ES8105743A1 - Procedimiento para preparar haluros de s-alcohilo ramificado-fosfonoditioicos - Google Patents

Procedimiento para preparar haluros de s-alcohilo ramificado-fosfonoditioicos

Info

Publication number
ES8105743A1
ES8105743A1 ES494630A ES494630A ES8105743A1 ES 8105743 A1 ES8105743 A1 ES 8105743A1 ES 494630 A ES494630 A ES 494630A ES 494630 A ES494630 A ES 494630A ES 8105743 A1 ES8105743 A1 ES 8105743A1
Authority
ES
Spain
Prior art keywords
alkyl
branched
production
halide intermediates
intermediates
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES494630A
Other languages
English (en)
Other versions
ES494630A0 (es
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Publication of ES8105743A1 publication Critical patent/ES8105743A1/es
Publication of ES494630A0 publication Critical patent/ES494630A0/es
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P—C bonds
    • C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
    • C07F9/165—Esters of thiophosphoric acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/42—Halides thereof
    • C07F9/425—Acid or estermonohalides thereof, e.g. RP(=X)(YR)(Hal) (X, Y = O, S; R = H, or hydrocarbon group)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/40—Esters thereof
    • C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/4006—Esters of acyclic acids which can have further substituents on alkyl

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Saccharide Compounds (AREA)

Abstract

PROCEDIMIENTO PARA LA PREPARACION DE HALUROS DE S-ALCOHILO RAMIFICADO-FOSFONODITIOICOS DE FORMULA (I), EN LA QUE R ES ALCOHILO DE 1 A 6 ATOMOS DE CARBONO; R1 ES ALCOHILO DE 4 A 8 ATOMOS DE CARBONO RAMIFICADO EN POSICION ALFA Y X ES HALOGENO. SE BASA EN LA REACCION DE ADICION DIRECTA DE TIOLES DE FORMULA R1SH A DIHALUROS ALCOHILFOSFONOTIOICOS DE FORMULA (II), EN AGUA O UN DISOLVENTE ORGANICO Y EN PRESENCIA DE UNA BASE, A TEMPERATURAS ENTRE 20 A 100 GC. SI EL DISOLVENTE ES AGUA, LA BASE ES HIDROXIDO SODICO, Y SI SE UTILIZA DISOLVENTE ORGANICO, LA BASE ES AMINA TERCIARIA, QUE SE AÑADE GOTA A GOTA A LOS OTROS REACTIVOS A TEMPERATURA INFERIOR A 50 GC, ANTES DE CALENTAR LA MEZCLA. ESTOS COMPUESTOS SON UTILES COMO INTERMEDIOS EN LA SINTESIS DE INSECTICIDADES Y NEMATOCIDAS. *FORMULA*
ES494630A 1979-08-31 1980-08-29 Procedimiento para preparar haluros de s-alcohilo ramificado-fosfonoditioicos Granted ES494630A0 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US7146579A 1979-08-31 1979-08-31

Publications (2)

Publication Number Publication Date
ES8105743A1 true ES8105743A1 (es) 1981-06-16
ES494630A0 ES494630A0 (es) 1981-06-16

Family

ID=22101507

Family Applications (1)

Application Number Title Priority Date Filing Date
ES494630A Granted ES494630A0 (es) 1979-08-31 1980-08-29 Procedimiento para preparar haluros de s-alcohilo ramificado-fosfonoditioicos

Country Status (15)

Country Link
EP (1) EP0025270B1 (es)
JP (1) JPS5645494A (es)
KR (1) KR830002057B1 (es)
AT (1) ATE8634T1 (es)
AU (1) AU541928B2 (es)
BR (1) BR8005509A (es)
CA (1) CA1178294A (es)
DD (1) DD153846A5 (es)
DE (1) DE3068679D1 (es)
DK (1) DK369980A (es)
EG (1) EG14458A (es)
ES (1) ES494630A0 (es)
HU (1) HU184823B (es)
IL (1) IL60893A (es)
ZA (1) ZA805027B (es)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4391760A (en) * 1980-12-31 1983-07-05 Rhone-Poulenc Agrochimie S-(Tertiary alkyl) alkylphosphonothioic halides
FR2523584B1 (fr) * 1982-03-17 1985-06-28 Rhone Poulenc Agrochimie Halogenures d'acides s-(tertioalcoyl) alcoylphosphonothioiques, leur preparation et leur utilisation

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1104506B (de) * 1959-09-08 1961-04-13 Bayer Ag Verfahren zur Herstellung von Dithiophosphonsaeureesterfluoriden oder -aziden
DE2652922A1 (de) * 1976-11-20 1978-05-24 Bayer Ag Diothiophosphonsaeureesterhalogenide, verfahren zu ihrer herstellung und ihre verwendung als zwischenprodukte
DE2702049A1 (de) * 1977-01-19 1978-07-20 Bayer Ag Substituierte dithiophosphonsaeureesteramide, verfahren zu ihrer herstellung und ihre verwendung als insektizide, akarizide und nematizide
DE2714771C2 (de) * 1977-04-02 1984-12-06 Bayer Ag, 5090 Leverkusen O-Phenyldithiophosphonsäureester, Verfahren zu ihrer Herstellung und ihre Verwendung als Insektizide, Akarizide und Nematizide

Also Published As

Publication number Publication date
AU6149580A (en) 1981-03-05
KR830002057B1 (ko) 1983-10-08
BR8005509A (pt) 1981-03-10
CA1178294A (en) 1984-11-20
DD153846A5 (de) 1982-02-03
ZA805027B (en) 1981-08-26
EG14458A (en) 1984-06-30
IL60893A0 (en) 1980-10-26
JPS5645494A (en) 1981-04-25
EP0025270B1 (en) 1984-07-25
DK369980A (da) 1981-03-01
KR830003507A (ko) 1983-06-21
ATE8634T1 (de) 1984-08-15
HU184823B (en) 1984-10-29
DE3068679D1 (en) 1984-08-30
AU541928B2 (en) 1985-01-31
ES494630A0 (es) 1981-06-16
IL60893A (en) 1984-05-31
EP0025270A1 (en) 1981-03-18
JPS6353197B2 (es) 1988-10-21

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