ES291595A1 - Method of manufacturing metallic images on aluminum and aluminum alloys - Google Patents
Method of manufacturing metallic images on aluminum and aluminum alloysInfo
- Publication number
- ES291595A1 ES291595A1 ES0291595A ES291595A ES291595A1 ES 291595 A1 ES291595 A1 ES 291595A1 ES 0291595 A ES0291595 A ES 0291595A ES 291595 A ES291595 A ES 291595A ES 291595 A1 ES291595 A1 ES 291595A1
- Authority
- ES
- Spain
- Prior art keywords
- image
- porous
- nuclear
- latent
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910000838 Al alloy Inorganic materials 0.000 title abstract 2
- 229910052782 aluminium Inorganic materials 0.000 title abstract 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 4
- 229910052709 silver Inorganic materials 0.000 abstract 4
- 239000004332 silver Substances 0.000 abstract 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 abstract 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 3
- 150000002500 ions Chemical class 0.000 abstract 3
- 229910052751 metal Inorganic materials 0.000 abstract 3
- 239000002184 metal Substances 0.000 abstract 3
- 238000000034 method Methods 0.000 abstract 3
- -1 silver ions Chemical class 0.000 abstract 3
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 abstract 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 abstract 2
- 229910017052 cobalt Inorganic materials 0.000 abstract 2
- 239000010941 cobalt Substances 0.000 abstract 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 abstract 2
- 229910052759 nickel Inorganic materials 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 abstract 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 abstract 1
- RBNPOMFGQQGHHO-UHFFFAOYSA-N -2,3-Dihydroxypropanoic acid Natural products OCC(O)C(O)=O RBNPOMFGQQGHHO-UHFFFAOYSA-N 0.000 abstract 1
- OVXMNRYLZWZZFE-UHFFFAOYSA-N 2-hydroxy-2-(4-nitrophenyl)acetonitrile Chemical compound N#CC(O)C1=CC=C([N+]([O-])=O)C=C1 OVXMNRYLZWZZFE-UHFFFAOYSA-N 0.000 abstract 1
- CMWKITSNTDAEDT-UHFFFAOYSA-N 2-nitrobenzaldehyde Chemical compound [O-][N+](=O)C1=CC=CC=C1C=O CMWKITSNTDAEDT-UHFFFAOYSA-N 0.000 abstract 1
- BXRFQSNOROATLV-UHFFFAOYSA-N 4-nitrobenzaldehyde Chemical compound [O-][N+](=O)C1=CC=C(C=O)C=C1 BXRFQSNOROATLV-UHFFFAOYSA-N 0.000 abstract 1
- PXRKCOCTEMYUEG-UHFFFAOYSA-N 5-aminoisoindole-1,3-dione Chemical compound NC1=CC=C2C(=O)NC(=O)C2=C1 PXRKCOCTEMYUEG-UHFFFAOYSA-N 0.000 abstract 1
- 229910000497 Amalgam Inorganic materials 0.000 abstract 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical class OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 abstract 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- RBNPOMFGQQGHHO-UWTATZPHSA-N D-glyceric acid Chemical compound OC[C@@H](O)C(O)=O RBNPOMFGQQGHHO-UWTATZPHSA-N 0.000 abstract 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 1
- 206010070834 Sensitisation Diseases 0.000 abstract 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric Acid Chemical compound [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 abstract 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 abstract 1
- 239000004411 aluminium Substances 0.000 abstract 1
- IZOWPILIWJADEL-UHFFFAOYSA-N anisole;sodium Chemical compound [Na].COC1=CC=CC=C1 IZOWPILIWJADEL-UHFFFAOYSA-N 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 239000003638 chemical reducing agent Substances 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 150000001261 hydroxy acids Chemical class 0.000 abstract 1
- 239000001630 malic acid Substances 0.000 abstract 1
- 235000011090 malic acid Nutrition 0.000 abstract 1
- 229910052753 mercury Inorganic materials 0.000 abstract 1
- BQPIGGFYSBELGY-UHFFFAOYSA-N mercury(2+) Chemical compound [Hg+2] BQPIGGFYSBELGY-UHFFFAOYSA-N 0.000 abstract 1
- 229940008718 metallic mercury Drugs 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 150000004986 phenylenediamines Chemical class 0.000 abstract 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 abstract 1
- 230000008313 sensitization Effects 0.000 abstract 1
- 238000001179 sorption measurement Methods 0.000 abstract 1
Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/10—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern
- H05K3/18—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern using precipitation techniques to apply the conductive material
- H05K3/181—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern using precipitation techniques to apply the conductive material by electroless plating
- H05K3/182—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern using precipitation techniques to apply the conductive material by electroless plating characterised by the patterning method
- H05K3/185—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern using precipitation techniques to apply the conductive material by electroless plating characterised by the patterning method by making a catalytic pattern by photo-imaging
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/04—Anodisation of aluminium or alloys based thereon
- C25D11/06—Anodisation of aluminium or alloys based thereon characterised by the electrolytes used
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/52—Compositions containing diazo compounds as photosensitive substances
- G03C1/62—Metal compounds reducible to metal
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/76—Photosensitive materials characterised by the base or auxiliary layers
- G03C1/77—Photosensitive materials characterised by the base or auxiliary layers the base being of metal
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C5/00—Photographic processes or agents therefor; Regeneration of such processing agents
- G03C5/58—Processes for obtaining metallic images by vapour deposition or physical development
