ES353310A1 - Self-bulking conjugate filaments - Google Patents
Self-bulking conjugate filamentsInfo
- Publication number
- ES353310A1 ES353310A1 ES353310A ES353310A ES353310A1 ES 353310 A1 ES353310 A1 ES 353310A1 ES 353310 A ES353310 A ES 353310A ES 353310 A ES353310 A ES 353310A ES 353310 A1 ES353310 A1 ES 353310A1
- Authority
- ES
- Spain
- Prior art keywords
- filaments
- components
- ethylene
- homopolymer
- copolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/06—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S264/00—Plastic and nonmetallic article shaping or treating: processes
- Y10S264/26—Composite fibers made of two or more materials
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2922—Nonlinear [e.g., crimped, coiled, etc.]
- Y10T428/2924—Composite
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2964—Artificial fiber or filament
- Y10T428/2967—Synthetic resin or polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2973—Particular cross section
Abstract
A conjugate filament comprises at least two components, one of said components being polypropylene homopolymer having a density of at least 0À88 and the or each other of said components being a copolymer of propylene and up to 25% of a second alpha-olefin having 2 to 6 carbon atoms, the or each said copolymer having a density of at least 0À88. A copolymer component may be either a random copolymer containing 2 to 5% ethylene, or a block copolymer containing 3 to 25% ethylene. The components of the filaments may be disposed in side-by-side or in sheath-and-core relationship, the former being preferred. The ratio of the components in the conjugate filaments can vary from about 1: 4 to 4: 1, but generally the filaments will be comprised of about equal portions of each component. After spinning through a suitable spinneret, the orienting draw is conducted at a temperature below the melting point of the polypropylene in order to develop the optimum properties of the filaments at above the temperature at which either of the components forms voids. Preferably, the drawing temperature will be between about 80 and 110 C. A draw to a draw ratio of at least 2À5 is required to produce sufficient shrinkage to result in useful crimped filaments. In some cases, the stretched filaments crimp spontaneously as soon as the stress imposed by the drawing operation is relaxed. In other cases, the crimp is developed by applying heat to the filaments in a relaxed state, causing the same to shrink, bringing the differential shrinkage effect into play. Such heat treatment is preferably effected in a batch operation, as with boiling water or an oven, at a temperature above that where the copolymer component shrinks, but below that at which substantial shrinkage of the homopolymer component takes place. Normally this will be between about 90 and 150 C. The specific temperature selected is also dependent upon the ethylene content of the copolymer component, higher temperatures being preferred at the lower levels of ethylene content. Heat treatment is preferably carried out for about 0À2 to 10 minutes. The heat treatment may also be effected continuously by bringing the yarn, moving suitably at 100 to 1000 metres per minute, into contact with a hot plate or through a heated zone. In such continuous operation, treatment times of the order of 0À01 second to about 1 minute are employed, and the heat source or zone can be at a temperature as high as 300 C. Filaments so made have a crimp frequency of about 5 to 100 crimps per inch. In Example 1, a conjugate filament yarn is spun from propylene homopolymer and a random copolymer of ethylene and propylene containing about 2À4% ethylene, the components being disposed in side-by-side relationship. Spinning is effected at 250 C. at a linear rate of 665 metres per minute to form a spun yarn which is drawn about 3À5 times at about 100 C. and develops crimps on subsequent heating in the tensionfree state by placing a skein of the same on a metal grating in an oven at 125 C. for two minutes. In example 2, example 1 is repeated, using the same homopolymer in combination with an end block copolymer containing about 25 % ethylene. The resulting yarn is heat treated in boiling water for five minutes to develop the crimp. In Example 3, the same homopolymer as before is used with a 3-block copolymer containing 3% ethylene. In further experiments the same homopolymer is used with a random copolymer of propylene and about 3À2% butene- 1. The resulting yarn is heat-treated at 125 C. for 5 minutes to develop the crimp. Filaments having more than two components, e.g. a homopolymer and two copolymer components, may be made, and conjugate filaments may also be prepared with polypropylene in one component and a mixture of copolymers in the other components, e.g., a mixture of ethylene-propylene and butene-propylene copolymers.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US64820767A | 1967-06-23 | 1967-06-23 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES353310A1 true ES353310A1 (en) | 1969-08-16 |
Family
ID=24599846
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES353310A Expired ES353310A1 (en) | 1967-06-23 | 1968-04-29 | Self-bulking conjugate filaments |
