ES2818399A1 - System for adsorption of pollutants from sludge and wastewater through fly ash from biomass combustion (Machine-translation by Google Translate, not legally binding) - Google Patents

System for adsorption of pollutants from sludge and wastewater through fly ash from biomass combustion (Machine-translation by Google Translate, not legally binding) Download PDF

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Publication number
ES2818399A1
ES2818399A1 ES201930876A ES201930876A ES2818399A1 ES 2818399 A1 ES2818399 A1 ES 2818399A1 ES 201930876 A ES201930876 A ES 201930876A ES 201930876 A ES201930876 A ES 201930876A ES 2818399 A1 ES2818399 A1 ES 2818399A1
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Spain
Prior art keywords
sludge
wastewater
tank
fly ash
cartridges
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Pending
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ES201930876A
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Spanish (es)
Inventor
De Rivera Durán Alejandro Cid
Carrasco Miguel Angel Bueno
Bogeat Angel Encinas
Calvo Ascensión Ciruelos
Herrero Rubén Sánchez
Bernet Montserrat Gómez-Cardoso
Cordero Laura Moreno
Carmona María Luisa Carmona
Vila Ana María Lozano
Castizo Manuel Martín
Rodríguez Juan Miguel Meneses
Menor Concepción Pacheco
Amado Raquel Maya
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ctaex_ Centro Tecnologico Nac Agroalimentario Extremadura
Disaim Ingenieria S L
Intromac_instituto Tecnologico De Rocas Ornamentales Y Mat De Construccion
FCC Aqualia SA
Original Assignee
Ctaex_ Centro Tecnologico Nac Agroalimentario Extremadura
Disaim Ingenieria S L
Intromac_instituto Tecnologico De Rocas Ornamentales Y Mat De Construccion
FCC Aqualia SA
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Application filed by Ctaex_ Centro Tecnologico Nac Agroalimentario Extremadura, Disaim Ingenieria S L, Intromac_instituto Tecnologico De Rocas Ornamentales Y Mat De Construccion, FCC Aqualia SA filed Critical Ctaex_ Centro Tecnologico Nac Agroalimentario Extremadura
Priority to ES201930876A priority Critical patent/ES2818399A1/en
Publication of ES2818399A1 publication Critical patent/ES2818399A1/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Fertilizers (AREA)
  • Treatment Of Sludge (AREA)

Abstract

Cylindrical tank that allows the agitation of sludge and/or wastewater in continuous contact with adsorbent material for heavy metals and/or other pollutants, contained in lattice cartridges to facilitate their separation and subsequent recovery. Such adsorbent material would be formed by a mixture of lime and fly ash from biomass plants, solving the problem of managing this type of waste. On the other hand, sewage sludge and/or wastewater contain levels of heavy metals that are polluting and harmful to health. After the agitation process, the decontaminated sludge is moved out of the tank and reused as fertilizers. To complete the cycle, the adsorbent material contained in the tank cartridges and composed of fly ash can be reused to make lower cost construction materials with less environmental impact. This material is recovered by removing the movable cartridges from inside the tank. (Machine-translation by Google Translate, not legally binding)

Description

DESCRIPCIÓNDESCRIPTION

SISTEMA DE ADSORCIÓN DE CONTAMINANTES DE LODOS Y AGUAS SLUDGE AND WATER POLLUTANT ADSORPTION SYSTEM

RESIDUALES A TRAVÉS DE CENIZAS VOLANTES DE COMBUSTIÓN DE RESIDUALS THROUGH FLYING ASHES FROM COMBUSTION

BIOMASABIOMASS

SECTOR DE LA TÉCNICATECHNICAL SECTOR

La presente invención se refiere a un sistema de adsorción de metales pesados y otros contaminantes procedentes de aguas residuales y/o lodos de depuradora mediante cenizas volantes procedentes de la combustión de biomasa. Este dispositivo permite, por un lado, utilizar como fertilizantes de bajo impacto los lodos de depuradora tratados. Por otro lado, los agregados de cenizas resultantes tras el tratamiento permiten su uso en materiales de construcción reciclables de bajo impacto medioambiental.The present invention relates to a system for the adsorption of heavy metals and other pollutants from sewage and / or sewage sludge using fly ash from biomass combustion. This device makes it possible, on the one hand, to use treated sewage sludge as low impact fertilizers. On the other hand, the resulting ash aggregates after treatment allow their use in recyclable building materials with low environmental impact.

