ES467414A1 - Triorganotin compounds and method for combating insects using same - Google Patents
Triorganotin compounds and method for combating insects using sameInfo
- Publication number
- ES467414A1 ES467414A1 ES467414A ES467414A ES467414A1 ES 467414 A1 ES467414 A1 ES 467414A1 ES 467414 A ES467414 A ES 467414A ES 467414 A ES467414 A ES 467414A ES 467414 A1 ES467414 A1 ES 467414A1
- Authority
- ES
- Spain
- Prior art keywords
- reaction
- hydroxide
- alkali metal
- oxide
- alcoholic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title abstract 3
- 150000001875 compounds Chemical class 0.000 title abstract 2
- 241000238631 Hexapoda Species 0.000 title 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 8
- 239000002253 acid Substances 0.000 abstract 5
- 230000001476 alcoholic effect Effects 0.000 abstract 5
- 229910052783 alkali metal Inorganic materials 0.000 abstract 5
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 abstract 4
- -1 alkali metal salt Chemical class 0.000 abstract 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 3
- 229910019142 PO4 Inorganic materials 0.000 abstract 3
- GNVMUORYQLCPJZ-UHFFFAOYSA-M Thiocarbamate Chemical compound NC([S-])=O GNVMUORYQLCPJZ-UHFFFAOYSA-M 0.000 abstract 3
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 abstract 3
- 125000004432 carbon atom Chemical group C* 0.000 abstract 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 3
- 239000012990 dithiocarbamate Substances 0.000 abstract 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 3
- 239000010452 phosphate Substances 0.000 abstract 3
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 abstract 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 abstract 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 2
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 abstract 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 abstract 2
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 abstract 2
- NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Chemical compound [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 abstract 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 abstract 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 abstract 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 abstract 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 abstract 1
- 229910002651 NO3 Inorganic materials 0.000 abstract 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 229910052936 alkali metal sulfate Inorganic materials 0.000 abstract 1
- 229910052977 alkali metal sulfide Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 150000004703 alkoxides Chemical class 0.000 abstract 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 abstract 1
- 150000008064 anhydrides Chemical class 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052794 bromium Inorganic materials 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 150000007942 carboxylates Chemical class 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- XLJMAIOERFSOGZ-UHFFFAOYSA-M cyanate Chemical compound [O-]C#N XLJMAIOERFSOGZ-UHFFFAOYSA-M 0.000 abstract 1
- 239000011737 fluorine Substances 0.000 abstract 1
- 229910052731 fluorine Inorganic materials 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-M phenolate Chemical compound [O-]C1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-M 0.000 abstract 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 235000003270 potassium fluoride Nutrition 0.000 abstract 1
- 239000011698 potassium fluoride Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- 239000011593 sulfur Substances 0.000 abstract 1
- 150000003606 tin compounds Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/22—Tin compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/22—Tin compounds
- C07F7/2208—Compounds having tin linked only to carbon, hydrogen and/or halogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/22—Tin compounds
- C07F7/2224—Compounds having one or more tin-oxygen linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
