ES376057A1 - Procedure for the manufacture of compounds containing phosphorus. (Machine-translation by Google Translate, not legally binding) - Google Patents
Procedure for the manufacture of compounds containing phosphorus. (Machine-translation by Google Translate, not legally binding)Info
- Publication number
- ES376057A1 ES376057A1 ES376057A ES376057A ES376057A1 ES 376057 A1 ES376057 A1 ES 376057A1 ES 376057 A ES376057 A ES 376057A ES 376057 A ES376057 A ES 376057A ES 376057 A1 ES376057 A1 ES 376057A1
- Authority
- ES
- Spain
- Prior art keywords
- compounds
- reaction
- general formula
- elements
- translation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001875 compounds Chemical class 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- 229910052698 phosphorus Inorganic materials 0.000 title 1
- 239000011574 phosphorus Substances 0.000 title 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 2
- CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 abstract 2
- -1 aryl alcohols Chemical class 0.000 abstract 2
- 238000009835 boiling Methods 0.000 abstract 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 2
- 229910052794 bromium Inorganic materials 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000000460 chlorine Substances 0.000 abstract 2
- 229910052801 chlorine Inorganic materials 0.000 abstract 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 2
- 150000003018 phosphorus compounds Chemical class 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 229910052787 antimony Inorganic materials 0.000 abstract 1
- 229910052785 arsenic Inorganic materials 0.000 abstract 1
- 150000005840 aryl radicals Chemical class 0.000 abstract 1
- 125000004429 atom Chemical group 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- 230000003247 decreasing effect Effects 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 abstract 1
- 229910000042 hydrogen bromide Inorganic materials 0.000 abstract 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 abstract 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 150000002894 organic compounds Chemical class 0.000 abstract 1
- 150000004831 organic oxygen compounds Chemical class 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
- 150000002989 phenols Chemical class 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
- 229910052717 sulfur Chemical group 0.000 abstract 1
- 239000011593 sulfur Chemical group 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/09—Esters of phosphoric acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/30—Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
- C07F9/32—Esters thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/46—Phosphinous acids [R2POH], [R2P(= O)H]: Thiophosphinous acids including[R2PSH]; [R2P(=S)H]; Aminophosphines [R2PNH2]; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/48—Phosphonous acids [RP(OH)2] including [RHP(=O)(OH)]; Thiophosphonous acids including [RP(SH)2], [RHP(=S)(SH)]; Derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Procedure for the preparation of phosphorous-containing compounds of the general formula **(See formula)** where A represents oxygen or sulfur, q and n each denoting 0 or 1, the three groups R1, R2 and R3 may be the same or different and each denoting an alcohol, cycloalkyl or aryl radical, and may be substituted by atoms of halogen in R1 a hydrogen atom or several hydrogen atoms by reaction of phosphorus compounds of the general formula **(See formula)** where a and q have the above meanings, Z and Y in each case signify chlorine, bromine, R1 or R2 or R10 or R20-, and X signifies chlorine or bromine, with organic compounds containing hydroxy groups of the general formula D - OH in which D means R1, R2 or R3, in the presence of catalysts and optionally organic solvents and with separation of hydrogen chloride or hydrogen bromide, characterized in that at the beginning of the reaction one works at temperatures between 0ºC and the points of boiling of the starting compounds, preferably at normal pressure, and in the course of the reaction, preferably after definitive mixing of all the participants in the reaction, the temperature is increased to the boiling point of the resulting product and is decreased to at the same time the pressure at 200 to 10 mm Hg, preferably at about 90 to 40 mm Hg, and as catalysts organic oxygen compounds of the elements of groups II IV or Y of the Periodic System of the Elements with numbers are used of order between 12 and 83, preferably of the elements Mg, Ca, Ti, Ge, Zr, V, As or Sb, and monovalent or polyvalent aryl alcohols, aliphatic alcohols cos or cycloaliphatic or phenols, in a concentration of 0.001 to 2% by weight, based on the amount of the corresponding phosphorus compounds. (Machine-translation by Google Translate, not legally binding)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19691905095 DE1905095A1 (en) | 1969-02-01 | 1969-02-01 | Process for the preparation of compounds containing phosphorus |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES376057A1 true ES376057A1 (en) | 1972-03-01 |
Family
ID=5724087
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES376057A Expired ES376057A1 (en) | 1969-02-01 | 1970-01-30 | Procedure for the manufacture of compounds containing phosphorus. (Machine-translation by Google Translate, not legally binding) |
Country Status (9)
| Country | Link |
|---|---|
| JP (1) | JPS519735B1 (en) |
| AU (1) | AU1092670A (en) |
| BE (1) | BE745090A (en) |
| CH (1) | CH541584A (en) |
| DE (1) | DE1905095A1 (en) |
| ES (1) | ES376057A1 (en) |
| FR (1) | FR2032672A5 (en) |
| LU (1) | LU60272A1 (en) |
| NL (1) | NL7001361A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19721347B9 (en) * | 1997-05-22 | 2005-09-29 | Celanese Chemicals Europe Gmbh | Process for the preparation of ester plasticizers |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3077491A (en) * | 1959-10-26 | 1963-02-12 | Fmc Corp | Preparation of triarylphosphates |
| GB1005710A (en) * | 1961-02-09 | 1965-09-29 | English Electric Co Ltd | Prevention of freezing in cooling towers |
| US3209021A (en) * | 1962-06-13 | 1965-09-28 | Monsanto Co | Process for preparing organo-phosphate esters |
| US3205251A (en) * | 1962-11-07 | 1965-09-07 | Monsanto Co | Process for preparing phosphate esters with a titanium trichloride catalyst |
| US3155710A (en) * | 1962-11-07 | 1964-11-03 | Monsanto Co | Process for preparing phosphate esters with a vanadium catalyst |
| GB1146173A (en) * | 1966-06-18 | 1969-03-19 | Geigy Uk Ltd | Production of triaryl phosphates |
-
1969
- 1969-02-01 DE DE19691905095 patent/DE1905095A1/en active Pending
-
1970
- 1970-01-27 CH CH116470A patent/CH541584A/en not_active IP Right Cessation
- 1970-01-28 BE BE745090D patent/BE745090A/en unknown
- 1970-01-30 LU LU60272D patent/LU60272A1/xx unknown
- 1970-01-30 ES ES376057A patent/ES376057A1/en not_active Expired
- 1970-01-30 FR FR7003416A patent/FR2032672A5/en not_active Expired
- 1970-01-30 NL NL7001361A patent/NL7001361A/xx unknown
- 1970-02-02 JP JP922670A patent/JPS519735B1/ja active Pending
- 1970-02-02 AU AU10926/70A patent/AU1092670A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DE1905095A1 (en) | 1970-08-13 |
| JPS519735B1 (en) | 1976-03-30 |
| BE745090A (en) | 1970-07-01 |
| CH541584A (en) | 1973-09-15 |
| LU60272A1 (en) | 1970-04-01 |
| FR2032672A5 (en) | 1970-11-27 |
| NL7001361A (en) | 1970-08-04 |
| AU1092670A (en) | 1971-08-05 |
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