ES8501419A1 - Increasing polymerisation of acrylic nitrile, amide, or acid - Google Patents
Increasing polymerisation of acrylic nitrile, amide, or acidInfo
- Publication number
- ES8501419A1 ES8501419A1 ES522332A ES522332A ES8501419A1 ES 8501419 A1 ES8501419 A1 ES 8501419A1 ES 522332 A ES522332 A ES 522332A ES 522332 A ES522332 A ES 522332A ES 8501419 A1 ES8501419 A1 ES 8501419A1
- Authority
- ES
- Spain
- Prior art keywords
- compsn
- cpd
- acrylamide
- acrylonitrile
- acrylic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Landscapes
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
EP--65078 A Compsn. comprises (a) acrylonitrile, acrylamide and/or acrylic acid and (b) a borane cpd. contg. at least one -B-H gp. and consisting of borohydrides and complexes of B hydrides. When (a) is acrylamide and/or acrylic acid and contains a sufficient quantity of a metallic ion or cpd. to form an initiator system in the presence of (b), the amt. of inhibitor is increased to prevent premature polymerisation of the compsn. When (a) is free of metallic ion or cpd., (a) is present as a 5-20 wt.% soln. in water and is free of added inhibitor. - The compsn. provides an inexpensive and convenient method for improving the polymerisability of poorly polymerisable (a). Acrolein content of acrylonitrile is greatly reduced. Water soluble polymers having higher mol. wts. and reduced insolubles can be produced. EPAB- EP--65078 B Compsn. comprises (a) acrylonitrile, acrylamide and/or acrylic acid and (b) a borane cpd. contg. at least one -B-H gp. and consisting of borohydrides and complexes of B hydrides. When (a) is acrylamide and/or acrylic acid and contains a sufficient quantity of a metallic ion or cpd. to form an initiator system in the presence of (b), the amt. of inhibitor is increased to prevent premature polymerisation of the compsn. When (a) is free of metallic ion or cpd., (a) is present as a 5-20 wt.% soln. in water and is free of added inhibitor. - The compsn. provides an inexpensive and convenient method for improving the polymerisability of poorly polymerisable (a). Acrolein content of acrylonitrile is greatly reduced. Water soluble polymers having higher mol. wts. and reduced insolubles can be produced. (37pp)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ES522332A ES8501419A1 (en) | 1983-05-12 | 1983-05-12 | Increasing polymerisation of acrylic nitrile, amide, or acid |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ES522332A ES8501419A1 (en) | 1983-05-12 | 1983-05-12 | Increasing polymerisation of acrylic nitrile, amide, or acid |
Publications (2)
Publication Number | Publication Date |
---|---|
ES522332A0 ES522332A0 (en) | 1984-12-16 |
ES8501419A1 true ES8501419A1 (en) | 1984-12-16 |
Family
ID=8485712
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES522332A Expired ES8501419A1 (en) | 1983-05-12 | 1983-05-12 | Increasing polymerisation of acrylic nitrile, amide, or acid |
Country Status (1)
Country | Link |
---|---|
ES (1) | ES8501419A1 (en) |
-
1983
- 1983-05-12 ES ES522332A patent/ES8501419A1/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
ES522332A0 (en) | 1984-12-16 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FD1A | Patent lapsed |
Effective date: 20001009 |