ES478320A1 - Process for the manufacture of methyl mercaptan - Google Patents
Process for the manufacture of methyl mercaptanInfo
- Publication number
- ES478320A1 ES478320A1 ES478320A ES478320A ES478320A1 ES 478320 A1 ES478320 A1 ES 478320A1 ES 478320 A ES478320 A ES 478320A ES 478320 A ES478320 A ES 478320A ES 478320 A1 ES478320 A1 ES 478320A1
- Authority
- ES
- Spain
- Prior art keywords
- sulfide
- oxide
- methyl mercaptan
- hydroxide
- salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 title abstract 4
- 238000004519 manufacturing process Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- -1 alkali metal inorganic base Chemical class 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 239000002585 base Substances 0.000 abstract 1
- 229910002090 carbon oxide Inorganic materials 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 239000011651 chromium Substances 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910052750 molybdenum Inorganic materials 0.000 abstract 1
- 239000011733 molybdenum Substances 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
- C07C319/02—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/04—Mixing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/20—Sulfiding
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Methyl mercaptan is obtained by reacting a carbon oxide, hydrogen and hydrogen sulfide (or elemental sulfur) in the vapour phase in the presence of a catalyst which comprises a single- phase solid supported catalyst prepared by mixing an oxide, sulfide, hydroxide or salt of a metal from the group of iron, nickel, chromium, cobalt, molybdenum and zinc with either an organic amine base or an alkali metal inorganic base that is an oxide, hydroxide, sulfide or salt, and then sulfidizing the admixture.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US88343878A | 1978-03-06 | 1978-03-06 | |
| US1197779A | 1979-02-14 | 1979-02-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES478320A1 true ES478320A1 (en) | 1980-01-16 |
Family
ID=26683002
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES478320A Expired ES478320A1 (en) | 1978-03-06 | 1979-03-06 | Process for the manufacture of methyl mercaptan |
Country Status (11)
| Country | Link |
|---|---|
| JP (1) | JPS54135715A (en) |
| AR (1) | AR222991A1 (en) |
| BR (1) | BR7901361A (en) |
| CA (1) | CA1120499A (en) |
| DE (1) | DE2908668A1 (en) |
| ES (1) | ES478320A1 (en) |
| FR (1) | FR2419281A1 (en) |
| GB (1) | GB2016468B (en) |
| IT (1) | IT1114467B (en) |
| MX (1) | MX151167A (en) |
| NL (1) | NL190447C (en) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4449006A (en) * | 1982-09-29 | 1984-05-15 | Pennwalt Corporation | Preparation of methyl mercaptan from carbon oxides |
| US4536492A (en) * | 1982-09-29 | 1985-08-20 | Pennwalt Corporation | Catalyst for the preparation of methyl mercaptan from carbon oxides |
| US4491639A (en) * | 1982-09-30 | 1985-01-01 | Gas Research Institute | Methods of making high activity transition metal catalysts |
| EP1670754A2 (en) | 2003-10-10 | 2006-06-21 | Degussa AG | Process for the manufacture of methylmercaptan |
| CN101143329A (en) * | 2006-09-11 | 2008-03-19 | 德古萨股份公司 | Mo-O-K base catalyst, its preparation method and application in synthesizing methyl mercaptan |
| EP1982764A1 (en) * | 2007-04-17 | 2008-10-22 | Evonik Degussa GmbH | Catalyst for the preparation of methyl mercaptan |
| DE102007024576A1 (en) * | 2007-05-25 | 2009-05-20 | Evonik Degussa Gmbh | Process for the continuous production of methylmercaptan from carbon- and hydrogen-containing compounds |
| FR2937566B1 (en) * | 2008-10-24 | 2014-07-18 | Arkema France | HYDROGENATION CATALYST, IN PARTICULAR CARBON SULPHIDE |
| DE102009027837A1 (en) * | 2009-07-20 | 2011-01-27 | Evonik Degussa Gmbh | Process for the continuous production of methylmercaptan from carbonaceous compounds, sulfur and hydrogen |
