ES447632A1 - Catalyst for the production of ethylene oxide - Google Patents
Catalyst for the production of ethylene oxideInfo
- Publication number
- ES447632A1 ES447632A1 ES447632A ES447632A ES447632A1 ES 447632 A1 ES447632 A1 ES 447632A1 ES 447632 A ES447632 A ES 447632A ES 447632 A ES447632 A ES 447632A ES 447632 A1 ES447632 A1 ES 447632A1
- Authority
- ES
- Spain
- Prior art keywords
- silver
- catalyst
- support
- ethylene oxide
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
A procedure for obtaining ethylene oxide, reacting ethylene in the vapor phase with molecular oxygen under conditions of ethylene oxide formation, characterized in that the reaction is carried out in the presence of a silver catalyst, which has been prepared by a process comprising the following steps: (a) impregnating a porous refractory support, having a surface area of from 0.03 m2/g to 10 m2/g, with a solution of an alkali metal compound having an atomic number of 19 at 55, in such a concentration as is obtained in the final catalyst, optionally after extraction with a solvent after step (b) or (c) below, a content of from 0.25 to 16 milliequivalents -gram of the alkali metal per kilogram of total catalyst for each square meter of surface area of the support per gram of support of the catalyst ((meq-g/kg)/(m2/g)); (b) at least partially drying the impregnated support of step (a); (c) contacting the product of step (b) with a liquid phase containing a dissolved silver compound or a suspension of silver particles or a silver compound, in an amount sufficient to deposit from 1 to 25 per weight percent silver, based on the total catalyst, on the surface of the support, and (d) heat treating the product from step (c) to convert the silver compound to metallic silver. (Machine-translation by Google Translate, not legally binding)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB49962/73A GB1489335A (en) | 1973-10-26 | 1973-10-26 | Catalyst for the production of ethylene oxide |
Publications (1)
Publication Number | Publication Date |
---|---|
ES447632A1 true ES447632A1 (en) | 1977-06-16 |
Family
ID=10454139
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES431308A Expired ES431308A1 (en) | 1973-10-26 | 1974-10-24 | Catalyst for the production of ethylene oxide |
ES447632A Expired ES447632A1 (en) | 1973-10-26 | 1976-05-06 | Catalyst for the production of ethylene oxide |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES431308A Expired ES431308A1 (en) | 1973-10-26 | 1974-10-24 | Catalyst for the production of ethylene oxide |
Country Status (15)
Country | Link |
---|---|
JP (1) | JPS581629B2 (en) |
BE (1) | BE821439A (en) |
CA (1) | CA1048010A (en) |
CS (1) | CS219313B2 (en) |
DD (1) | DD114407A5 (en) |
DE (1) | DE2448449C2 (en) |
ES (2) | ES431308A1 (en) |
FR (1) | FR2249087B1 (en) |
GB (1) | GB1489335A (en) |
IN (1) | IN143192B (en) |
IT (1) | IT1025175B (en) |
NL (1) | NL7413748A (en) |
PL (1) | PL99702B1 (en) |
RO (1) | RO84369B (en) |
SE (2) | SE407156B (en) |
Families Citing this family (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2640540C3 (en) * | 1976-09-09 | 1988-07-28 | Basf Ag, 6700 Ludwigshafen | Catalyst for the production of ethylene oxide |
US4066575A (en) * | 1976-07-26 | 1978-01-03 | Halcon International, Inc. | Process for the preparation of a supported silver catalyst |
DE2819595A1 (en) * | 1977-05-12 | 1978-12-07 | Basf Ag | CATALYST FOR THE PRODUCTION OF ETHYLENE OXIDE |
JPS5689843A (en) * | 1979-12-25 | 1981-07-21 | Nippon Shokubai Kagaku Kogyo Co Ltd | Silver catalyst for production of ethylene oxide |
US4419276A (en) | 1981-09-30 | 1983-12-06 | Union Carbide Corporation | Silver catalyst for the manufacture of ethylene oxide and a process for preparing the catalyst |
US4455392A (en) * | 1981-10-05 | 1984-06-19 | Union Carbide Corporation | Process for preparing a supported silver catalyst |
BG37835A3 (en) * | 1982-06-30 | 1985-08-15 | Hoechst Aktiengesellschaft | Method for preparing silver catalyst |
US4575494A (en) * | 1984-02-08 | 1986-03-11 | The Dow Chemical Company | Alumina compositions useful as catalyst supports for ethylene oxidation |
JPS60216844A (en) * | 1984-04-13 | 1985-10-30 | Nippon Shokubai Kagaku Kogyo Co Ltd | Silver catalyst for producing ethylene oxide |
