ES342144A1 - Organo-Antimony-Tin Compounds - Google Patents
Organo-Antimony-Tin CompoundsInfo
- Publication number
- ES342144A1 ES342144A1 ES342144A ES342144A ES342144A1 ES 342144 A1 ES342144 A1 ES 342144A1 ES 342144 A ES342144 A ES 342144A ES 342144 A ES342144 A ES 342144A ES 342144 A1 ES342144 A1 ES 342144A1
- Authority
- ES
- Spain
- Prior art keywords
- acid
- atom
- compounds
- antimony
- linked
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 mercapto compounds Chemical class 0.000 abstract 3
- 125000000962 organic group Chemical group 0.000 abstract 3
- 125000004434 sulfur atom Chemical group 0.000 abstract 3
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 abstract 2
- 239000003513 alkali Substances 0.000 abstract 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 abstract 2
- 239000003125 aqueous solvent Substances 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- QRMMMWOSHHVOCJ-UHFFFAOYSA-N 2,2-dimethylheptanoic acid Chemical compound CCCCCC(C)(C)C(O)=O QRMMMWOSHHVOCJ-UHFFFAOYSA-N 0.000 abstract 1
- PSYGHMBJXWRQFD-UHFFFAOYSA-N 2-(2-sulfanylacetyl)oxyethyl 2-sulfanylacetate Chemical compound SCC(=O)OCCOC(=O)CS PSYGHMBJXWRQFD-UHFFFAOYSA-N 0.000 abstract 1
- OEOIWYCWCDBOPA-UHFFFAOYSA-N 6-methyl-heptanoic acid Chemical compound CC(C)CCCCC(O)=O OEOIWYCWCDBOPA-UHFFFAOYSA-N 0.000 abstract 1
- RZBBHEJLECUBJT-UHFFFAOYSA-N 6-methylheptyl 2-sulfanylacetate Chemical compound CC(C)CCCCCOC(=O)CS RZBBHEJLECUBJT-UHFFFAOYSA-N 0.000 abstract 1
- ZDUAIORLKPNXNS-UHFFFAOYSA-N C(CS)(=O)O.C(CCCCCC(C)C)(=O)O Chemical compound C(CS)(=O)O.C(CCCCCC(C)C)(=O)O ZDUAIORLKPNXNS-UHFFFAOYSA-N 0.000 abstract 1
- SUZILOGKFMVOEN-XBOSCTMBSA-L C(\C=C/C(=O)O)(=O)O.C(CCC)[Sn](CCCC)(Cl)Cl Chemical compound C(\C=C/C(=O)O)(=O)O.C(CCC)[Sn](CCCC)(Cl)Cl SUZILOGKFMVOEN-XBOSCTMBSA-L 0.000 abstract 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 abstract 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000004703 alkoxides Chemical class 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- CWERGRDVMFNCDR-UHFFFAOYSA-N alpha-mercaptoacetic acid Natural products OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052787 antimony Inorganic materials 0.000 abstract 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 abstract 1
- 230000001588 bifunctional effect Effects 0.000 abstract 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 1
- JGFBRKRYDCGYKD-UHFFFAOYSA-N dibutyl(oxo)tin Chemical compound CCCC[Sn](=O)CCCC JGFBRKRYDCGYKD-UHFFFAOYSA-N 0.000 abstract 1
- LQRUPWUPINJLMU-UHFFFAOYSA-N dioctyl(oxo)tin Chemical compound CCCCCCCC[Sn](=O)CCCCCCCC LQRUPWUPINJLMU-UHFFFAOYSA-N 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 abstract 1
- 229910001887 tin oxide Inorganic materials 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/22—Tin compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/90—Antimony compounds
- C07F9/902—Compounds without antimony-carbon linkages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/59—Arsenic- or antimony-containing compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Organo-antimony-tin compounds are made by reacting at least two mercapto compounds, at least one of which is bifunctional (SH/SH or SH/CO 2 H) with either: (1) dialkyl tin oxide or alkoxide and antimony trioxide with or without an aliphatic carboxylic acid (C 4 or more) or (2) dialkyl tin dihalide and antimony trihalide in presence of an alkali, with or without an alkali derivative of an aliphatic carboxylic acid (C 4 or more). Reaction in either case is effected by heating in presence of a non-aqueous solvent with continuous removal of the water produced in the reaction, and with final removal of the non-aqueous solvent. Typical compounds are: where R1 is an organic group (which may contain Sn and/or Sb) linked to Sn via a -CO 2 H or -SH group and is the radical of a mercaptan or a carboxylic acid as defined R2 is alkyl, R3 and R4 are organic groups linked to the S atom via a C atom and are, together with the S atom, radicals of mercapto compounds, and R5 is an organic group (which may contain Sn and/or Sb) linked to the S atom via a C atom. Specified starting materials are dibutyl tin oxide, dioctyl tin oxide, and dibutyl tin dichloride maleic acid, [alpha]-ethyl hexyl acid, 2,2-dimethyl heptanic acid, isooctanoic acid, and isononanoic acid thioglycolic acid, #- mercapto-propionic acid, thioglycolic acid isooctyl ester, thioglycolic acid lauryl ester and ethylene glycol dithioglycolate. The compounds are used as polymer stabilizers (Division C3).
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEC0039505 | 1966-07-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES342144A1 true ES342144A1 (en) | 1968-07-16 |
Family
ID=7023758
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES342144A Expired ES342144A1 (en) | 1966-07-01 | 1967-06-21 | Organo-Antimony-Tin Compounds |
Country Status (6)
| Country | Link |
|---|---|
| AT (1) | AT270234B (en) |
| BE (1) | BE691039A (en) |
| DE (1) | DE1568297A1 (en) |
| ES (1) | ES342144A1 (en) |
| GB (1) | GB1194414A (en) |
| NL (1) | NL6703880A (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0031295B1 (en) * | 1979-11-08 | 1983-05-18 | Ciba-Geigy Ag | Organic antimony-sulphur compounds, their use as stabilisers in chloric thermoplastics, and thermoplastics so stabilised |
| US4988750A (en) * | 1981-07-17 | 1991-01-29 | Schering Ag | Non-toxic stabilizer for halogenated polymer |
| CN106188144B (en) * | 2016-07-20 | 2018-12-25 | 浙江海普顿新材料股份有限公司 | A kind of liquid organotin antimonial and its preparation method and application |
-
1966
- 1966-07-01 DE DE19661568297 patent/DE1568297A1/en active Pending
- 1966-12-12 BE BE691039D patent/BE691039A/xx unknown
-
1967
- 1967-02-21 AT AT169367A patent/AT270234B/en active
- 1967-03-15 NL NL6703880A patent/NL6703880A/xx unknown
- 1967-06-07 GB GB2623567A patent/GB1194414A/en not_active Expired
- 1967-06-21 ES ES342144A patent/ES342144A1/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| GB1194414A (en) | 1970-06-10 |
| AT270234B (en) | 1969-04-25 |
| DE1568297A1 (en) | 1970-01-02 |
| NL6703880A (en) | 1968-01-02 |
| BE691039A (en) | 1967-05-16 |
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