ES8106741A1 - Cleavage of ethylene ester copolymers - Google Patents
Cleavage of ethylene ester copolymersInfo
- Publication number
- ES8106741A1 ES8106741A1 ES494985A ES494985A ES8106741A1 ES 8106741 A1 ES8106741 A1 ES 8106741A1 ES 494985 A ES494985 A ES 494985A ES 494985 A ES494985 A ES 494985A ES 8106741 A1 ES8106741 A1 ES 8106741A1
- Authority
- ES
- Spain
- Prior art keywords
- cleavage
- ester copolymers
- ethylene ester
- ester
- copolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001577 copolymer Polymers 0.000 title abstract 3
- 239000005977 Ethylene Substances 0.000 title abstract 2
- 238000003776 cleavage reaction Methods 0.000 title 1
- 230000007017 scission Effects 0.000 title 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000003377 acid catalyst Substances 0.000 abstract 1
- 125000002843 carboxylic acid group Chemical group 0.000 abstract 1
- 125000004185 ester group Chemical group 0.000 abstract 1
- 150000002576 ketones Chemical class 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/12—Hydrolysis
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
- C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2810/00—Chemical modification of a polymer
- C08F2810/50—Chemical modification of a polymer wherein the polymer is a copolymer and the modification is taking place only on one or more of the monomers present in minority
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
A copolymer of (a) more than 50% by weight ethylene with (b) an ester of a C3-C12 alkene carboxylic acid with a C3-C8 sec. and/or C4-C8 tert. alcohol, is cleaved to convert ester groups to carboxylic acid groups by suspending the copolymer, in the form of particles having a size of 0.1 to 8 mm, in a ketone, alcohol or ester at 40 to 75 DEG C and in the presence of an acid catalyst.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2937239A DE2937239C2 (en) | 1979-09-14 | 1979-09-14 | Process for the production of copolymers of ethylene |
Publications (2)
Publication Number | Publication Date |
---|---|
ES494985A0 ES494985A0 (en) | 1981-08-01 |
ES8106741A1 true ES8106741A1 (en) | 1981-08-01 |
Family
ID=6080913
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES494985A Expired ES8106741A1 (en) | 1979-09-14 | 1980-09-12 | Cleavage of ethylene ester copolymers |
Country Status (7)
Country | Link |
---|---|
BE (1) | BE885125A (en) |
DE (1) | DE2937239C2 (en) |
ES (1) | ES8106741A1 (en) |
FR (1) | FR2464969B1 (en) |
GB (1) | GB2058795B (en) |
IT (1) | IT1145669B (en) |
NL (1) | NL182729C (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4334846A1 (en) * | 1993-10-13 | 1995-04-20 | Basf Ag | Process for the preparation of copolymers of ethylene containing carboxyl groups |
DE10008931A1 (en) | 2000-02-25 | 2001-08-30 | Basf Ag | Process for the preparation of emulsifiable ethylene polymers |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1745136A1 (en) * | 1967-08-16 | 1971-08-05 | Monsanto Chemicals | Production of polymers containing hydroxyl groups |
-
1979
- 1979-09-14 DE DE2937239A patent/DE2937239C2/en not_active Expired
-
1980
- 1980-09-01 NL NLAANVRAGE8004965,A patent/NL182729C/en not_active IP Right Cessation
- 1980-09-05 FR FR8019278A patent/FR2464969B1/en not_active Expired
- 1980-09-08 BE BE0/202018A patent/BE885125A/en not_active IP Right Cessation
- 1980-09-12 ES ES494985A patent/ES8106741A1/en not_active Expired
- 1980-09-15 GB GB8029695A patent/GB2058795B/en not_active Expired
- 1980-09-15 IT IT49676/80A patent/IT1145669B/en active
Also Published As
Publication number | Publication date |
---|---|
ES494985A0 (en) | 1981-08-01 |
BE885125A (en) | 1981-03-09 |
IT8049676A0 (en) | 1980-09-15 |
FR2464969A1 (en) | 1981-03-20 |
DE2937239A1 (en) | 1981-03-19 |
NL182729B (en) | 1987-12-01 |
NL182729C (en) | 1988-05-02 |
NL8004965A (en) | 1981-03-17 |
GB2058795B (en) | 1983-05-05 |
GB2058795A (en) | 1981-04-15 |
DE2937239C2 (en) | 1985-10-03 |
FR2464969B1 (en) | 1985-11-22 |
IT1145669B (en) | 1986-11-05 |
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