ES379723A1 - Process for the manufacture of vinyl ester polymer dispersions - Google Patents
Process for the manufacture of vinyl ester polymer dispersionsInfo
- Publication number
- ES379723A1 ES379723A1 ES379723A ES379723A ES379723A1 ES 379723 A1 ES379723 A1 ES 379723A1 ES 379723 A ES379723 A ES 379723A ES 379723 A ES379723 A ES 379723A ES 379723 A1 ES379723 A1 ES 379723A1
- Authority
- ES
- Spain
- Prior art keywords
- weight
- monomers
- alcoholic
- methacrylic
- acrylic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F263/00—Macromolecular compounds obtained by polymerising monomers on to polymers of esters of unsaturated alcohols with saturated acids as defined in group C08F18/00
- C08F263/02—Macromolecular compounds obtained by polymerising monomers on to polymers of esters of unsaturated alcohols with saturated acids as defined in group C08F18/00 on to polymers of vinyl esters with monocarboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Process for the preparation of highly viscous and stable aqueous vinyl polyester dispersions with a particle size of 0.03 to 0.2 μ by radical polymerization in aqueous phase of straight or branched chain carboxylic acid vinyl esters with 2 to 18 carbon atoms and optionally other ethylenically unsaturated monomers up to a weight ratio of 60%, based on the total amount of monomers, at a temperature of 10 to 100ºC, in the presence of alcoholic polyoxides or derivatives of alcoholic polyoxide with 5 to 50 ethylene oxide units per molecule and optionally anionic emulsifiers, characterized in that 5 to 25% by weight, preferably 8 to 20% by weight of the total amount of monomers in the presence of the emulsifier solution, polymerize to a degree of transformation of at least 70% by weight of the previously disposed monomer and are then metered in Continue the remaining monomers and a mixture of 0.1 to 2% by weight of acrylic, methacrylic or crotonic acid as well as 0.1 to 2% by weight of acrylic, methacrylic or crotonic acid amide, always referring to the total weight of the vinyl polyester dispersion, such that the monomer content of the reaction mixture does not exceed 25% by weight, preferably 15% by weight, based on the reaction mixture. (Machine-translation by Google Translate, not legally binding)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19691925353 DE1925353C3 (en) | 1969-05-19 | 1969-05-19 | Process for the production of polyvinyl ester dispersions |
Publications (1)
Publication Number | Publication Date |
---|---|
ES379723A1 true ES379723A1 (en) | 1973-01-16 |
Family
ID=5734524
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES379723A Expired ES379723A1 (en) | 1969-05-19 | 1970-05-16 | Process for the manufacture of vinyl ester polymer dispersions |
Country Status (7)
Country | Link |
---|---|
JP (1) | JPS4837989B1 (en) |
BE (1) | BE750493A (en) |
DE (1) | DE1925353C3 (en) |
ES (1) | ES379723A1 (en) |
FR (1) | FR2047822A5 (en) |
GB (1) | GB1307890A (en) |
NL (1) | NL162093C (en) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
LU65552A1 (en) * | 1972-06-20 | 1973-12-27 | ||
JPS5120396U (en) * | 1974-08-01 | 1976-02-14 | ||
JPS6047315B2 (en) * | 1976-12-10 | 1985-10-21 | 住友化学工業株式会社 | New pressure sensitive adhesive |
JPS5721336U (en) * | 1980-07-09 | 1982-02-03 | ||
US4812510A (en) * | 1986-04-17 | 1989-03-14 | The Glidden Company | Small particle size latex based on vinyl acetate polymers |
GB2327087A (en) * | 1995-01-18 | 1999-01-13 | Gore & Ass | Dispersion of PTFE particles |
-
1969
- 1969-05-19 DE DE19691925353 patent/DE1925353C3/en not_active Expired
-
1970
- 1970-05-14 NL NL7007006A patent/NL162093C/en not_active IP Right Cessation
- 1970-05-15 FR FR7017804A patent/FR2047822A5/fr not_active Expired
- 1970-05-15 BE BE750493D patent/BE750493A/en unknown
- 1970-05-16 ES ES379723A patent/ES379723A1/en not_active Expired
- 1970-05-19 GB GB2422170A patent/GB1307890A/en not_active Expired
- 1970-05-19 JP JP4279270A patent/JPS4837989B1/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
DE1925353A1 (en) | 1970-11-26 |
NL162093B (en) | 1979-11-15 |
NL162093C (en) | 1980-04-15 |
NL7007006A (en) | 1970-11-23 |
JPS4837989B1 (en) | 1973-11-14 |
DE1925353C3 (en) | 1974-09-05 |
BE750493A (en) | 1970-11-16 |
FR2047822A5 (en) | 1971-03-12 |
DE1925353B2 (en) | 1974-01-24 |
GB1307890A (en) | 1973-02-21 |
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