ANTECEDENTES DE LA INVENCIÓNBACKGROUND OF THE INVENTION

La utilización de cenizas volantes como adsorbente de metales pesados o de otros contaminantes es conocida por diversos estudios publicados. En general, se trata de procedimientos divulgados en revistas científicas como las indicadas a continuación: Revista Ingeniería y Región, 13(1) (2015) 73-90.The use of fly ash as an adsorbent for heavy metals or other pollutants is known from various published studies. In general, these are procedures disclosed in scientific journals such as those indicated below: Revista Ingeniería y Región, 13 (1) (2015) 73-90.

Progress in Energy and Combustion Science, 36 (2010) 327-363Progress in Energy and Combustion Science, 36 (2010) 327-363

Journal of Hazardous Materials, 148 (2007) 538-547Journal of Hazardous Materials, 148 (2007) 538-547

Asimismo, hay patentes de dispositivos relativos a la purificación de aguas residuales. Por ejemplo, el relativo a la patente ES-2142193_A1 representa un equipo móvil de aspiración-impulsión de lodos para su limpieza general. Otra patente, con referencia ES-2216203_T3, presenta un dispositivo para la recepción y tratamiento de substrato contaminado, especialmente de lodo, que se aspira durante la limpieza de un canal, con un espacio de recepción de la suciedad.There are also patents for devices related to the purification of wastewater. For example, the one relating to patent ES-2142193_A1 represents a mobile suction-impulsion equipment for sludge for general cleaning. Another patent, with reference ES-2216203_T3, presents a device for the reception and treatment of contaminated substrate, especially mud, which is aspirated during the cleaning of a channel, with a dirt reception space.

Sin embargo, no existe o no ha sido encontrado por los solicitantes, dispositivos o sistemas que utilicen las cenizas volantes procedentes de la combustión de biomasa como material adsorbente de metales pesados para la purificación de aguas residuales o lodos.However, it does not exist or has not been found by applicants, devices or systems that use fly ash from biomass combustion as heavy metal adsorbent material for the purification of wastewater or sludge.

.EXPLICACIÓN DE LA INVENCIÓN . EXPLANATION OF THE INVENTION

Con el fin de mejorar los sistemas purificadores de aguas residuales, la invención propone un dispositivo para implantación en planta depuradora industrial que incorpora cenizas volantes de combustión de la biomasa para adsorber metales pesados y otros contaminantes orgánicos. Partiendo de ello, la presente invención presenta un sistema que resuelve conjuntamente distintos problemas como son la gestión de residuos de cenizas volantes de plantas de combustión a partir de biomasa, así como la gestión de aguas contaminadas provenientes de zonas industriales. A su vez, los lodos de depuradora tratados con las cenizas volantes pueden utilizarse como fertilizantes, enriqueciendo satisfactoriamente de manera ecológica a otro sector diferente a los mencionados. Para cerrar el ciclo de ventajas y aplicaciones del dispositivo, otra medida ventajosa sería la reutilización de las cenizas volantes empleadas en el tratamiento de lodos y/o aguas residuales como componente sustitutivo de cementos en materiales de construcción, lo cual no sólo abarata el proceso de fabricación sino que supone una ventaja de impacto medioambiental.In order to improve wastewater purification systems, the invention proposes a device for implantation in an industrial treatment plant that incorporates biomass combustion fly ash to adsorb heavy metals and other organic pollutants. Starting from this, the present invention presents a system that jointly solves different problems such as the management of fly ash waste from biomass combustion plants, as well as the management of polluted water from industrial areas. In turn, the sewage sludge treated with fly ash can be used as fertilizers, satisfactorily enriching another sector different from those mentioned in an ecological way. To close the cycle of advantages and applications of the device, another advantageous measure would be the reuse of the fly ash used in the treatment of sludge and / or wastewater as a substitute component for cements in construction materials, which not only makes the process of manufacturing but is an environmental impact advantage.

En este sentido, la colaboración inter-industrias incrementa la productividad y competitividad económica, de manera sostenible y a largo plazo. Se estarían integrando medidas adicionales de eficiencia para el uso optimizado de energía, agua y materiales.In this sense, inter-industry collaboration increases productivity and economic competitiveness, in a sustainable and long-term manner. Additional efficiency measures are being integrated for the optimized use of energy, water and materials.

El equipo a patentar comprende un tanque de agitación y adsorción con las características básicas detalladas en siguientes apartados:The equipment to be patented comprises a stirring and adsorption tank with the basic characteristics detailed in the following sections:

Se trata de un tanque construido en acero inoxidable y montado sobre una bancada monoblock junto con el cuadro de control y una bomba de trasiego de lodos.It is a tank built in stainless steel and mounted on a monoblock bench together with the control panel and a sludge transfer pump.

