ES365184A1 - Phenylacetic acid and its esters - Google Patents
Phenylacetic acid and its estersInfo
- Publication number
- ES365184A1 ES365184A1 ES365184A ES365184A ES365184A1 ES 365184 A1 ES365184 A1 ES 365184A1 ES 365184 A ES365184 A ES 365184A ES 365184 A ES365184 A ES 365184A ES 365184 A1 ES365184 A1 ES 365184A1
- Authority
- ES
- Spain
- Prior art keywords
- phenylacetic acid
- prepared
- esters
- acid
- methyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Phenylacetic acid or an ester thereof is prepared by reacting benzyl chloride with carbon monoxide and with a hydroxy compound ROH, wherein R is a hydrogen atom of a hydrocarbyl C 1-12 radical, in the presence of a catalytic system formed of nickel carbonyl and bromide or iodide ions in solution in a basic polar solvent e.g. DMF, DMSO, hexamethyl-phosphor-triamide or tetra methyl urea, preferably in the presence of an acid binding agent e.g. MgO, CaO, MgCO 3 and CaCO 3 . In examples phenylacetic acid and its methyl, amyl, phenyl esters are prepared benzyl phenyl acetate is formed as a by-product.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT1435968 | 1968-03-25 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES365184A1 true ES365184A1 (en) | 1971-01-01 |
Family
ID=11145004
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES365184A Expired ES365184A1 (en) | 1968-03-25 | 1969-03-24 | Phenylacetic acid and its esters |
Country Status (6)
Country | Link |
---|---|
BE (1) | BE730379A (en) |
DE (1) | DE1914391A1 (en) |
ES (1) | ES365184A1 (en) |
FR (1) | FR2004634A1 (en) |
GB (1) | GB1245029A (en) |
NL (1) | NL6904128A (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3974202A (en) * | 1972-08-17 | 1976-08-10 | Dynamit Nobel Aktiengesellschaft | Method of preparing arylacetic acid alkyl esters |
IT1076234B (en) | 1977-01-18 | 1985-04-27 | Montedison Spa | PHENYLACETIC ACID PREPARATION PROCESS |
DE10057262A1 (en) * | 2000-11-18 | 2002-05-23 | Clariant Gmbh | Process for the preparation of phenylacetic acid derivatives |
EP2863087B1 (en) | 2013-10-16 | 2018-03-07 | Contitech France | Airspring with sliding sheet |
-
1969
- 1969-03-18 NL NL6904128A patent/NL6904128A/xx unknown
- 1969-03-21 FR FR6908286A patent/FR2004634A1/fr not_active Withdrawn
- 1969-03-21 DE DE19691914391 patent/DE1914391A1/en active Pending
- 1969-03-24 GB GB1525269A patent/GB1245029A/en not_active Expired
- 1969-03-24 BE BE730379D patent/BE730379A/xx not_active IP Right Cessation
- 1969-03-24 ES ES365184A patent/ES365184A1/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
BE730379A (en) | 1969-09-24 |
GB1245029A (en) | 1971-09-02 |
FR2004634A1 (en) | 1969-11-28 |
DE1914391A1 (en) | 1969-10-23 |
NL6904128A (en) | 1969-09-29 |
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