ES340481A1 - Preparation of printing plates employing organic polymerizable photoconductor - Google Patents
Preparation of printing plates employing organic polymerizable photoconductorInfo
- Publication number
- ES340481A1 ES340481A1 ES340481A ES340481A ES340481A1 ES 340481 A1 ES340481 A1 ES 340481A1 ES 340481 A ES340481 A ES 340481A ES 340481 A ES340481 A ES 340481A ES 340481 A1 ES340481 A1 ES 340481A1
- Authority
- ES
- Spain
- Prior art keywords
- vinyl
- photo
- printing plates
- developer
- peroxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- 239000007788 liquid Substances 0.000 abstract 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- -1 azoisobutyronitrile Chemical compound 0.000 abstract 2
- 239000004020 conductor Substances 0.000 abstract 2
- 238000010438 heat treatment Methods 0.000 abstract 2
- 229920005989 resin Polymers 0.000 abstract 2
- 239000011347 resin Substances 0.000 abstract 2
- BOOBDAVNHSOIDB-UHFFFAOYSA-N (2,3-dichlorobenzoyl) 2,3-dichlorobenzenecarboperoxoate Chemical compound ClC1=CC=CC(C(=O)OOC(=O)C=2C(=C(Cl)C=CC=2)Cl)=C1Cl BOOBDAVNHSOIDB-UHFFFAOYSA-N 0.000 abstract 1
- KRMMZNOTUOIFQX-UHFFFAOYSA-N 1,1,2,2-tetraphenylhydrazine Chemical compound C1=CC=CC=C1N(C=1C=CC=CC=1)N(C=1C=CC=CC=1)C1=CC=CC=C1 KRMMZNOTUOIFQX-UHFFFAOYSA-N 0.000 abstract 1
- ALJVFDIHBBRASK-UHFFFAOYSA-N 1-[3,5-bis[4-(diethylamino)phenyl]-1,2,4-triazol-4-yl]ethanol Chemical compound OC(C)N1C(=NN=C1C1=CC=C(C=C1)N(CC)CC)C1=CC=C(C=C1)N(CC)CC ALJVFDIHBBRASK-UHFFFAOYSA-N 0.000 abstract 1
- UCVSGJVQGIBHQA-UHFFFAOYSA-N 1-ethenyldibenzofuran Chemical class O1C2=CC=CC=C2C2=C1C=CC=C2C=C UCVSGJVQGIBHQA-UHFFFAOYSA-N 0.000 abstract 1
- GIVBQSUFWURSOS-UHFFFAOYSA-N 1-ethenyltriazole Chemical class C=CN1C=CN=N1 GIVBQSUFWURSOS-UHFFFAOYSA-N 0.000 abstract 1
- MKTOIPPVFPJEQO-UHFFFAOYSA-N 4-(3-carboxypropanoylperoxy)-4-oxobutanoic acid Chemical compound OC(=O)CCC(=O)OOC(=O)CCC(O)=O MKTOIPPVFPJEQO-UHFFFAOYSA-N 0.000 abstract 1
- JJQOKUCYWIGCIN-UHFFFAOYSA-N 4-[4-(2-chlorophenyl)-2-ethenyl-1,3-oxazol-5-yl]-n,n-diethylaniline Chemical compound C1=CC(N(CC)CC)=CC=C1C1=C(C=2C(=CC=CC=2)Cl)N=C(C=C)O1 JJQOKUCYWIGCIN-UHFFFAOYSA-N 0.000 abstract 1
- UQRJMUPLHTXTKM-UHFFFAOYSA-N 9-(2-methylprop-1-enyl)carbazole Chemical compound C1=CC=C2N(C=C(C)C)C3=CC=CC=C3C2=C1 UQRJMUPLHTXTKM-UHFFFAOYSA-N 0.000 abstract 1
- 239000004342 Benzoyl peroxide Substances 0.000 abstract 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 abstract 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 1
- 239000004793 Polystyrene Substances 0.000 abstract 1
- 239000004115 Sodium Silicate Substances 0.000 abstract 1
- PJANXHGTPQOBST-VAWYXSNFSA-N Stilbene Natural products C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 abstract 1
- SAQSTQBVENFSKT-UHFFFAOYSA-M TCA-sodium Chemical compound [Na+].[O-]C(=O)C(Cl)(Cl)Cl SAQSTQBVENFSKT-UHFFFAOYSA-M 0.000 abstract 1
- CXNAFLUSDQQXCP-UHFFFAOYSA-N [(2-diazonioimino-1,2-diphenylethylidene)hydrazinylidene]azanide Chemical compound C=1C=CC=CC=1C(=NN=[N-])C(=N[N+]#N)C1=CC=CC=C1 CXNAFLUSDQQXCP-UHFFFAOYSA-N 0.000 abstract 1
- 125000004054 acenaphthylenyl group Chemical group C1(=CC2=CC=CC3=CC=CC1=C23)* 0.000 abstract 1
- HXGDTGSAIMULJN-UHFFFAOYSA-N acetnaphthylene Natural products C1=CC(C=C2)=C3C2=CC=CC3=C1 HXGDTGSAIMULJN-UHFFFAOYSA-N 0.000 abstract 1
