ES426529A1 - Zirconium enhanced activity of transition metal-bromine catalysis of di- and trimethyl benzene oxidation in liquid phase - Google Patents

Zirconium enhanced activity of transition metal-bromine catalysis of di- and trimethyl benzene oxidation in liquid phase

Info

Publication number
ES426529A1
ES426529A1 ES426529A ES426529A ES426529A1 ES 426529 A1 ES426529 A1 ES 426529A1 ES 426529 A ES426529 A ES 426529A ES 426529 A ES426529 A ES 426529A ES 426529 A1 ES426529 A1 ES 426529A1
Authority
ES
Spain
Prior art keywords
bromine
zirconium
liquid phase
catalysis
transition metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES426529A
Other languages
Spanish (es)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Standard Oil Co
Original Assignee
Standard Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Standard Oil Co filed Critical Standard Oil Co
Publication of ES426529A1 publication Critical patent/ES426529A1/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
    • C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

Process of oxidation of di- or trimethylbenzenes, with molecular oxygen to form di- or tricarboxylic acids, under liquid phase conditions, at temperatures of the order of 130 to 275ºC, characterized in that it involves conducting said oxidation in the presence of a catalytic system consisting of a source of bromine with manganese or cobalt and manganese and zirconium as the only non-polyvalent metal. (Machine-translation by Google Translate, not legally binding)
ES426529A 1973-05-21 1974-05-21 Zirconium enhanced activity of transition metal-bromine catalysis of di- and trimethyl benzene oxidation in liquid phase Expired ES426529A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US362464A US3920735A (en) 1973-05-21 1973-05-21 Zirconium enhanced activity of transition metal-bromine catalysis of di- and trimethyl benzene oxidation in liquid phase

Publications (1)

Publication Number Publication Date
ES426529A1 true ES426529A1 (en) 1976-07-01

Family

ID=23426220

Family Applications (1)

Application Number Title Priority Date Filing Date
ES426529A Expired ES426529A1 (en) 1973-05-21 1974-05-21 Zirconium enhanced activity of transition metal-bromine catalysis of di- and trimethyl benzene oxidation in liquid phase

Country Status (24)

Country Link
US (1) US3920735A (en)
JP (1) JPS5653531B2 (en)
AR (1) AR201586A1 (en)
BE (1) BE814349A (en)
BG (1) BG22371A3 (en)
BR (1) BR7404000D0 (en)
CA (1) CA1020567A (en)
CS (1) CS177176B2 (en)
DD (1) DD111896A5 (en)
DE (1) DE2420960C2 (en)
EG (1) EG11167A (en)
ES (1) ES426529A1 (en)
FR (1) FR2240913B1 (en)
GB (1) GB1467886A (en)
HU (2) HU174969B (en)
IN (1) IN142878B (en)
IT (1) IT1013188B (en)
NL (1) NL175908C (en)
PL (1) PL94127B1 (en)
RO (1) RO65801A (en)
SE (1) SE428559B (en)
SU (1) SU674667A3 (en)
TR (1) TR17961A (en)
YU (1) YU141274A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2081265A1 (en) * 1993-09-28 1996-02-16 Samsung General Chemicals Co Production method of high purity isomers of benzenedicarboxylic acids

