ES398552A1 - Oxacylation of olefins in the gaseous phase - Google Patents

Oxacylation of olefins in the gaseous phase

Info

Publication number
ES398552A1
ES398552A1 ES398552A ES398552A ES398552A1 ES 398552 A1 ES398552 A1 ES 398552A1 ES 398552 A ES398552 A ES 398552A ES 398552 A ES398552 A ES 398552A ES 398552 A1 ES398552 A1 ES 398552A1
Authority
ES
Spain
Prior art keywords
olefins
oxacylation
gaseous phase
pore volume
total pore
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES398552A
Other languages
Spanish (es)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Farbwerke Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG, Farbwerke Hoechst AG filed Critical Hoechst AG
Publication of ES398552A1 publication Critical patent/ES398552A1/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
    • C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Procedure for the oxidation of olefins in the gas phase with the aid of support catalysts containing palladium compounds, with specific surfaces of between 40 and 350 m2/g and a total pore volume of between 0.4 and 1.2 ml/g, characterized by using a carrier that has, relative to the total pore volume, less than 10% of micropores with a diameter less than 30 Å. (Machine-translation by Google Translate, not legally binding)
ES398552A 1971-01-08 1972-01-03 Oxacylation of olefins in the gaseous phase Expired ES398552A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE2100778A DE2100778C3 (en) 1971-01-08 1971-01-08 Process for the preparation of the esters of unsaturated alcohols

Publications (1)

Publication Number Publication Date
ES398552A1 true ES398552A1 (en) 1974-08-16

Family

ID=5795437

Family Applications (1)

Application Number Title Priority Date Filing Date
ES398552A Expired ES398552A1 (en) 1971-01-08 1972-01-03 Oxacylation of olefins in the gaseous phase

Country Status (25)

Country Link
JP (1) JPS575215B1 (en)
AT (1) AT312571B (en)
AU (1) AU460233B2 (en)
BE (1) BE777880A (en)
BG (1) BG20080A3 (en)
BR (1) BR7200088D0 (en)
CA (1) CA934387A (en)
CH (1) CH555797A (en)
CS (1) CS176180B2 (en)
DE (1) DE2100778C3 (en)
EG (1) EG11829A (en)
ES (1) ES398552A1 (en)
FR (1) FR2121693B1 (en)
GB (1) GB1373272A (en)
HU (1) HU164760B (en)
IT (1) IT946346B (en)
LU (1) LU64557A1 (en)
NL (1) NL7200013A (en)
NO (1) NO136925C (en)
PL (1) PL82922B1 (en)
RO (1) RO58637A (en)
SE (1) SE392264B (en)
SU (1) SU510991A3 (en)
YU (1) YU35426B (en)
ZA (1) ZA7237B (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2315037C3 (en) * 1973-03-26 1978-03-09 Hoechst Ag, 6000 Frankfurt Process for the preparation of unsaturated esters of carboxylic acids
JP2530333B2 (en) * 1987-04-23 1996-09-04 三菱化学株式会社 Method for producing unsaturated glycol diester
CA2135021A1 (en) * 1993-11-19 1995-05-20 David J. Gulliver Process for the preparation of catalysts for use in the production of vinyl acetate
DE19843693A1 (en) * 1998-09-24 2000-03-30 Degussa Catalyst for vinyl acetate production from ethylene, acetic acid and oxygen contains palladium and other metals on a pyrogenic mixed oxide support based on silicon, aluminum, titanium and/or zirconium oxide
JP4969501B2 (en) * 2007-04-13 2012-07-04 昭和電工株式会社 Method for producing a catalyst for the production of allyl acetate
DE102007047430A1 (en) 2007-10-04 2009-04-09 Evonik Degussa Gmbh catalyst
WO2011104170A1 (en) 2010-02-24 2011-09-01 Evonik Degussa Gmbh Thermally and mechanically stable precious metal-loaded catalysts

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1236989A (en) * 1967-12-02 1971-06-23 Hoechst Ag Improvements in and relating to catalysts

Also Published As

Publication number Publication date
CS176180B2 (en) 1977-06-30
DE2100778A1 (en) 1972-07-20
FR2121693A1 (en) 1972-08-25
NO136925B (en) 1977-08-22
AU3754472A (en) 1973-07-05
BE777880A (en) 1972-07-10
GB1373272A (en) 1974-11-06
PL82922B1 (en) 1975-10-31
RO58637A (en) 1975-09-15
DE2100778C3 (en) 1978-07-13
SU510991A3 (en) 1976-04-15
AT312571B (en) 1974-01-10
IT946346B (en) 1973-05-21
YU330371A (en) 1980-06-30
ZA7237B (en) 1972-09-27
HU164760B (en) 1974-04-11
AU460233B2 (en) 1975-04-24
DE2100778B2 (en) 1977-11-17
SE392264B (en) 1977-03-21
EG11829A (en) 1978-06-30
BR7200088D0 (en) 1973-06-14
YU35426B (en) 1981-02-28
BG20080A3 (en) 1975-10-30
LU64557A1 (en) 1973-07-16
JPS575215B1 (en) 1982-01-29
FR2121693B1 (en) 1977-07-15
CA934387A (en) 1973-09-25
CH555797A (en) 1974-11-15
NO136925C (en) 1977-11-30
NL7200013A (en) 1972-07-11

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