- 239000000654 additive Substances 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 235000019400 benzoyl peroxide Nutrition 0.000 abstract 1
- 239000001913 cellulose Substances 0.000 abstract 1
- 229920002678 cellulose Polymers 0.000 abstract 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000000975 dye Substances 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract 1
- 238000007654 immersion Methods 0.000 abstract 1
- 235000021388 linseed oil Nutrition 0.000 abstract 1
- 239000000944 linseed oil Substances 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 abstract 1
- KKFHAJHLJHVUDM-UHFFFAOYSA-N n-vinylcarbazole Chemical compound C1=CC=C2N(C=C)C3=CC=CC=C3C2=C1 KKFHAJHLJHVUDM-UHFFFAOYSA-N 0.000 abstract 1
- 125000005609 naphthenate group Chemical group 0.000 abstract 1
- 239000005011 phenolic resin Substances 0.000 abstract 1
- 229920001568 phenolic resin Polymers 0.000 abstract 1
- 229920005990 polystyrene resin Polymers 0.000 abstract 1
- 235000019795 sodium metasilicate Nutrition 0.000 abstract 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052911 sodium silicate Inorganic materials 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 abstract 1
- 235000021286 stilbenes Nutrition 0.000 abstract 1
- 150000003440 styrenes Chemical class 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G13/00—Electrographic processes using a charge pattern
- G03G13/26—Electrographic processes using a charge pattern for the production of printing plates for non-xerographic printing processes
- G03G13/32—Relief printing plates
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G13/00—Electrographic processes using a charge pattern
- G03G13/26—Electrographic processes using a charge pattern for the production of printing plates for non-xerographic printing processes
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
- G03G5/02—Charge-receiving layers
- G03G5/04—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
- G03G5/06—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being organic
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/09—Colouring agents for toner particles
- G03G9/0926—Colouring agents for toner particles characterised by physical or chemical properties
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S430/00—Radiation imagery chemistry: process, composition, or product thereof
- Y10S430/1053—Imaging affecting physical property or radiation sensitive material, or producing nonplanar or printing surface - process, composition, or product: radiation sensitive composition or product or process of making binder containing
- Y10S430/1055—Radiation sensitive composition or product or process of making
- Y10S430/114—Initiator containing
- Y10S430/117—Free radical
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S430/00—Radiation imagery chemistry: process, composition, or product thereof
- Y10S430/1053—Imaging affecting physical property or radiation sensitive material, or producing nonplanar or printing surface - process, composition, or product: radiation sensitive composition or product or process of making binder containing
- Y10S430/1055—Radiation sensitive composition or product or process of making
- Y10S430/114—Initiator containing
- Y10S430/12—Nitrogen compound containing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S430/00—Radiation imagery chemistry: process, composition, or product thereof