A procedure to prepare new tri (sec-alcoholic) tin compounds of the general formula: **(See formula)** wherein R1 and R2 are individually selected from the group consisting of a branched and straight-chain alcohol containing 1 to 4 carbon atoms, provided that the total number of carbon atoms in R1 and R2 is 5 to 7, Y is selected from the group consisting of chlorine, bromine, fluorine, hydroxyl, cyanide, carbamate, thiocarbamate, dithiocarbamate, nitrate, phenoxy, (see formula), SR3, OR4, oxygen, sulfur, sulfate and phosphate, where R3 represents an alcoholic group containing 1 to 12 carbon or phenyl atoms, R4 is an alcoholic containing 1 to 12 carbon atoms, a represents the valence of Y and is selected from the integers 1, 2 and 3 and n represents a integer from 1 to 6, inclusive, in which said process comprises the steps of reacting at a temperature of 25 to + 80ºC, in a hydrocarbon solvent, a tetraorganotin compound of the general formula: **(See formula)** if desired, to form the corresponding fluoride by reaction with potassium fluoride or hydrofluoric acid, or via oxide or hydroxide by reaction with hydrofluoric acid; (a) the corresponding hydroxide by reaction with an aqueous alkali metal hydroxide; (b) the corresponding carboxylate by reaction with a carboxylic acid in the presence of an acid acceptor or with an alkali metal salt of a carboxylic acid, or via oxide or hydroxide by reaction with a carboxylic acid or an anhydride; (c) the corresponding phenoxide by reaction with an alkali metal phenoxide or with phenol in the presence of an acid acceptor, or via the oxide or hydroxide by reaction with phenol; (d) the corresponding alkoxide by reaction with an alkali metal alkoxide or with an alcohol in the presence of an acid acceptor; or via the oxide or hydroxide by reaction with an alcohol; (e) the corresponding mercaptide by reaction with an alcoholic mercaptan in the presence of an acid acceptor, or via the oxide or hydroxide by reaction with an alcoholic mercaptan; (f) the corresponding oxide by reaction with an alcoholic alkali metal hydroxide; (g) the corresponding sulfurized by reaction with an alkali metal sulfide, or via oxide or hydroxide by reaction with hydrogen sulfide; (h) the corresponding sulfate by reaction with alkali metal sulfate, or via the oxide or hydroxide by reaction with aqueous sulfuric acid; (i) the corresponding cyanate, thiocyanate, thiocarbamate or dithiocarbamate by reaction with an alkali metal cyanate, thiocyanate, thiocarbamate or dithiocarbamate or (j) the corresponding phosphate by reaction with phosphoric acid and in the presence of an acid acceptor or with a phosphate of alkali metal. (Machine-translation by Google Translate, not legally binding)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US77394177A | 1977-03-03 | 1977-03-03 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES467414A1 true ES467414A1 (en) | 1978-10-16 |
Family
ID=25099782
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES467414A Expired ES467414A1 (en) | 1977-03-03 | 1978-03-01 | Triorganotin compounds and method for combating insects using same |
Country Status (13)
| Country | Link |
|---|---|
| JP (1) | JPS53108930A (en) |
| AU (1) | AU514511B2 (en) |
| BE (1) | BE864360A (en) |
| BR (1) | BR7801204A (en) |
| CA (1) | CA1117132A (en) |
| DE (1) | DE2805987A1 (en) |
| DK (1) | DK95778A (en) |
| ES (1) | ES467414A1 (en) |
| FR (1) | FR2382457A1 (en) |
| GB (1) | GB1579410A (en) |
| IT (1) | IT1103083B (en) |
| NL (1) | NL7802351A (en) |
| SE (1) | SE7802325L (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55115807A (en) * | 1979-03-02 | 1980-09-06 | Kanesho Kk | Acaricide in agriculture and horticulture |
| AR243195A1 (en) * | 1985-09-03 | 1993-07-30 | Shionogi & Co Ltd Y Nitto Kase | Tri-organo-tin compounds and pesticide compounds that contain them. |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3226292A (en) * | 1962-04-18 | 1965-12-28 | Dow Chemical Co | Bis(tripropyltin) oxide anthelmintic composition and method of using same |
-
1978
- 1978-02-02 GB GB4300/78A patent/GB1579410A/en not_active Expired
- 1978-02-13 DE DE19782805987 patent/DE2805987A1/en not_active Withdrawn
- 1978-02-20 AU AU33436/78A patent/AU514511B2/en not_active Expired
- 1978-02-23 FR FR7805219A patent/FR2382457A1/en active Pending
- 1978-02-27 CA CA000297818A patent/CA1117132A/en not_active Expired
- 1978-02-27 BE BE185519A patent/BE864360A/en unknown
- 1978-02-28 BR BR7801204A patent/BR7801204A/en unknown
- 1978-02-28 IT IT09361/78A patent/IT1103083B/en active
- 1978-03-01 ES ES467414A patent/ES467414A1/en not_active Expired
- 1978-03-01 SE SE7802325A patent/SE7802325L/en unknown
- 1978-03-02 DK DK95778A patent/DK95778A/en not_active Application Discontinuation
- 1978-03-03 JP JP2368478A patent/JPS53108930A/en active Pending
- 1978-03-03 NL NL7802351A patent/NL7802351A/en not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| AU514511B2 (en) | 1981-02-12 |
| GB1579410A (en) | 1980-11-19 |
| DE2805987A1 (en) | 1978-11-02 |
| BE864360A (en) | 1978-06-16 |
| FR2382457A1 (en) | 1978-09-29 |
| SE7802325L (en) | 1978-09-04 |
| CA1117132A (en) | 1982-01-26 |
| IT7809361A0 (en) | 1978-02-28 |
| BR7801204A (en) | 1979-01-02 |
| IT1103083B (en) | 1985-10-14 |
| AU3343678A (en) | 1979-08-30 |
| DK95778A (en) | 1978-09-04 |
| NL7802351A (en) | 1978-09-05 |
| JPS53108930A (en) | 1978-09-22 |
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