| CN109195948B (en) | 2016-05-31 | 2021-05-11 | 诺华丝国际股份有限公司 | Method for producing methyl mercaptan from dimethyl sulfide |
| CN114849693A (en) * | 2022-06-17 | 2022-08-05 | 黄河三角洲京博化工研究院有限公司 | Catalyst for synthesizing methyl mercaptan, preparation method and application |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3070632A (en) * | 1959-12-21 | 1962-12-25 | Pennsalt Chemicals Corp | Process for preparation of methyl mercaptan |
-
1979
- 1979-03-01 GB GB7907182A patent/GB2016468B/en not_active Expired
- 1979-03-05 CA CA000322731A patent/CA1120499A/en not_active Expired
- 1979-03-05 MX MX176799A patent/MX151167A/en unknown
- 1979-03-05 IT IT48218/79A patent/IT1114467B/en active
- 1979-03-05 NL NLAANVRAGE7901730,A patent/NL190447C/en not_active IP Right Cessation
- 1979-03-06 BR BR7901361A patent/BR7901361A/en unknown
- 1979-03-06 AR AR275717A patent/AR222991A1/en active
- 1979-03-06 ES ES478320A patent/ES478320A1/en not_active Expired
- 1979-03-06 FR FR7905762A patent/FR2419281A1/en active Granted
- 1979-03-06 JP JP2519279A patent/JPS54135715A/en active Granted
- 1979-03-06 DE DE2908668A patent/DE2908668A1/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| GB2016468A (en) | 1979-09-26 |
| DE2908668C2 (en) | 1992-10-29 |
| JPS6312866B2 (en) | 1988-03-23 |
| AR222991A1 (en) | 1981-07-15 |
| FR2419281A1 (en) | 1979-10-05 |
| FR2419281B1 (en) | 1984-06-22 |
| NL7901730A (en) | 1979-09-10 |
| DE2908668A1 (en) | 1979-09-20 |
| NL190447B (en) | 1993-10-01 |
| NL190447C (en) | 1994-03-01 |
| CA1120499A (en) | 1982-03-23 |
| IT7948218A0 (en) | 1979-03-05 |
| GB2016468B (en) | 1982-09-15 |
| MX151167A (en) | 1984-10-08 |
| JPS54135715A (en) | 1979-10-22 |
| BR7901361A (en) | 1979-10-02 |
| IT1114467B (en) | 1986-01-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ES478320A1 (en) | Process for the manufacture of methyl mercaptan | |
| GB312717A (en) | Improvements in the manufacture and production of hydrocarbons | |
| ES526085A0 (en) | A PROCEDURE FOR PREPARING A TRANSITIONAL METAL SULPHIDE BASED CATALYST. | |
| KR850700131A (en) | Process for producing alcohol from carbon monoxide and hydrogen using alkali-molybdenum sulfide catalyst. | |
| ES2005467A6 (en) | Process for the production of organic polysulfides, and catalytic system for carrying it out. | |
| DE2960788D1 (en) | Process for preparing acetaldehyde | |
| GB907770A (en) | A process for the catalytic desulphurisation of hydrocarbon oils | |
| GB2347929A (en) | Production of formaldehyde using carbon oxides hydrogen and H 2 S | |
| ES482114A1 (en) | Process for preparing mercaptans | |
| ES8403864A1 (en) | Process for the synthesis by heterogeneous catalysis of mercaptans from olefines and hydrogen sulfide. | |
| GB1419603A (en) | Process for the producition of 3-halogen-and 3,5-dihalogen phenols | |
| GB1495011A (en) | Preparation of ketones | |
| ES2052836T3 (en) | PROCEDURE FOR PRODUCING ORGANIC SULFUR COMPOUNDS. | |
| ES8104217A1 (en) | Production of thiophenols. | |
| GB1475379A (en) | Preparation of thiocarbamyl sulphenamides | |
| ES390265A1 (en) | Production of sulphur from iron sulphide and sulphur dioxide | |
| GB861371A (en) | Process for the preparation of cyclopentadienyl manganese tricarbonyl compounds | |
| JPS5226361A (en) | Process for refining of harmful gases | |
| GB469933A (en) | Process for desulphurising gases | |
| GB1014444A (en) | Process for the preparation of ethyl mercaptan with or without diethyl sulfide | |
| ES417860A1 (en) | Process for the preparation of ketones | |
| DE3361725D1 (en) | Process for preparing 1,3-diamino-2,2-dialkyl propanes | |
| Neto et al. | Fundamental Aspects of Nickel Desulfurization | |
| LEE | Gaseous sulfidation of pure molybdenum at 700 deg- 950 deg C[Ph. D. Thesis] | |
| KR910016805A (en) | Method for producing polyphenylene sulfide |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FD1A | Patent lapsed |
Effective date: 19971001 |