ES358358A1 - Procedimiento para la separacion de productos de desinte- gracion de delta4,20,22-bufatrienolidos. - Google Patents
Procedimiento para la separacion de productos de desinte- gracion de delta4,20,22-bufatrienolidos.Info
- Publication number
- ES358358A1 ES358358A1 ES358358A ES358358A ES358358A1 ES 358358 A1 ES358358 A1 ES 358358A1 ES 358358 A ES358358 A ES 358358A ES 358358 A ES358358 A ES 358358A ES 358358 A1 ES358358 A1 ES 358358A1
- Authority
- ES
- Spain
- Prior art keywords
- bufatrienolide
- dihydroxy
- compounds
- vii
- yields
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000926 separation method Methods 0.000 title abstract 2
- 230000007062 hydrolysis Effects 0.000 title 1
- 238000006460 hydrolysis reaction Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 150000001875 compounds Chemical class 0.000 abstract 4
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 abstract 3
- 238000005903 acid hydrolysis reaction Methods 0.000 abstract 2
- OVUOVMIMOCJILI-KFZANIOBSA-N scillarenin Chemical compound C=1([C@H]2CC[C@]3(O)[C@H]4[C@@H]([C@]5(CC[C@H](O)C=C5CC4)C)CC[C@@]32C)C=CC(=O)OC=1 OVUOVMIMOCJILI-KFZANIOBSA-N 0.000 abstract 2
- OVUOVMIMOCJILI-UHFFFAOYSA-N 3alpha-Scillarenin Natural products CC12CCC(C3(CCC(O)C=C3CC3)C)C3C1(O)CCC2C=1C=CC(=O)OC=1 OVUOVMIMOCJILI-UHFFFAOYSA-N 0.000 abstract 1
- TWCMVXMQHSVIOJ-UHFFFAOYSA-N Aglycone of yadanzioside D Natural products COC(=O)C12OCC34C(CC5C(=CC(O)C(O)C5(C)C3C(O)C1O)C)OC(=O)C(OC(=O)C)C24 TWCMVXMQHSVIOJ-UHFFFAOYSA-N 0.000 abstract 1
- PLMKQQMDOMTZGG-UHFFFAOYSA-N Astrantiagenin E-methylester Natural products CC12CCC(O)C(C)(CO)C1CCC1(C)C2CC=C2C3CC(C)(C)CCC3(C(=O)OC)CCC21C PLMKQQMDOMTZGG-UHFFFAOYSA-N 0.000 abstract 1
- MYEJFUXQJGHEQK-ALRJYLEOSA-N Proscillaridin Chemical compound O[C@@H]1[C@H](O)[C@@H](O)[C@H](C)O[C@H]1O[C@@H]1C=C2CC[C@H]3[C@@]4(O)CC[C@H](C5=COC(=O)C=C5)[C@@]4(C)CC[C@@H]3[C@@]2(C)CC1 MYEJFUXQJGHEQK-ALRJYLEOSA-N 0.000 abstract 1
- WETWJCDKMRHUPV-UHFFFAOYSA-N acetyl chloride Chemical compound CC(Cl)=O WETWJCDKMRHUPV-UHFFFAOYSA-N 0.000 abstract 1
- 239000012346 acetyl chloride Substances 0.000 abstract 1
- 230000021736 acetylation Effects 0.000 abstract 1
- 238000006640 acetylation reaction Methods 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 230000032050 esterification Effects 0.000 abstract 1
- 238000005886 esterification reaction Methods 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- PFOARMALXZGCHY-UHFFFAOYSA-N homoegonol Natural products C1=C(OC)C(OC)=CC=C1C1=CC2=CC(CCCO)=CC(OC)=C2O1 PFOARMALXZGCHY-UHFFFAOYSA-N 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229930190098 proscillaridin Natural products 0.000 abstract 1
- 229960003584 proscillaridin Drugs 0.000 abstract 1
- MYEJFUXQJGHEQK-UHFFFAOYSA-N proscillaridin A Natural products OC1C(O)C(O)C(C)OC1OC1C=C2CCC3C4(O)CCC(C5=COC(=O)C=C5)C4(C)CCC3C2(C)CC1 MYEJFUXQJGHEQK-UHFFFAOYSA-N 0.000 abstract 1
- 238000010898 silica gel chromatography Methods 0.000 abstract 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19671668337 DE1668337A1 (de) | 1967-09-21 | 1967-09-21 | Abbauprodukte scillareninhaltiger Bufadienolide und Verfahren zu deren Trennung |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES358358A1 true ES358358A1 (es) | 1970-06-16 |
Family
ID=5686095
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES358358A Expired ES358358A1 (es) | 1967-09-21 | 1968-09-20 | Procedimiento para la separacion de productos de desinte- gracion de delta4,20,22-bufatrienolidos. |
Country Status (6)
| Country | Link |
|---|---|
| AT (1) | AT298687B (es) |
| BE (1) | BE721153A (es) |
| CH (1) | CH549005A (es) |
| ES (1) | ES358358A1 (es) |
| FR (1) | FR1591088A (es) |
| GB (1) | GB1193789A (es) |
-
1968
- 1968-09-11 GB GB4309868A patent/GB1193789A/en not_active Expired
- 1968-09-20 FR FR1591088D patent/FR1591088A/fr not_active Expired
- 1968-09-20 CH CH1411768A patent/CH549005A/de not_active IP Right Cessation
- 1968-09-20 ES ES358358A patent/ES358358A1/es not_active Expired
- 1968-09-20 BE BE721153D patent/BE721153A/xx unknown
- 1968-09-27 AT AT907268A patent/AT298687B/de not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| GB1193789A (en) | 1970-06-03 |
| AT298687B (de) | 1972-04-15 |
| BE721153A (es) | 1969-03-20 |
| CH549005A (de) | 1974-05-15 |
| FR1591088A (es) | 1970-04-27 |
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