MX256050B (en) * | 2002-06-28 | 2008-04-07 | Shell Int Research | A method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin. |
CN1665797B (en) | 2002-06-28 | 2011-09-14 | 国际壳牌研究有限公司 | Method for the start-up of an epoxidation process and a process for the epoxidation of an olefin |
US7348444B2 (en) | 2003-04-07 | 2008-03-25 | Shell Oil Company | Process for the production of an olefin oxide |
US6846774B2 (en) * | 2003-04-23 | 2005-01-25 | Scientific Design Co., Inc. | Ethylene oxide catalyst |
US20040225138A1 (en) | 2003-05-07 | 2004-11-11 | Mcallister Paul Michael | Reactor system and process for the manufacture of ethylene oxide |
EP1624964B1 (en) * | 2003-05-07 | 2019-07-31 | Shell International Research Maatschappij B.V. | Silver-containing catalysts, the manufacture of such silver-containing catalysts, and the use thereof |
US8148555B2 (en) | 2003-06-26 | 2012-04-03 | Shell Oil Company | Method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin |
BRPI0515905A (en) | 2004-09-24 | 2008-08-12 | Shell Int Research | a process for selecting molded particles, a process for installing a system, a process for reacting a gaseous feed load on such a system, a computer program product, and a computer system |
KR20100017689A (en) | 2007-05-09 | 2010-02-16 | 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 | An epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine |
JP5868703B2 (en) | 2008-05-07 | 2016-02-24 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | Process for producing olefin oxide, 1,2-diol, 1,2-diol ether, 1,2-carbonate or alkanolamine |
EP2297124B1 (en) | 2008-05-07 | 2013-08-21 | Shell Internationale Research Maatschappij B.V. | A process for the start-up of an epoxidation process, a process for the production of ethylene oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine |
US11801493B2 (en) | 2016-12-02 | 2023-10-31 | Shell Usa, Inc. | Methods for conditioning an ethylene epoxidation catalyst and associated methods for the production of ethylene oxide |
US11772082B1 (en) | 2018-06-21 | 2023-10-03 | Avn Corporation | Catalyst supports—composition and process of manufacture |
WO2019245859A1 (en) | 2018-06-21 | 2019-12-26 | The J. David Gladstone Institutes | Generation of a population of hindbrain cells and hindbrain-like organoids from pluripotent stem cells |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE793658A (en) * | 1972-01-07 | 1973-07-04 | Shell Int Research | CATALYST USED FOR THE PRODUCTION OF ETHYLENE OXIDE |
-
1973
- 1973-10-26 GB GB49962/73A patent/GB1489335A/en not_active Expired
-
1974
- 1974-10-03 SE SE7412461A patent/SE407156B/en not_active IP Right Cessation
- 1974-10-07 CA CA210,866A patent/CA1048010A/en not_active Expired
- 1974-10-10 DE DE2448449A patent/DE2448449C2/en not_active Expired
- 1974-10-21 NL NL7413748A patent/NL7413748A/en active Search and Examination
- 1974-10-22 IN IN2330/CAL/74A patent/IN143192B/en unknown
- 1974-10-24 BE BE149849A patent/BE821439A/en not_active IP Right Cessation
- 1974-10-24 ES ES431308A patent/ES431308A1/en not_active Expired
- 1974-10-24 JP JP49122005A patent/JPS581629B2/en not_active Expired
- 1974-10-24 IT IT28761/74A patent/IT1025175B/en active
- 1974-10-24 FR FR7435691A patent/FR2249087B1/fr not_active Expired
- 1974-10-25 RO RO80324A patent/RO84369B/en unknown
- 1974-10-25 CS CS747326A patent/CS219313B2/en unknown
- 1974-10-25 DD DD181925A patent/DD114407A5/xx unknown
- 1974-10-25 PL PL1974175085A patent/PL99702B1/en unknown
-
1976
- 1976-05-06 ES ES447632A patent/ES447632A1/en not_active Expired
-
1978
- 1978-08-24 SE SE7808959A patent/SE434837B/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
SE7412461L (en) | 1975-04-28 |
IN143192B (en) | 1977-10-15 |
GB1489335A (en) | 1977-10-19 |
SE7808959L (en) | 1978-08-24 |
JPS5074589A (en) | 1975-06-19 |
BE821439A (en) | 1975-04-24 |
CS219313B2 (en) | 1983-03-25 |
DE2448449C2 (en) | 1986-03-06 |
IT1025175B (en) | 1978-08-10 |
NL7413748A (en) | 1975-04-29 |
CA1048010A (en) | 1979-02-06 |
JPS581629B2 (en) | 1983-01-12 |
DE2448449A1 (en) | 1975-04-30 |
FR2249087A1 (en) | 1975-05-23 |
SE407156B (en) | 1979-03-19 |
PL99702B1 (en) | 1978-08-31 |
RO84369A (en) | 1984-06-21 |
RO84369B (en) | 1984-08-30 |
ES431308A1 (en) | 1976-11-16 |
SE434837B (en) | 1984-08-20 |
FR2249087B1 (en) | 1976-10-22 |
DD114407A5 (en) | 1975-08-05 |
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