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- General Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacturing & Machinery (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Electrochemistry (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Printing Plates And Materials Therefor (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
Abstract
Internal and/or external metallic images are made by exposing an aluminium or aluminium alloy carrier having its surface oxidized to form a porous oxide layer separated from the metal of the carrier by a non-porous intermediate layer, the porous layer being sensitized with a photosensitive compound whose light-reaction product will deposit metallic mercury from mercurous ions, treating the exposed carrier with a nuclearintroduction bath comprising a solution containing mercurous ions with or without silver ions to form a latent mercury or silver amalgam nuclear image, and intensifying the latent image with metal, e.g. silver, copper, nickel, cobalt or nickel and cobalt, by treatment with a solution of a salt of such a metal and a reducing agent for said salt. Internal dye images may be obtained by intensifying the latent image using a silver physical developer containing a colour coupler and a phenylene diamine colour developer followed by removal of the metallic image. A mercuric ion adsorption effect which may occur during the nuclear-introduction step and cause fogging is prevented or suppressed by (i) adjusting the concentration of the mercuric ions in the nuclearintroduction bath up to a value of at least 10<-4> molar, (ii) treating the porous oxide layer before sensitization with a solution of a mercuric compound or (iii) adding an organic hydroxy acid e. g. citric, tartaric, glycollic, glyceric or malic acid to the nuclear-introduction bath or (iv) otherwise treating the latent nuclear image prior to intensification with a solution of such an acid. When a dye image is to be formed the latent nuclear image may be treated with a citric acid or glycollic acid solution to prevent colour fog. The intensification step may be conducted by the method described in Specification 1, 64, 725. Oxidation methods for forming the porous and non-porous layers on the carrier are described and photo-sensitive compounds specified for use in the process are aromatic diazosulphonates such as sodium o-methoxybenzene diazosulphonate, aromatic diazocyanides, o-hydroxybenzene or -naphthalene diazonium compounds, o- or p-nitro-mandelonitrile, the bisulphite compounds of o- and p-nitrobenzaldehyde and inorganic metal complex compounds liberating CN<->, CNS<->, NO<->2, SO3<=>, S2O3<=>, NH3, pyridine or derivatives thereof or thiourea or derivatives thereof.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL283265 | 1962-09-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES291595A1 true ES291595A1 (en) | 1963-12-01 |
Family
ID=19754114
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES0291595A Expired ES291595A1 (en) | 1962-09-14 | 1963-09-12 | Method of manufacturing metallic images on aluminum and aluminum alloys |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US3390988A (en) |
| AT (1) | AT243614B (en) |
| BE (1) | BE637400A (en) |
| CH (1) | CH446882A (en) |
| DE (1) | DE1213239B (en) |
| DK (1) | DK109586C (en) |
| ES (1) | ES291595A1 (en) |
| GB (1) | GB1064726A (en) |
| NL (1) | NL283265A (en) |
| SE (1) | SE330127B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3731622A (en) * | 1970-03-18 | 1973-05-08 | California Electro Scient | Intermittent type drum advancing means in a high speed printer |
| US3805023A (en) * | 1972-03-31 | 1974-04-16 | Horizons Inc | Electrical heating device having metal depositions: in a porous anodized metal layer |
| FR2847569B1 (en) * | 2002-11-21 | 2005-01-21 | Commissariat Energie Atomique | PROCESS FOR THE PREPARATION OF MONOLITHIC HYDRATED ALUMINA, AMORPHOUS OR CRYSTALLIZED ALUMINA, ALUMINATES AND COMPOSITE MATERIALS BY METAL ALUMINUM OXIDATION OR ALUMINUM ALLOY |
| US20140061054A1 (en) * | 2012-08-29 | 2014-03-06 | Jack Ye | Anodizing color drawing method |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE407603A (en) * | 1930-02-05 | |||
| NL38606C (en) * | 1932-06-30 | |||
| US2115339A (en) * | 1932-10-27 | 1938-04-26 | Aluminum Co Of America | Photographic plate |
| NL86387C (en) * | 1949-08-08 | |||
| BE503489A (en) * | 1950-05-26 | |||
| BE506160A (en) * | 1950-10-03 | |||
| BE510182A (en) * | 1951-03-27 | |||
| US2733144A (en) * | 1951-03-28 | 1956-01-31 | Method of producing photographic | |
| US2929709A (en) * | 1951-07-10 | 1960-03-22 | Philips Corp | Photographic process |
| US2766119A (en) * | 1952-01-19 | 1956-10-09 | Horizons Inc | Aluminum photographic surfaces |
| US2923626A (en) * | 1956-09-18 | 1960-02-02 | Philips Corp | Method of forming photographic images |
| NL113853C (en) * | 1959-07-22 | |||
| BE598570A (en) * | 1959-12-30 |
-
0
- BE BE637400D patent/BE637400A/xx unknown
- NL NL283265D patent/NL283265A/xx unknown
-
1963
- 1963-09-11 DK DK429963AA patent/DK109586C/en active
- 1963-09-11 SE SE09948/63A patent/SE330127B/xx unknown
- 1963-09-11 AT AT730663A patent/AT243614B/en active
- 1963-09-11 DE DEN23743A patent/DE1213239B/en active Pending
- 1963-09-12 CH CH1125563A patent/CH446882A/en unknown
- 1963-09-12 ES ES0291595A patent/ES291595A1/en not_active Expired
- 1963-09-12 GB GB35943/63A patent/GB1064726A/en not_active Expired
- 1963-09-13 US US308695A patent/US3390988A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| AT243614B (en) | 1965-11-25 |
| GB1064726A (en) | 1967-04-05 |
| NL283265A (en) | |
| BE637400A (en) | |
| SE330127B (en) | 1970-11-02 |
| DK109586C (en) | 1968-05-13 |
| DE1213239B (en) | 1966-03-24 |
| CH446882A (en) | 1967-11-15 |
| US3390988A (en) | 1968-07-02 |
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