- Y10S430/1053—Imaging affecting physical property or radiation sensitive material, or producing nonplanar or printing surface - process, composition, or product: radiation sensitive composition or product or process of making binder containing
- Y10S430/1055—Radiation sensitive composition or product or process of making
- Y10S430/114—Initiator containing
- Y10S430/124—Carbonyl compound containing
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Printing Plates And Materials Therefor (AREA)
- Liquid Developers In Electrophotography (AREA)
- Photoreceptors In Electrophotography (AREA)
- Developing Agents For Electrophotography (AREA)
- Photosensitive Polymer And Photoresist Processing (AREA)
Abstract
Printing plates are produced by charging e.g. by corona discharge, and imagewise exposing e.g. contact, dia or episcopic exposure, a photo-conductive layer comprising a polymerizable organic photo-conductor containing an olefinic double bond or capable of forming such bonds during heating, developing the charge image with a finely divided substance which forms free radials on heat, heating to 50 -300 C. and removing the non-image areas with a solvent. Specified photo-conductors are N-(dimethyl vinyl) carbazole, N-vinyl carbazole, 2-vinyl-4-(o-chlorophenyl)-5-(p-diethyl aminophenyl)-oxazole, 1-hydroxyethyl-2, 5-bis- (p-diethylamino-phenyl)-1, 3, 4-triazole, N-vinyl triazoles, vinyl dibenzofurans, acenaphthylene, stilbene and styrene derivatives. The photoconductors may be dispersed in an alkali-soluble resin e.g. copolymers of styrene and maleic anhydride, polystyrene or phenolic resins and the layer may contain sensitizers. Supports for the photo-conductive layer are Al, Zn, Mg and Cu plates and cellulose products. Specified developers are benzoyl peroxide, a dichlorobenzoyl peroxide, succinyl peroxide, azoisobutyronitrile, tetraphenyl hydrazine, dehydrolophine, diazidostilbene and sodium trichloroacetate. The developer may be applied in solid form with or without carrier e.g. iron chips or a resin-containing toner or dispersed in a liquid together with a dyestuff. Hydrocarbons and chlorinated hydrocarbons are used as such liquids which may contain additives such as naphthenates or linseed oil. Application of the developer is by magnetic brush or drum or immersion or roller application for liquids. The unpolymerized areas are removed by aqueous alkali e.g. aqeous solutions of sodium metasilicate containing glycol, methanol and glycerol.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEK0059245 | 1966-05-13 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES340481A1 true ES340481A1 (en) | 1968-06-01 |
Family
ID=7229057
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES340481A Expired ES340481A1 (en) | 1966-05-13 | 1967-05-12 | Preparation of printing plates employing organic polymerizable photoconductor |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US3615385A (en) |
| AT (1) | AT275569B (en) |
| BE (1) | BE698311A (en) |
| DE (1) | DE1522497C3 (en) |
| ES (1) | ES340481A1 (en) |
| GB (2) | GB1182175A (en) |
| NL (1) | NL156832B (en) |
| SE (1) | SE316372B (en) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4066453A (en) * | 1973-05-02 | 1978-01-03 | Hoechst Aktiengesellschaft | Process for the preparation of printing forms |
