ES367116A1 - A procedure for the preparation of substituted propylphosphonic acid esters. (Machine-translation by Google Translate, not legally binding) - Google Patents
A procedure for the preparation of substituted propylphosphonic acid esters. (Machine-translation by Google Translate, not legally binding)Info
- Publication number
- ES367116A1 ES367116A1 ES367116A ES367116A ES367116A1 ES 367116 A1 ES367116 A1 ES 367116A1 ES 367116 A ES367116 A ES 367116A ES 367116 A ES367116 A ES 367116A ES 367116 A1 ES367116 A1 ES 367116A1
- Authority
- ES
- Spain
- Prior art keywords
- substituted
- formula
- procedure
- aryl
- translation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title abstract 3
- NSETWVJZUWGCKE-UHFFFAOYSA-N propylphosphonic acid Chemical class CCCP(O)(O)=O NSETWVJZUWGCKE-UHFFFAOYSA-N 0.000 title abstract 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- 125000003342 alkenyl group Chemical group 0.000 abstract 2
- 125000000304 alkynyl group Chemical group 0.000 abstract 2
- 125000003710 aryl alkyl group Chemical class 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 125000005842 heteroatom Chemical group 0.000 abstract 2
- -1 mesyloxy, tosyloxy Chemical group 0.000 abstract 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 1
- 150000001342 alkaline earth metals Chemical class 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 abstract 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052794 bromium Chemical group 0.000 abstract 1
- 239000003638 chemical reducing agent Substances 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 125000001309 chloro group Chemical group Cl* 0.000 abstract 1
- 150000005690 diesters Chemical class 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 125000001072 heteroaryl group Chemical group 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 1
- 125000003107 substituted aryl group Chemical group 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- 239000011593 sulfur Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4006—Esters of acyclic acids which can have further substituents on alkyl
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
Abstract
A procedure for the preparation of substituted propylphosphonic acid esters of formula: **(See formula)** where R1 is brosyloxy, mesyloxy, tosyloxy, halogen, 0-aralkyl, O-substituted aralkyl, O-lower alkenyl, O-lower alkynyl, O-aryl, O-aryl, O-tolyl and amino; and R2 is lower alkyl, aralkyl, substituted benzyl, aryl, substituted aryl, heteroaryl from 1 to 3 heteroatoms in which each of the heteroatoms is sulfur, oxygen or nitrogen, lower alkenyl and infer alkynyl; whose procedure is to react a compound of formula: **(See formula)** where R1 is as defined above and X is chlorine and bromine, with a compound of the formula: **(See formula)** where R2 is as defined above and M is an alkali metal or an alkaline earth metal and reduce the diester of α-substituted propionylphosphonic acid formed as an intermediate with a reducing agent. (Machine-translation by Google Translate, not legally binding)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US72946568A | 1968-05-15 | 1968-05-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES367116A1 true ES367116A1 (en) | 1971-04-01 |
Family
ID=24931160
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES367116A Expired ES367116A1 (en) | 1968-05-15 | 1969-05-12 | A procedure for the preparation of substituted propylphosphonic acid esters. (Machine-translation by Google Translate, not legally binding) |
Country Status (7)
| Country | Link |
|---|---|
| BE (1) | BE733058A (en) |
| BR (1) | BR6908791D0 (en) |
| CH (1) | CH523287A (en) |
| DE (1) | DE1924104A1 (en) |
| ES (1) | ES367116A1 (en) |
| IL (1) | IL32137A0 (en) |
| NL (1) | NL6905272A (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4206156A (en) * | 1976-07-27 | 1980-06-03 | Fujisawa Pharmaceutical Company, Limited | Hydroxyaminohydrocarbonphosphonic acids |
| GB1580899A (en) | 1976-07-27 | 1980-12-10 | Fujisawa Pharmaceutical Co | Hydroxyaminohydrocarbonphosphonic acid derivatives and production and use thereof |
| DE3130433A1 (en) * | 1981-07-31 | 1983-02-17 | Bayer Ag, 5090 Leverkusen | METHOD FOR PRODUCING (ALPHA) -HYDROXY-PHOSPHONIC ACID |
-
1969
- 1969-04-03 NL NL6905272A patent/NL6905272A/xx unknown
- 1969-05-01 IL IL32137A patent/IL32137A0/en unknown
- 1969-05-06 CH CH688769A patent/CH523287A/en not_active IP Right Cessation
- 1969-05-12 ES ES367116A patent/ES367116A1/en not_active Expired
- 1969-05-12 DE DE19691924104 patent/DE1924104A1/en active Pending
- 1969-05-14 BR BR208791/69A patent/BR6908791D0/en unknown
- 1969-05-14 BE BE733058D patent/BE733058A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CH523287A (en) | 1972-05-31 |
| NL6905272A (en) | 1969-11-18 |
| BE733058A (en) | 1969-11-14 |
| IL32137A0 (en) | 1969-07-30 |
| BR6908791D0 (en) | 1973-03-15 |
| DE1924104A1 (en) | 1970-01-15 |
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