El tanque incluye en su interior un motor agitador para mantener los lodos en suspensión homogénea y cuenta con 6 soportes interiores para introducir los agregados de cenizas volantes de biomasa (cenizas-cal 4:1) en forma de cartuchos enrejados para maximizar el contacto con el lodo. Tales cartuchos o cestas de acero inoxidable son desmontables por parte superior y fijación interior. Las cenizas volantes procedentes de biomasa se añaden en forma de agregados cenizas-cal para incrementar su microestructura y porosidad estimulando la adsorción y, a su vez, para diferenciar el rango de granulometría para facilitar la separación de lodo y cenizas al final del tratamiento.The tank includes inside a stirrer motor to keep the sludge in homogeneous suspension and has 6 internal supports to introduce the biomass fly ash aggregates (4: 1 ash-lime) in the form of cartridges. grating to maximize mud contact. Such cartridges or stainless steel baskets are removable by upper part and internal fixation. Fly ash from biomass is added in the form of ash-lime aggregates to increase its microstructure and porosity, stimulating adsorption and, in turn, to differentiate the granulometry range to facilitate the separation of sludge and ash at the end of the treatment.

El lodo entra en el tanque proveniente del espesador por gravedad y se bombea al final del tiempo del ciclo de trabajo a la línea de fangos haciéndose pasar por la centrífuga siguiendo el normal funcionamiento de la planta.The sludge enters the tank from the gravity thickener and is pumped at the end of the work cycle time to the sludge line, passing through the centrifuge following the normal operation of the plant.

Siguiendo con el ciclo normal de la línea de fangos de una depuradora, en la centrífuga se reduce su contenido de humedad y se depositan en la tolva de almacenamiento de lodos deshidratados, desde donde serán recogidos para ser aplicados como compost o fertilizante de bajo impacto.Continuing with the normal cycle of the sludge line of a sewage treatment plant, in the centrifuge its moisture content is reduced and it is deposited in the dehydrated sludge storage hopper, from where it will be collected to be applied as compost or low impact fertilizer.

BREVE DESCRIPCIÓN DE LOS DIBUJOSBRIEF DESCRIPTION OF THE DRAWINGS

Para complementar la descripción que se está realizando y con objeto de ayudar a una mejor comprensión de las características de la invención, se acompaña como parte integrante de dicha descripción, un juego de dibujos en donde con carácter ilustrativo y no limitativo, se ha representado lo siguiente:To complement the description that is being made and in order to help a better understanding of the characteristics of the invention, a set of drawings is attached as an integral part of said description, where, with an illustrative and non-limiting nature, the following has been represented following:

Figura 1.- Muestra una vista transversal superior del dispositivo de la invención.Figure 1.- Shows a top cross-sectional view of the device of the invention.

Figura 2.- Muestra una vista frontal del dispositivo de la invención incluyendo el cuadro de mandos.Figure 2.- Shows a front view of the device of the invention including the control panel.

Figura 3.- Muestra una vista lateral del dispositivo de la invención.Figure 3.- Shows a side view of the device of the invention.

Figura 4.- Muestra una vista lateral del dispositivo de la invención.Figure 4.- Shows a side view of the device of the invention.

Figura 5.- Muestra una vista lateral y transversal superior del cartucho.Figure 5.- Shows a lateral and upper cross-sectional view of the cartridge.

