ES8105253A1 - Novel m-phenoxybenzyl ester derivative useful as insecticidal and acaracidal agent - Google Patents
Novel m-phenoxybenzyl ester derivative useful as insecticidal and acaracidal agentInfo
- Publication number
- ES8105253A1 ES8105253A1 ES478787A ES478787A ES8105253A1 ES 8105253 A1 ES8105253 A1 ES 8105253A1 ES 478787 A ES478787 A ES 478787A ES 478787 A ES478787 A ES 478787A ES 8105253 A1 ES8105253 A1 ES 8105253A1
- Authority
- ES
- Spain
- Prior art keywords
- novel
- acaracidal
- insecticidal
- agent
- alpha
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/10—Aromatic or araliphatic carboxylic acids, or thio analogues thereof; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/34—Nitriles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
- A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/10—Sulfones; Sulfoxides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P33/00—Antiparasitic agents
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
- C07C255/01—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
- C07C255/32—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing at least one six-membered aromatic ring
- C07C255/38—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing at least one six-membered aromatic ring the carbon skeleton being further substituted by esterified hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
- C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
- C07C45/70—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction with functional groups containing oxygen only in singly bound form
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C47/00—Compounds having —CHO groups
- C07C47/52—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings
- C07C47/575—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings containing ether groups, groups, groups, or groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/08—Preparation of carboxylic acids or their salts, halides or anhydrides from nitriles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
- C07C51/363—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by introduction of halogen; by substitution of halogen atoms by other halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
- C07C51/367—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by introduction of functional groups containing oxygen only in singly bound form
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/58—Preparation of carboxylic acid halides
- C07C51/60—Preparation of carboxylic acid halides by conversion of carboxylic acids or their anhydrides or esters, lactones, salts into halides with the same carboxylic acid part
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/612—Esters of carboxylic acids having a carboxyl group bound to an acyclic carbon atom and having a six-membered aromatic ring in the acid moiety
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/612—Esters of carboxylic acids having a carboxyl group bound to an acyclic carbon atom and having a six-membered aromatic ring in the acid moiety
- C07C69/614—Esters of carboxylic acids having a carboxyl group bound to an acyclic carbon atom and having a six-membered aromatic ring in the acid moiety of phenylacetic acid
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Environmental Sciences (AREA)
- Dentistry (AREA)
- Pest Control & Pesticides (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Veterinary Medicine (AREA)
- Tropical Medicine & Parasitology (AREA)
- General Chemical & Material Sciences (AREA)
- Medicinal Chemistry (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Pharmacology & Pharmacy (AREA)
- Animal Behavior & Ethology (AREA)
- Public Health (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
This invention provides a novel m- phenoxybenzyl ester derivative which is useful as an insecticidal and acaracidal agent. The novel compound is (+/-)- alpha -cyano-m-phenoxybenzyl (+)- alpha -isopropyl-4- difluoromethoxyphenylacetate which may be obtained by reaction of a (+)- alpha -isopropyl-4-difluoromethoxyacetyl halide with (+/-)- alpha -cyano-m- phenoxybenzyl alcohol. The structure of the novel compound is represented by the formula: < IMAGE > The novel compound exhibits outstanding activity as a contact and stomach poison for ixodide ticks and for a wide variety of insects.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US05/890,568 US4199595A (en) | 1976-10-01 | 1978-03-20 | M-phenoxybenzyl and α-cyano-M-phenoxybenzyl esters of 2-haloalkyl (oxy-, thio-, sulfinyl-, or sulfonyl)phenylalkanoic acids |
US05/890,721 US4178460A (en) | 1976-10-01 | 1978-03-20 | 2-Haloalkyl(oxy-, thio-, sulfinyl-, or sulfonyl)-phenylalkanoic acids |
Publications (2)
Publication Number | Publication Date |
---|---|
ES8105253A1 true ES8105253A1 (en) | 1981-05-16 |
ES478787A0 ES478787A0 (en) | 1981-05-16 |
Family
ID=27128953
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES478785A Expired ES8303283A2 (en) | 1978-03-20 | 1979-03-20 | Novel m-phenoxybenzyl ester derivative useful as insecticidal and acaracidal agent |
