO, COMO TETRAHIDROFURANO; Y B) SEPARAR EL ETER CICLICO Y EL RESIDUO DE HIDROCARBURO MEDIANTE DESTILACION O EVAPORACION. SIENDO 1 LA RELACION MOLAR ENTRE EL HALURO HIDROCARBONADO Y EL MAGNESIO Y DE LACTAMA Y MAGNESIO; Y SIENDO SUFICIENTE LA CANTIDAD DE ETER PARA MANTENER EL HALURO DE LACTAMA-MAGNESIO PRODUCIDO EN SOLUCION A LA TEMPERATURA DE REACCION. SE UTILIZA COMO CATALIZADOR ANIONICO PARA LA POLIMERIZACION DEL NILON O DE COPOLIMERO EN BLOQUE DE NILON.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/456,702 US4438034A (en) | 1983-01-10 | 1983-01-10 | Process for preparing lactam magnesium halides |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES528705A0 ES528705A0 (es) | 1985-11-16 |
| ES8601873A1 true ES8601873A1 (es) | 1985-11-16 |
Family
ID=23813815
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES528705A Expired ES8601873A1 (es) | 1983-01-10 | 1984-01-05 | Un metodo de preparar un haluro de lactama-magnesio |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US4438034A (es) |
| EP (1) | EP0116527B1 (es) |
| JP (1) | JPS59130892A (es) |
| AT (1) | ATE42953T1 (es) |
| AU (1) | AU555614B2 (es) |
| BR (1) | BR8400073A (es) |
| CA (1) | CA1215049A (es) |
| DD (1) | DD211551A5 (es) |
| DE (1) | DE3478112D1 (es) |
| DK (1) | DK7884A (es) |
| EG (1) | EG17034A (es) |
| ES (1) | ES8601873A1 (es) |
| GR (1) | GR79471B (es) |
| MX (1) | MX158645A (es) |
| PT (1) | PT77933B (es) |
| ZA (1) | ZA84171B (es) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4508646A (en) * | 1984-01-30 | 1985-04-02 | Ppg Industries, Inc. | Process for the preparation of a catalyst useful for anionic lactam polymerization |
| US4683344A (en) * | 1984-01-30 | 1987-07-28 | Ppg Industries, Inc. | Process for the preparation of an organomagnesium compound |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3018273A (en) * | 1958-04-21 | 1962-01-23 | Monsanto Chemicals | Process of polymerizing higher lactams |
| US3451963A (en) * | 1965-11-15 | 1969-06-24 | Monsanto Co | Polymerization of lactams |
| IL28220A (en) * | 1966-07-14 | 1971-12-29 | Monsanto Co | Anionic lactam catalyst system |
| RO70742A (ro) * | 1974-12-18 | 1981-08-17 | Borsodi Vegyi Kombinat,Hu | Procedeu pentru obtinerea de halogenuri de lactam-magneziu |
-
1983
- 1983-01-10 US US06/456,702 patent/US4438034A/en not_active Expired - Fee Related
-
1984
- 1984-01-05 ES ES528705A patent/ES8601873A1/es not_active Expired
- 1984-01-06 EP EP84870003A patent/EP0116527B1/en not_active Expired
- 1984-01-06 AT AT84870003T patent/ATE42953T1/de not_active IP Right Cessation
- 1984-01-06 DE DE8484870003T patent/DE3478112D1/de not_active Expired
- 1984-01-09 ZA ZA84171A patent/ZA84171B/xx unknown
- 1984-01-09 DD DD84259292A patent/DD211551A5/de unknown
- 1984-01-09 BR BR8400073A patent/BR8400073A/pt unknown
- 1984-01-09 JP JP59000925A patent/JPS59130892A/ja active Granted
- 1984-01-09 GR GR73454A patent/GR79471B/el unknown
- 1984-01-09 PT PT77933A patent/PT77933B/pt unknown
- 1984-01-09 CA CA000444894A patent/CA1215049A/en not_active Expired
- 1984-01-09 DK DK7884A patent/DK7884A/da not_active Application Discontinuation
- 1984-01-09 MX MX199989A patent/MX158645A/es unknown
- 1984-01-09 EG EG15/84A patent/EG17034A/xx active
- 1984-01-09 AU AU23156/84A patent/AU555614B2/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| MX158645A (es) | 1989-02-21 |
| PT77933B (en) | 1986-04-16 |
| DK7884A (da) | 1984-07-11 |
| EP0116527A2 (en) | 1984-08-22 |
| EG17034A (en) | 1990-08-30 |
| PT77933A (en) | 1984-02-01 |
| JPH0533232B2 (es) | 1993-05-19 |
| ES528705A0 (es) | 1985-11-16 |
| CA1215049A (en) | 1986-12-09 |
| JPS59130892A (ja) | 1984-07-27 |
| DE3478112D1 (en) | 1989-06-15 |
| ZA84171B (en) | 1984-08-29 |
| EP0116527A3 (en) | 1986-01-22 |
| GR79471B (es) | 1984-10-30 |
| US4438034A (en) | 1984-03-20 |
| ATE42953T1 (de) | 1989-05-15 |
| DK7884D0 (da) | 1984-01-09 |
| AU555614B2 (en) | 1986-10-02 |
| EP0116527B1 (en) | 1989-05-10 |
| BR8400073A (pt) | 1984-08-14 |
| AU2315684A (en) | 1984-07-12 |
| DD211551A5 (de) | 1984-07-18 |
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