Families Citing this family (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS52106833A (en) * 1976-02-24 1977-09-07 Matsuyama Sekyu Kagaku Kk Production of telephthalic acid for direct polymerization
US4158738A (en) * 1977-05-26 1979-06-19 E. I. Du Pont De Nemours And Company Process for the production of fiber-grade terephthalic acid
US4299977A (en) * 1978-01-05 1981-11-10 Standard Oil Company (Indiana) Preparation of phthalic acid by solventless oxidation of liquid ortho-xylene
US4322549A (en) * 1978-02-01 1982-03-30 Standard Oil Company (Indiana) Oxidation of di- and trimethyl aromatic hydrocarbons having ortho-oriented methyl groups in liquid phthalic acid
US4211881A (en) * 1978-11-17 1980-07-08 Standard Oil Company (Indiana) Preparation of phthalic acid by single step continuous air oxidation of liquid ortho-xylene
US4387243A (en) * 1979-06-20 1983-06-07 Standard Oil Company (Indiana) Continuous production of ortho-phthalic acid product by two-step catalytic neat oxidation of liquid ortho-xylene with air
NL7906575A (en) * 1979-09-01 1981-03-03 Stamicarbon PROCESS FOR PREPARING AROMATIC CARBONIC ACIDS.
US4233227A (en) * 1979-10-05 1980-11-11 Standard Oil Company (Indiana) Phthalic anhydride formation and separation
JPS5826899B2 (en) * 1979-11-28 1983-06-06 三菱瓦斯化学株式会社 Production method of trimellitic acid
US4895978A (en) * 1982-05-28 1990-01-23 Amoco Corporation Oxidation of pseudocumene to trimellitic acid enhanced by low gram atom ratios of zirconium to transition metal in oxidation catalyst system
US4816601A (en) * 1983-12-27 1989-03-28 Amoco Corporation Process for the manufacture of trimellitic acid
US4755622A (en) * 1983-12-29 1988-07-05 Amoco Corporation Process for the production of trimellitic acid and pyromellitic acid by staged bromine addition in an oxidation of polyalkylaromatics
DE3520841A1 (en) * 1985-04-26 1986-11-06 Rütgerswerke AG, 6000 Frankfurt Process for the oxidation of alkylaromatic compounds
US4764639A (en) * 1985-05-15 1988-08-16 Amoco Corporation Process for the production of trimellitic acid
US4754062A (en) * 1985-05-24 1988-06-28 Amoco Corporation Iron-enhanced selectivity of heavy metal-bromine catalysis in the oxidation of polyalkylaromatics
JPH0755917B2 (en) * 1985-05-30 1995-06-14 アモコ・コ−ポレ−シヨン Method for producing trimellitic anhydride and pyromellitic dianhydride
US4786753A (en) * 1987-05-18 1988-11-22 Amoco Corporation Oxidation process for the manufacture of aromatic acids from alkylaromatic compounds
JPH0515817Y2 (en) * 1988-07-12 1993-04-26
JPH0261279U (en) * 1988-10-28 1990-05-08
US5028737A (en) * 1990-02-22 1991-07-02 Amoco Corporation Preparation of isopropylidene bis(phthalic acid)
US5342968A (en) * 1990-06-22 1994-08-30 Amoco Corporation Process for producing sulfonylbis (phthalic anhydride)
JPH0618477U (en) * 1992-08-07 1994-03-11 株式会社イナックス Drain pipe mounting structure
DE4441881A1 (en) 1994-11-24 1996-05-30 Hoechst Ag Process for the production of brominated or chlorinated aromatic carboxylic acids
ES2104512B1 (en) * 1995-09-21 1998-07-01 Interquisa INDUSTRIAL PROCEDURE FOR THE MANUFACTURE OF AROMATIC CARBOXYL ACIDS.
IE970418A1 (en) * 1997-06-04 1998-12-16 Chemical Technologies And Know Process for production of aromatic tricarboxylic acids
US20020151745A1 (en) * 1999-05-10 2002-10-17 Kazuo Tanaka Process for producing pyromellitic acid
DE60009785T2 (en) * 1999-05-10 2004-08-19 Mitsubishi Gas Chemical Co., Inc. Process for the preparation of pyromellitic acid
MY123568A (en) 2000-06-09 2006-05-31 Mitsubishi Gas Chemical Co Process for producing trimellitec anhydride
JP4678081B2 (en) * 2000-06-09 2011-04-27 三菱瓦斯化学株式会社 Method for producing trimellitic acid
US6657068B2 (en) 2002-03-22 2003-12-02 General Electric Company Liquid phase oxidation of halogenated ortho-xylenes
US6649773B2 (en) 2002-03-22 2003-11-18 General Electric Company Method for the manufacture of halophthalic acids and anhydrides
US6657067B2 (en) 2002-03-22 2003-12-02 General Electric Company Method for the manufacture of chlorophthalic anhydride
US7541489B2 (en) 2004-06-30 2009-06-02 Sabic Innovative Plastics Ip B.V. Method of making halophthalic acids and halophthalic anhydrides
US20060205974A1 (en) * 2005-03-08 2006-09-14 Lavoie Gino G Processes for producing aromatic dicarboxylic acids
US7550627B2 (en) * 2005-03-08 2009-06-23 Eastman Chemical Company Processes for producing aromatic dicarboxylic acids
EP2111388A1 (en) * 2006-12-21 2009-10-28 E. I. Du Pont de Nemours and Company Process for the synthesis of halogenated aromatic diacids
US9212121B2 (en) 2013-09-24 2015-12-15 Eastman Chemical Company Processes for producing terephthalic acid
US9199906B2 (en) 2013-09-24 2015-12-01 Eastman Chemical Company Processes for producing isophthalic acid
CN114685280A (en) * 2022-01-25 2022-07-01 南昌大学 Preparation method of 3-nitrophthalic acid
CN114773368B (en) * 2022-05-06 2023-08-25 青岛大学 Boron-nitrogen organic small molecule and preparation method and application thereof

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB851562A (en) * 1958-05-19 1960-10-19 Ici Ltd Process for the production of terephthalic acid
NL140508C (en) * 1963-05-01
US3472900A (en) * 1966-07-18 1969-10-14 Baird Chem Ind Preparation of trialkylamines
US3562318A (en) * 1966-11-10 1971-02-09 Petro Tex Chem Corp Catalytic oxidation process of mono-aryl compounds
US3683016A (en) * 1970-04-24 1972-08-08 Standard Oil Co Staged catalyst addition for catalytic liquid phase oxidation of pseudocumene to trimellitic acid

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2081265A1 (en) * 1993-09-28 1996-02-16 Samsung General Chemicals Co Production method of high purity isomers of benzenedicarboxylic acids

Also Published As

Publication number Publication date
SU674667A3 (en) 1979-07-15
FR2240913A1 (en) 1975-03-14
US3920735A (en) 1975-11-18
YU141274A (en) 1982-06-18
DE2420960C2 (en) 1985-12-12
JPS5018434A (en) 1975-02-26
SE428559B (en) 1983-07-11
AR201586A1 (en) 1975-03-31
BR7404000D0 (en) 1974-12-03
PL94127B1 (en) 1977-07-30
NL7406166A (en) 1974-11-25
IN142878B (en) 1977-09-03
CA1020567A (en) 1977-11-08
IT1013188B (en) 1977-03-30
CS177176B2 (en) 1977-07-29
DD111896A5 (en) 1975-03-12
NL175908C (en) 1985-01-16
JPS5653531B2 (en) 1981-12-19
NL175908B (en) 1984-08-16
EG11167A (en) 1977-01-31
RO65801A (en) 1979-06-15
FR2240913B1 (en) 1978-01-13
BE814349A (en) 1974-10-29
TR17961A (en) 1976-07-23
BG22371A3 (en) 1977-02-20
HU174969B (en) 1980-04-28
GB1467886A (en) 1977-03-23
DE2420960A1 (en) 1974-12-12
HU176425B (en) 1981-02-28

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