ES263221A1 - Un procedimiento de producir un polimero - Google Patents
Un procedimiento de producir un polimeroInfo
- Publication number
- ES263221A1 ES263221A1 ES0263221A ES263221A ES263221A1 ES 263221 A1 ES263221 A1 ES 263221A1 ES 0263221 A ES0263221 A ES 0263221A ES 263221 A ES263221 A ES 263221A ES 263221 A1 ES263221 A1 ES 263221A1
- Authority
- ES
- Spain
- Prior art keywords
- sulphide
- diethyl
- iodine
- titanium
- aluminium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 title abstract 5
- 239000010936 titanium Substances 0.000 title abstract 5
- 229910052719 titanium Inorganic materials 0.000 title abstract 5
- 239000003054 catalyst Substances 0.000 title abstract 4
- 229920003194 trans-1,4-polybutadiene polymer Polymers 0.000 title 1
- -1 halo alkoxides Chemical class 0.000 abstract 8
- 229930195733 hydrocarbon Natural products 0.000 abstract 5
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 abstract 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 4
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 abstract 4
- LJSQFQKUNVCTIA-UHFFFAOYSA-N diethyl sulfide Chemical compound CCSCC LJSQFQKUNVCTIA-UHFFFAOYSA-N 0.000 abstract 4
- 150000002430 hydrocarbons Chemical class 0.000 abstract 4
- 229910052740 iodine Inorganic materials 0.000 abstract 4
- 239000011630 iodine Substances 0.000 abstract 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- 229910052782 aluminium Inorganic materials 0.000 abstract 3
- 239000004411 aluminium Substances 0.000 abstract 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 3
- PPQUYYAZSOKTQD-UHFFFAOYSA-M diethylalumanylium;iodide Chemical compound CC[Al](I)CC PPQUYYAZSOKTQD-UHFFFAOYSA-M 0.000 abstract 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 abstract 3
- 238000006116 polymerization reaction Methods 0.000 abstract 3
- 239000004215 Carbon black (E152) Substances 0.000 abstract 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 abstract 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 abstract 2
- 150000001350 alkyl halides Chemical class 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 150000002902 organometallic compounds Chemical class 0.000 abstract 2
- 150000003568 thioethers Chemical class 0.000 abstract 2
- NLLZTRMHNHVXJJ-UHFFFAOYSA-J titanium tetraiodide Chemical compound I[Ti](I)(I)I NLLZTRMHNHVXJJ-UHFFFAOYSA-J 0.000 abstract 2
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 abstract 1
- OIVUHPTVQVCONM-UHFFFAOYSA-N 6-bromo-4-methyl-1h-indazole Chemical compound CC1=CC(Br)=CC2=C1C=NN2 OIVUHPTVQVCONM-UHFFFAOYSA-N 0.000 abstract 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 abstract 1
- HTIRHQRTDBPHNZ-UHFFFAOYSA-N Dibutyl sulfide Chemical compound CCCCSCCCC HTIRHQRTDBPHNZ-UHFFFAOYSA-N 0.000 abstract 1
- XYWDPYKBIRQXQS-UHFFFAOYSA-N Diisopropyl sulfide Chemical compound CC(C)SC(C)C XYWDPYKBIRQXQS-UHFFFAOYSA-N 0.000 abstract 1
- QMMFVYPAHWMCMS-UHFFFAOYSA-N Dimethyl sulfide Chemical compound CSC QMMFVYPAHWMCMS-UHFFFAOYSA-N 0.000 abstract 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 abstract 1
- QZRGKCOWNLSUDK-UHFFFAOYSA-N Iodochlorine Chemical compound ICl QZRGKCOWNLSUDK-UHFFFAOYSA-N 0.000 abstract 1
- KEQFTVQCIQJIQW-UHFFFAOYSA-N N-Phenyl-2-naphthylamine Chemical compound C=1C=C2C=CC=CC2=CC=1NC1=CC=CC=C1 KEQFTVQCIQJIQW-UHFFFAOYSA-N 0.000 abstract 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052776 Thorium Inorganic materials 0.000 abstract 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 1
- 150000004703 alkoxides Chemical class 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 abstract 1
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 abstract 1
- SIPUZPBQZHNSDW-UHFFFAOYSA-N diisobutylaluminium hydride Substances CC(C)C[Al]CC(C)C SIPUZPBQZHNSDW-UHFFFAOYSA-N 0.000 abstract 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- AEHWKBXBXYNPCX-UHFFFAOYSA-N ethylsulfanylbenzene Chemical class CCSC1=CC=CC=C1 AEHWKBXBXYNPCX-UHFFFAOYSA-N 0.000 abstract 1