REALIZACIÓN PREFERENTE DE LA INVENCIÓNPREFERRED EMBODIMENT OF THE INVENTION

A la vista de las mencionadas figuras, y de acuerdo con la numeración adoptada, se puede observar en ellas un ejemplo de realización preferente de la invención, la cual comprende las partes y elementos que se indican y describen en detalle a continuación. Así, tal y como se observa en las figuras 1-4, una posible realización preferente del dispositivo comprende las características mecánicas indicadas a continuación: La carga superior de lodos (1) se realiza con válvula motorizada. Dentro del tanque, se encuentran anclados entre sí y al tanque las seis unidades o cartuchos (2). Tales cartuchos son cestas de acero inoxidable donde se introducen los agregados de cenizas-cal. El mismo tanque también comprende un agitador (4) y una hélice inferior con dos sentidos de giro, horario y antihorario y selector de velocidad. La salida de lodos una vez procesados tendría lugar por aspiración a través de un cono inferior en tanque con brida roscada (5). Para el traslado de los lodos descontaminados se dispone de una bomba de trasiego (6). Un filtro (8) durante el trasiego impide que cuerpos sólidos puedan afectar al correcto funcionamiento de la bomba. El sistema comprende en esta fase también una llave de maneta manual de seguridad y limpieza del filtro (9). La descarga inferior de lodos con válvula motorizada (7) está acoplada a la bomba de trasiego.In view of the aforementioned figures, and in accordance with the numbering adopted, an example of a preferred embodiment of the invention can be seen in them, which comprises the parts and elements that are indicated and described in detail below. continuation. Thus, as seen in Figures 1-4, a possible preferred embodiment of the device comprises the mechanical characteristics indicated below: The upper loading of sludge (1) is carried out with a motorized valve. Inside the tank, the six units or cartridges (2) are anchored to each other and to the tank. Such cartridges are stainless steel baskets where the ash-lime aggregates are introduced. The same tank also includes an agitator (4) and a lower propeller with two directions of rotation, clockwise and counterclockwise, and a speed selector. The sludge outlet once processed would take place by suction through a lower cone in the tank with a threaded flange (5). For the transfer of the decontaminated sludge there is a transfer pump (6). A filter (8) during the transfer prevents solid bodies from affecting the correct operation of the pump. In this phase, the system also includes a manual safety and filter cleaning handle key (9). The lower sludge discharge with motorized valve (7) is coupled to the transfer pump.

Con respecto al mando y control eléctrico, el dispositivo dispone de un armario eléctrico (12) listo para recibir acometida eléctrica con salidas de fuerza, protegidas por térmico y diferencial a bomba y motor, autómata programable y display multifunción, con las siguientes capacidades:With regard to electrical command and control, the device has an electrical cabinet (12) ready to receive an electrical connection with force outputs, protected by thermal and differential to pump and motor, programmable automaton and multifunction display, with the following capabilities:

-Sonda de control de llenado de nivel máximo con alarma de superación de nivel de rebose (13).-Maximum level filling control probe with overflow level alarm (13).

-Sonda de control de llenado de nivel mínimo (14).-Minimum level filling control probe (14).

-Sonda de control de pH con información visible en pantalla (15).-Ph control probe with information visible on screen (15).

-Sonda de temperatura con información visible en pantalla (16).-Temperature probe with information visible on the screen (16).

-Reloj temporizador con contador de ciclos visible en pantalla (17).-Timer clock with cycle counter visible on screen (17).

-Control apertura-cierre válvula de llenado modo manual y automático (18).-Control opening-closing filling valve manual and automatic mode (18).

-Control apertura-cierre válvula de vaciado modo manual y automático (19).-Control opening-closing drain valve manual and automatic mode (19).

-Arranque-paro bomba de trasiego modo manual y automático (20).-Start-stop transfer pump manual and automatic mode (20).

-Arranque-paro agitador, modo manual y automático, control de rpm y sentido de giro del motor de agitación (21).-Start-stop stirrer, manual and automatic mode, control of rpm and direction of rotation of the stirring motor (21).

-Acometida eléctrica 450/750V (22).-Acometida electric 450 / 750V (22).

La figura 5 muestra el detalle de estructura del cartucho contenedor de los agregados de cenizas volantes empleado dentro del tanque. Esta cesta cilíndrica comprende una malla de acero galvanizado (1) que evita la salida al exterior del material adsorbente. Figure 5 shows the detail of the structure of the cartridge containing the fly ash aggregates used inside the tank. This cylindrical basket comprises a galvanized steel mesh (1) that prevents the adsorbent material from escaping to the outside.

Para un mejor soporte del peso de la estructura en su conjunto, la estructura dispone de aros de refuerzo pletina también en acero galvanizado (2). Los cartuchos en el interior del tanque se mantendrían correctamente cerrados con una tapadera de la misma malla de acero con palomillas y tuerca hexagonal de cierre (3). Debido a que la extracción de los cartuchos tras el tratamiento con los lodos es manual, se han colocado unas asas de tubo de acero para un adecuado agarre (4) (a escala industrial se podría hacer con un polipasto, pero igualmente necesita unas sujeciones para elevarlo). Por último, para insertar cada cartucho en el interior del tanque, disponen de un vástago de apoyo en cono de depósito.To better support the weight of the structure as a whole, the structure has plate reinforcement rings also in galvanized steel (2). The cartridges inside the tank would be kept properly closed with a lid made of the same steel mesh with wing nuts and hexagonal closing nut (3). Since the extraction of the cartridges after the treatment with the sludge is manual, some steel tube handles have been placed for an adequate grip (4) (on an industrial scale it could be done with a hoist, but it also needs fasteners to raise it). Finally, to insert each cartridge inside the tank, they have a support rod in a tank cone.

