ES463432A1 - Procedimiento para mejorar la actividad de catalizadores portadores de plata usados. - Google Patents

Procedimiento para mejorar la actividad de catalizadores portadores de plata usados.

Info

Publication number
ES463432A1
ES463432A1 ES463432A ES463432A ES463432A1 ES 463432 A1 ES463432 A1 ES 463432A1 ES 463432 A ES463432 A ES 463432A ES 463432 A ES463432 A ES 463432A ES 463432 A1 ES463432 A1 ES 463432A1
Authority
ES
Spain
Prior art keywords
activity
improving
supported silver
silver catalysts
used supported
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES463432A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG filed Critical Hoechst AG
Publication of ES463432A1 publication Critical patent/ES463432A1/es
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/48Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/485Impregnating or reimpregnating with, or deposition of metal compounds or catalytically active elements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66Silver or gold
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90Regeneration or reactivation
    • B01J23/96Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the noble metals
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D301/00Preparation of oxiranes
    • C07D301/02Synthesis of the oxirane ring
    • C07D301/03Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/584Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Epoxy Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Procedimiento para mejorar la actividad de catalizadores portadores de plata usados destinados a la oxidación directa de etileno en óxido de etileno con oxígeno molecular o aire, mediante la aplicación de 1 a 1.000 partes de cesio y/o rubidio por cada millón de partes de catalizador sobre el catalizador ya consumido para la oxidación directa, con un líquido de impregnación que contenga compuestos de cesio y/o rubidio, caracterizado porque la aplicación se efectúa en dos o más pasos, acoplándose el catalizador después de cada paso del tratamiento nuevamente para la obtención de óxido de etileno mediante la oxidación directa de etileno con oxígeno molar o aire.
ES463432A 1976-10-29 1977-10-21 Procedimiento para mejorar la actividad de catalizadores portadores de plata usados. Expired ES463432A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE2649359A DE2649359C3 (de) 1976-10-29 1976-10-29 Verfahren zur Verbesserung der Wirksamkeit von gebrauchten Silber-Trägerkatalysatoren

Publications (1)

Publication Number Publication Date
ES463432A1 true ES463432A1 (es) 1978-07-01

Family

ID=5991887

Family Applications (1)

Application Number Title Priority Date Filing Date
ES463432A Expired ES463432A1 (es) 1976-10-29 1977-10-21 Procedimiento para mejorar la actividad de catalizadores portadores de plata usados.

Country Status (13)

Country Link
US (1) US4177169A (es)
JP (1) JPS5944898B2 (es)
AU (1) AU510768B2 (es)
BE (1) BE860353A (es)
BR (1) BR7707210A (es)
CA (1) CA1093056A (es)
DE (1) DE2649359C3 (es)
ES (1) ES463432A1 (es)
FR (1) FR2369275A1 (es)
GB (1) GB1577438A (es)
IT (1) IT1088157B (es)
NL (1) NL179980C (es)
SE (1) SE434804B (es)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5387751A (en) * 1978-02-10 1995-02-07 Imperial Chemical Industries Plc Production of olefine oxides
DE2936036A1 (de) * 1979-09-06 1981-04-02 EC Erdölchemie GmbH, 5000 Köln Verfahren zur herstellung von ethylenoxid
US4350616A (en) * 1980-07-03 1982-09-21 The Dow Chemical Company Method of making catalysts for the production of ethylene oxide
SE8203955L (sv) * 1981-07-17 1983-01-18 Northern Petro Chem Co Forfarande for avlegsnande av kalium fran anvenda etenoxidkatalysatorer?
US4419276A (en) * 1981-09-30 1983-12-06 Union Carbide Corporation Silver catalyst for the manufacture of ethylene oxide and a process for preparing the catalyst
US4760042A (en) * 1982-03-24 1988-07-26 Scientific Design Company, Inc. Process for preparing an alkali metal-promoted silver catalyst
US4406820A (en) * 1982-04-02 1983-09-27 Internorth, Inc. Controlled addition of promoters to ethylene oxide catalysts
US4774222A (en) * 1982-06-16 1988-09-27 Scientific Design Company, Inc. Catalyst for oxidation of ethylene to ethylene oxide and process for preparing the catalyst
DE3229541A1 (de) * 1982-08-07 1984-02-09 Hoechst Ag, 6230 Frankfurt Verfahren zur verbesserung der wirksamkeit von gebrauchten silber-traegerkatalysatoren
US4864042A (en) * 1984-05-14 1989-09-05 Scientific Design Company, Inc. Process for preparing silver catalysts
US4663303A (en) * 1986-02-24 1987-05-05 The Halcon Sd Group, Inc. Process for preparing silver catalysts
US5008413A (en) * 1989-10-23 1991-04-16 Scientific Design Company, Inc. Catalyst for oxidation of ethylene to ethylene oxide
WO1995014529A1 (fr) * 1993-11-23 1995-06-01 Institut Kataliza Imeni G.K.Boreskova Sibirskogo Otdelenia Rossiiskoi Akademii Nauk Compose poreux
BRPI0920425A2 (pt) 2008-10-08 2015-08-04 Basf Se Processo continuo para produzir um óxido de alquileno.

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2519599C2 (de) * 1975-05-02 1977-02-17 Hoechst Ag Verfahren zum reaktivieren von gebrauchten silber-traegerkatalysatoren
ES447348A1 (es) * 1975-05-02 1977-07-01 Hoechst Ag Procedimiento para la reactivacion de catalizadores de platausados para obtener oxido de etileno de acuerdo con el pro- cedimiento de oxidacion directa.
GB1574426A (en) * 1976-03-25 1980-09-10 Shell Int Research Process for preparing modified silver catalysts
FR2362846A1 (fr) * 1976-08-26 1978-03-24 Naphtachimie Sa Regeneration des catalyseurs de fabrication d'oxyde d'ethylene
DE2740480B2 (de) * 1977-09-08 1979-07-05 Hoechst Ag, 6000 Frankfurt Verfahren zur Verbesserung der Wirksamkeit von Silber-Trägerkatalysatoren

Also Published As

Publication number Publication date
GB1577438A (en) 1980-10-22
JPS5388682A (en) 1978-08-04
DE2649359A1 (de) 1978-05-03
NL179980B (nl) 1986-07-16
AU510768B2 (en) 1980-07-10
CA1093056A (en) 1981-01-06
SE434804B (sv) 1984-08-20
IT1088157B (it) 1985-06-10
US4177169A (en) 1979-12-04
FR2369275A1 (fr) 1978-05-26
JPS5944898B2 (ja) 1984-11-01
BR7707210A (pt) 1978-07-25
DE2649359B2 (es) 1978-11-30
FR2369275B1 (es) 1982-05-28
BE860353A (fr) 1978-05-02
NL179980C (nl) 1986-12-16
AU3014077A (en) 1979-05-03
DE2649359C3 (de) 1979-07-26
NL7711653A (nl) 1978-05-03
SE7712150L (sv) 1978-04-30

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Legal Events

Date Code Title Description
FD1A Patent lapsed

Effective date: 19971001