Country Status (7)
Country | Link |
---|---|
US (1) | US3505164A (en) |
BE (1) | BE717000A (en) |
DE (1) | DE1769329A1 (en) |
ES (1) | ES353310A1 (en) |
FR (1) | FR1570262A (en) |
GB (1) | GB1171274A (en) |
NL (1) | NL6808780A (en) |
Families Citing this family (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3900678A (en) * | 1965-10-23 | 1975-08-19 | Asahi Chemical Ind | Composite filaments and process for the production thereof |
US3604196A (en) * | 1969-07-10 | 1971-09-14 | Allied Chem | Method of making latently crimpable yarn from polyblend and product |
US3900680A (en) * | 1972-03-08 | 1975-08-19 | Goodyear Tire & Rubber | Cord for extensible belt |
US4189338A (en) * | 1972-11-25 | 1980-02-19 | Chisso Corporation | Method of forming autogenously bonded non-woven fabric comprising bi-component fibers |
JPS5212830B2 (en) * | 1972-11-25 | 1977-04-09 | ||
NZ185412A (en) * | 1976-10-20 | 1980-03-05 | Chisso Corp | Heat-adhesive compsite fibres based on propylene |
US4115620A (en) * | 1977-01-19 | 1978-09-19 | Hercules Incorporated | Conjugate filaments |
JPS53147816A (en) * | 1977-05-24 | 1978-12-22 | Chisso Corp | Hot-melt fiber of polypropylene |
JPS5584420A (en) * | 1978-12-20 | 1980-06-25 | Chisso Corp | Method of making side by side conjugate fiber with no crimp |
DE3027835A1 (en) * | 1980-07-23 | 1982-03-04 | Gretsch-Unitas Gmbh Baubeschlagfabrik, 7257 Ditzingen | OPTIONAL TILT OR PARALLEL DETACHABLE LEAF OF A WINDOW, DOOR OR THE LIKE. |
CS237872B1 (en) * | 1983-06-09 | 1985-11-13 | Rudolf Simo | Cigarette filtration stick filling and method of this filling making |
DE3323109A1 (en) * | 1983-06-27 | 1985-01-03 | Lentia GmbH Chem. u. pharm. Erzeugnisse - Industriebedarf, 8000 München | MONOAXIAL STRETCHED TAPES MADE OF POLYPROPYLENE OR PROPYLENE-AETHYLENE COPOLYMERS |
DE3813773A1 (en) * | 1988-04-23 | 1989-11-02 | Henkel Kgaa | DETERGENT PRODUCTS |
JPH0598165A (en) * | 1990-01-02 | 1993-04-20 | Hercules Inc | Pavement composition of fiber-reinforced asphalt type and preparation thereof |
FI112252B (en) * | 1990-02-05 | 2003-11-14 | Fibervisions L P | High temperature resistant fiber bindings |
DE69324280T2 (en) * | 1992-01-13 | 1999-08-12 | Hercules Inc | Heat-bondable fibers for resistant nonwovens |
SG50447A1 (en) * | 1993-06-24 | 1998-07-20 | Hercules Inc | Skin-core high thermal bond strength fiber on melt spin system |
DE4321560A1 (en) * | 1993-06-29 | 1995-01-12 | Danubia Petrochem Deutschland | Polyolefin yarn and fabric |
JP3569972B2 (en) * | 1994-08-11 | 2004-09-29 | チッソ株式会社 | Heat-fusible composite fiber and heat-fusible nonwoven fabric |
DK0719879T3 (en) * | 1994-12-19 | 2000-09-18 | Fibervisions L P | Process for producing fibers for high strength nonwoven materials and the resulting fibers and nonwoven fabrics |
AU2002226738B9 (en) * | 2001-01-29 | 2007-04-05 | Mitsui Chemicals, Inc. | Non-woven fabrics of wind-shrink fiber and laminates thereof |
AU2006202427A1 (en) * | 2005-07-13 | 2007-02-01 | Tyco Healthcare Group Lp | Monofilament sutures made from a composition containing ultra high molecular weight polyethylene |
DK2343406T3 (en) * | 2008-10-29 | 2014-01-20 | Mitsui Chemicals Inc | Shrinked composite fiber and nonwoven fabric comprising the fiber |
US9163334B1 (en) | 2011-11-23 | 2015-10-20 | The United States Of America As Represented By The Secretary Of The Army | Actuators based on unbalanced moments of inertia |
US10252456B1 (en) | 2011-11-23 | 2019-04-09 | The United States Of America, As Represented By The Secretary Of The Army | Method of making actuators based on unbalanced moments of inertia |
CN107502984B (en) * | 2017-08-23 | 2019-11-29 | 常州灵达特种纤维有限公司 | The preparation method of soft highlight type polypropylene fiber bulked yarn |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL50503C (en) * | 1937-04-22 | |||
FR1124921A (en) * | 1954-02-26 | 1956-10-22 | Du Pont | Textile materials and their production process |
US2912424A (en) * | 1955-11-29 | 1959-11-10 | Eastman Kodak Co | Polymerization of alpha-olefins to solid polymers with catalytic mixtures of aluminum metal, a titanium compound and a tetra substituted ammonium salt |
FR1354058A (en) * | 1962-04-30 | 1964-02-28 | Monsanto Chemicals | Synthetic textile fiber enhancements |
US3268624A (en) * | 1962-11-29 | 1966-08-23 | Avisun Corp | Block copolymers of ethylene and propylene |
US3315021A (en) * | 1964-06-19 | 1967-04-18 | Snia Viscosa | Process for the production of crimpable composite synthetic yarns |
-
1967
- 1967-06-23 US US648207A patent/US3505164A/en not_active Expired - Lifetime
-
1968
- 1968-04-29 ES ES353310A patent/ES353310A1/en not_active Expired
- 1968-05-03 GB GB21194/68A patent/GB1171274A/en not_active Expired
- 1968-05-09 DE DE19681769329 patent/DE1769329A1/en active Pending
- 1968-06-12 FR FR1570262D patent/FR1570262A/fr not_active Expired
- 1968-06-21 NL NL6808780A patent/NL6808780A/xx unknown
- 1968-06-21 BE BE717000D patent/BE717000A/xx unknown
Also Published As
Publication number | Publication date |
---|---|
FR1570262A (en) | 1969-06-06 |
DE1769329A1 (en) | 1971-11-18 |
BE717000A (en) | 1968-12-23 |
GB1171274A (en) | 1969-11-19 |
NL6808780A (en) | 1968-12-24 |
US3505164A (en) | 1970-04-07 |
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