| DE2556386C2 (en) * | 1975-12-15 | 1985-02-28 | Hoechst Ag, 6230 Frankfurt | Process for the production of printing forms and / or metallized images |
| JPS5629250A (en) * | 1979-08-08 | 1981-03-24 | Konishiroku Photo Ind Co Ltd | Printing original plate and printing plate forming method |
| US4254196A (en) * | 1979-10-18 | 1981-03-03 | American Hoechst Corporation | Method of preparing lithoplates and plate |
| DE3215967A1 (en) * | 1982-04-29 | 1983-11-03 | Basf Ag, 6700 Ludwigshafen | ELECTROGRAPHIC RECORDING MATERIALS WITH SPECIAL CONNECTORS TRANSPORTING CONNECTIONS |
| DE3304330A1 (en) * | 1983-02-09 | 1984-08-09 | Basf Ag, 6700 Ludwigshafen | NEW 2H-V-TRIAZOLYL (4,5-D) -PYRIMIDINE AND THEIR USE |
| US4533612A (en) * | 1983-04-27 | 1985-08-06 | Basf Aktiengesellschaft | Electrophotographic recording materials containing special charge carrier-transporting compounds |
| DE3324090A1 (en) * | 1983-07-05 | 1985-01-17 | Basf Ag, 6700 Ludwigshafen | ELECTROPHOTOGRAPHIC RECORDING MATERIALS WITH IMPROVED PHOTO SENSITIVITY |
| DE3324089A1 (en) * | 1983-07-05 | 1985-01-17 | Basf Ag, 6700 Ludwigshafen | ELECTROPHOTOGRAPHIC RECORDING MATERIALS WITH IMPROVED PHOTO SENSITIVITY |
| DE3635303A1 (en) | 1986-10-17 | 1988-04-28 | Hoechst Ag | METHOD FOR REMOVING MODIFICATION OF CARRIER MATERIALS MADE OF ALUMINUM OR ITS ALLOYS, AND THEIR ALLOYS AND THEIR USE IN THE PRODUCTION OF OFFSET PRINTING PLATES |
| DE4001466A1 (en) * | 1990-01-19 | 1991-07-25 | Hoechst Ag | Electrochemical roughening of aluminium for printing plate mfr. - using combination of mechanical and electrochemical roughening before and/or after main electrochemical roughening stage |
| GB9326150D0 (en) * | 1993-12-22 | 1994-02-23 | Alcan Int Ltd | Electrochemical roughening method |
| US5750314A (en) | 1995-12-05 | 1998-05-12 | Howard A. Fromson | Method for selectively imaging a lithographic printing plate |
| DE69930831T2 (en) * | 1998-07-07 | 2006-11-30 | Sun Chemical Corp. | CATIONICALLY HARDENABLE LITHOGRAPHIC PRINTED FABRICS HAVING LITTLE CONTENT OF FLUID ORGANIC COMPOUNDS |
| US6489375B2 (en) * | 1998-07-07 | 2002-12-03 | Sun Chemical Corporation | Low VOC cationic curable lithographic printing inks |
-
1966
- 1966-05-13 DE DE1522497A patent/DE1522497C3/en not_active Expired
-
1967
- 1967-05-03 NL NL6706225.A patent/NL156832B/en unknown
- 1967-05-10 AT AT439367A patent/AT275569B/en active
- 1967-05-10 BE BE698311D patent/BE698311A/xx unknown
- 1967-05-11 US US637639A patent/US3615385A/en not_active Expired - Lifetime
- 1967-05-12 GB GB35074/69A patent/GB1182175A/en not_active Expired
- 1967-05-12 ES ES340481A patent/ES340481A1/en not_active Expired
- 1967-05-12 GB GB22093/67A patent/GB1182174A/en not_active Expired
- 1967-05-12 SE SE6735/67A patent/SE316372B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE1522497B2 (en) | 1974-02-14 |
| DE1522497A1 (en) | 1969-09-11 |
| BE698311A (en) | 1967-11-10 |
| AT275569B (en) | 1969-10-27 |
| NL156832B (en) | 1978-05-16 |
| GB1182175A (en) | 1970-02-25 |
| SE316372B (en) | 1969-10-20 |
| NL6706225A (en) | 1967-11-14 |
| DE1522497C3 (en) | 1974-09-19 |
| GB1182174A (en) | 1970-02-25 |
| US3615385A (en) | 1971-10-26 |
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