A nivel de explotación industrial, este sistema no sólo permite gestionar de una manera sostenible los niveles de contaminantes de aguas y lodos en depuradoras sino que permite una aplicación posterior de esos lodos como fertilizantes y de los agregados de cenizas volantes para formar parte de materiales de construcción más ecológicos. At the industrial exploitation level, this system not only allows to manage in a sustainable way the levels of pollutants in water and sludge in sewage treatment plants, but also allows a subsequent application of these sludge as fertilizers and fly ash aggregates to form part of waste materials. greener construction.

Claims (6)

REIVINDICACIONES 1. Tanque de agitación de lodos y/o aguas residuales que comprende una serie de cartuchos donde es incorporado el material adsorbente de metales pesados y/o contaminantes orgánicos.1. Agitation tank for sludge and / or wastewater comprising a series of cartridges where the adsorbent material for heavy metals and / or organic pollutants is incorporated. 2. Dispositivo según la reivindicación 1 que comprende en su interior un motor agitador para mantener la suspensión homogénea previniendo la decantación.2. Device according to claim 1 comprising inside a stirrer motor to keep the suspension homogeneous preventing settling. 3. Dispositivo según la reivindicación 1 que comprende cartuchos o cestas desmontables por parte superior y fijación interior con enrejado en malla para mantener separado el material adsorbente de la suspensión.3. Device according to claim 1 comprising cartridges or baskets removable at the top and internal fixation with mesh lattice to keep the adsorbent material from the suspension separate. 4. Dispositivo según reivindicación 1 que comprende una bomba de aspiración para la extracción de los lodos y/o aguas residuales tratados.4. Device according to claim 1 comprising a suction pump for the extraction of the treated sludge and / or wastewater. 5. Dispositivo según la reivindicación 1 caracterizado porque permite su manejo a través de cuadro de control eléctrico. El sistema comprende un armario eléctrico (12) con salidas de fuerza, protegidas por térmico y diferencial a bomba y motor, autómata programable y display multifunción.5. Device according to claim 1 characterized in that it allows its handling through an electrical control panel. The system comprises an electrical cabinet (12) with force outputs, protected by thermal and differential pump and motor, programmable automaton and multifunction display. 6. Dispositivo según la reivindicación 1 caracterizado porque permite eliminar los olores desagradables de lodos y/o aguas residuales. 6. Device according to claim 1, characterized in that it allows eliminating unpleasant odors from sludge and / or waste water.
ES201930876A 2019-10-08 2019-10-08 System for adsorption of pollutants from sludge and wastewater through fly ash from biomass combustion (Machine-translation by Google Translate, not legally binding) Pending ES2818399A1 (en)

Priority Applications (1)

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ES201930876A ES2818399A1 (en) 2019-10-08 2019-10-08 System for adsorption of pollutants from sludge and wastewater through fly ash from biomass combustion (Machine-translation by Google Translate, not legally binding)

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ES201930876A ES2818399A1 (en) 2019-10-08 2019-10-08 System for adsorption of pollutants from sludge and wastewater through fly ash from biomass combustion (Machine-translation by Google Translate, not legally binding)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2027676C1 (en) * 1991-02-11 1995-01-27 Украинский государственный научно-исследовательский институт прогрессивных технологий в коммунальном хозяйстве Domestic filter
ES2360766T3 (en) * 2000-09-26 2011-06-08 Lanxess Deutschland Gmbh ADSORTION CONTAINER AND IRON OXIDE ADSORBENT.

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2027676C1 (en) * 1991-02-11 1995-01-27 Украинский государственный научно-исследовательский институт прогрессивных технологий в коммунальном хозяйстве Domestic filter
ES2360766T3 (en) * 2000-09-26 2011-06-08 Lanxess Deutschland Gmbh ADSORTION CONTAINER AND IRON OXIDE ADSORBENT.

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
ARANGO-MARTÍNEZ, NANCY; PÉREZ-BUENO, JOSÉ DE JESÚS; GOCHI-PONCE, YADIRA; SÁNCHEZ-RUBIO, MANUEL. Zeolitas a partir de cenizas volantes generadas en las centrales carboeléctricas para el tratamiento de agua contaminada con Mn y Pb. Tecnología, Ciencia, Educación, Instituto Mexicano de Ingenieros Químicos A.C Monterrey, México. 01/06/20011, 01/06/2011, Vol. 26, Páginas 5-13 Recuperado de Internet (URL:http://www.redalyc.org/articulo.oa?id=48219771002), Pág. 8-9 y resumen *

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