ES478787A Granted ES478787A0 (en) | 1978-03-20 | 1979-03-20 | PROCEDURE FOR PREPARING PHENYLALCANOIC ACIDS. |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES478785A Expired ES8303283A2 (en) | 1978-03-20 | 1979-03-20 | Novel m-phenoxybenzyl ester derivative useful as insecticidal and acaracidal agent |
Country Status (17)
Country | Link |
---|---|
JP (1) | JPS54135742A (en) |
AR (1) | AR228014A1 (en) |
AT (1) | AT367965B (en) |
AU (2) | AU525146B2 (en) |
BR (1) | BR7901697A (en) |
CH (2) | CH640513A5 (en) |
DD (5) | DD149601A6 (en) |
DK (1) | DK112679A (en) |
ES (2) | ES8303283A2 (en) |
GB (1) | GB2017688B (en) |
GR (1) | GR74446B (en) |
HU (1) | HU182016B (en) |
NL (1) | NL7902153A (en) |
NZ (1) | NZ189915A (en) |
PL (1) | PL123011B1 (en) |
RO (1) | RO79551A (en) |
SE (1) | SE444313B (en) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2837524A1 (en) * | 1978-08-28 | 1980-03-20 | Bayer Ag | Phenylacetic acid ester derivs. from pyrethroid alcohol(s) - useful as insecticides and acaricides, and new intermediates |
IL61348A (en) * | 1979-11-28 | 1984-05-31 | American Cyanamid Co | (-)-alpha-cyano-m-phenoxybenzyl(+)alpha-isopropyl-4-difluoromethoxy-phenylacetate,its preparation and its use as an insecticide |
JPS56133253A (en) * | 1980-03-24 | 1981-10-19 | Sumitomo Chem Co Ltd | Optical isomer of cyanohydrin ester, its production and insecticide and acaricide containing the same as effective ingredient |
JPS56139445A (en) * | 1980-04-02 | 1981-10-30 | Sumitomo Chem Co Ltd | Stereoisomer of cyanohydrin ester, its production and insecticide, acaricide containing the same as active principle |
JPS5793948A (en) * | 1980-12-02 | 1982-06-11 | Sumitomo Chem Co Ltd | Preparation of stereoisomer mixture of higher active phenylacetic ester derivative |
DE3103325A1 (en) * | 1981-01-31 | 1982-08-26 | Bayer Ag, 5090 Leverkusen | 4-FLUOR-3-HALOPHENOXY-BENZYL ESTER, METHOD FOR THE PRODUCTION AND USE THEREOF IN PEST CONTROL, AND NEW INTERMEDIATE PRODUCTS AND METHOD FOR THE PRODUCTION THEREOF |
FR2512815B1 (en) * | 1981-04-16 | 1989-04-14 | Roussel Uclaf | NOVEL DERIVATIVES OF CYCLOPROPANE CARBOXYLIC ACID, THEIR PREPARATION METHOD, THEIR APPLICATION TO THE CONTROL OF PESTS |
IL69304A0 (en) * | 1982-08-23 | 1983-11-30 | American Cyanamid Co | Method for the preparation of difluoromethoxyaromatic compounds |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5133612B2 (en) * | 1973-04-19 | 1976-09-21 | Sumitomo Chemical Co | |
IL52973A (en) * | 1976-10-01 | 1983-10-31 | American Cyanamid Co | Alpha-(haloalkoxy and haloalkyl-thiophenyl)alkanoic acid ester derivatives,their preparation and insecticidal and acaricidal compositions containing them |
-
1979
- 1979-02-16 GR GR58388A patent/GR74446B/el unknown
- 1979-03-15 NZ NZ189915A patent/NZ189915A/en unknown
- 1979-03-17 RO RO7996953A patent/RO79551A/en unknown
- 1979-03-19 AT AT0204979A patent/AT367965B/en not_active IP Right Cessation
- 1979-03-19 NL NL7902153A patent/NL7902153A/en not_active Application Discontinuation
- 1979-03-19 DK DK112679A patent/DK112679A/en not_active Application Discontinuation
- 1979-03-19 AU AU45242/79A patent/AU525146B2/en not_active Ceased
- 1979-03-19 CH CH257479A patent/CH640513A5/en not_active IP Right Cessation
- 1979-03-19 AU AU45251/79A patent/AU528525B2/en not_active Expired
- 1979-03-19 BR BR7901697A patent/BR7901697A/en unknown
- 1979-03-19 SE SE7902467A patent/SE444313B/en not_active IP Right Cessation
- 1979-03-19 GB GB7909542A patent/GB2017688B/en not_active Expired
- 1979-03-19 PL PL1979214234A patent/PL123011B1/en unknown
- 1979-03-19 CH CH257379A patent/CH641638A5/en not_active IP Right Cessation
- 1979-03-20 DD DD79219673A patent/DD149601A6/en unknown
- 1979-03-20 DD DD79211693A patent/DD143601A5/en unknown
- 1979-03-20 DD DD79220465A patent/DD154535A5/en unknown
- 1979-03-20 ES ES478785A patent/ES8303283A2/en not_active Expired
- 1979-03-20 JP JP3318979A patent/JPS54135742A/en active Granted
- 1979-03-20 DD DD79220007A patent/DD152539A5/en unknown
- 1979-03-20 ES ES478787A patent/ES478787A0/en active Granted
- 1979-03-20 AR AR275883A patent/AR228014A1/en active
- 1979-03-20 HU HU79AE565A patent/HU182016B/en unknown
- 1979-03-20 DD DD79211694A patent/DD150455A6/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
RO79551A (en) | 1982-08-17 |
GB2017688A (en) | 1979-10-10 |
AU525146B2 (en) | 1982-10-21 |
AU528525B2 (en) | 1983-05-05 |
DD150455A6 (en) | 1981-09-02 |
DD149601A6 (en) | 1981-07-22 |
ATA204979A (en) | 1982-01-15 |
DD154535A5 (en) | 1982-03-31 |
HU182016B (en) | 1983-12-28 |
AR228014A1 (en) | 1983-01-14 |
SE7902467L (en) | 1979-11-19 |
GB2017688B (en) | 1982-08-18 |
CH641638A5 (en) | 1984-03-15 |
DK112679A (en) | 1979-09-21 |
PL123011B1 (en) | 1982-09-30 |
ES478785A0 (en) | 1983-02-01 |
DD152539A5 (en) | 1981-12-02 |
JPS54135742A (en) | 1979-10-22 |
SE444313B (en) | 1986-04-07 |
AU4524279A (en) | 1979-09-27 |
NL7902153A (en) | 1979-09-24 |
ES478787A0 (en) | 1981-05-16 |
DD143601A5 (en) | 1980-09-03 |
CH640513A5 (en) | 1984-01-13 |
GR74446B (en) | 1984-06-28 |
ES8303283A2 (en) | 1983-02-01 |
AU4525179A (en) | 1979-09-27 |
PL214234A3 (en) | 1980-08-25 |
AT367965B (en) | 1982-08-25 |
JPS6362507B2 (en) | 1988-12-02 |
BR7901697A (en) | 1979-10-16 |
NZ189915A (en) | 1981-04-24 |
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