- 229910052733 gallium Inorganic materials 0.000 abstract 1
- 229910052735 hafnium Inorganic materials 0.000 abstract 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical group 0.000 abstract 1
- 229910001385 heavy metal Inorganic materials 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 abstract 1
- 229910000043 hydrogen iodide Inorganic materials 0.000 abstract 1
- 229910052738 indium Inorganic materials 0.000 abstract 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 abstract 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 abstract 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 229910052716 thallium Inorganic materials 0.000 abstract 1
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 abstract 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
Un procedimiento de producir un polímero, que tiene por lo menos 70% de sus unidades en la configuración trans- 1,4, a partir de un hidrocarburo diolefínico conjugado que tiene cuatro átomos de carbono en la cadena insaturada, que comprende polimerizar dicho hidrocarburo diolefínico conjugado en presencia de un catalizador que contiene yodo y que comprende una mezcla de (1) un compuesto reducible de un metal pesado del grupo IVB de la tabla periódica, (2) un compuesto organometálico que tiene la fórmula Me R1R2R3, en la cual Me es un metal elegido del grupo IIIA de la tabla periódica, R1 y R2 son radicales hidrocarburos y R3 se elige del grupo consistente en hidrógeno, halógeno, radicales hidrocarburo y radicales oxihidrocarburo, y (3) un tioeter, en el cual al menos uno de los compuestos (1) y (2) contiene yodo.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA789266 | 1959-12-26 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES263221A1 true ES263221A1 (es) | 1961-05-16 |
Family
ID=4141154
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES0263221A Expired ES263221A1 (es) | 1959-12-26 | 1960-12-14 | Un procedimiento de producir un polimero |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US3196143A (es) |
| BE (1) | BE598453A (es) |
| DE (1) | DE1128145B (es) |
| ES (1) | ES263221A1 (es) |
| FR (1) | FR1280835A (es) |
| GB (1) | GB897472A (es) |
| NL (2) | NL128229C (es) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3350378A (en) * | 1961-11-17 | 1967-10-31 | Polymer Corp | 1, 3 butadiene polymers |
| US3547864A (en) * | 1967-08-18 | 1970-12-15 | Polymer Corp | Stereospecific polymerization of conjugated diolefins in the presence of halogen substituted diolefins |
| US4020008A (en) * | 1974-03-01 | 1977-04-26 | Phillips Petroleum Company | Catalysts for producing high trans-polybutadiene |
| US3926933A (en) * | 1974-03-01 | 1975-12-16 | Phillips Petroleum Co | Catalysts for producing high trans-polybutadiene |
| US4207205A (en) * | 1975-10-16 | 1980-06-10 | Exxon Research & Engineering Co. | Reduction of TiCl4 with reducing agents modified with Lewis bases |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE547699A (es) * | 1955-05-10 | |||
| US2843577A (en) * | 1955-10-17 | 1958-07-15 | Standard Oil Co | Process and catalyst for polymerization using polyvalent metal salts and a reducing agent plus a sulfur compound |
| NL111783C (es) * | 1955-10-17 | |||
| BE552578A (es) * | 1955-11-14 | |||
| US3020269A (en) * | 1957-01-10 | 1962-02-06 | Union Carbide Corp | Butadiene polymerization |
-
0
- BE BE598453D patent/BE598453A/xx unknown
- NL NL259400D patent/NL259400A/xx unknown
- NL NL128229D patent/NL128229C/xx active
-
1960
- 1960-12-05 US US73481A patent/US3196143A/en not_active Expired - Lifetime
- 1960-12-14 ES ES0263221A patent/ES263221A1/es not_active Expired
- 1960-12-15 GB GB43219/60A patent/GB897472A/en not_active Expired
- 1960-12-22 FR FR847721A patent/FR1280835A/fr not_active Expired
- 1960-12-24 DE DEP26289A patent/DE1128145B/de active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| DE1128145B (de) | 1962-04-19 |
| US3196143A (en) | 1965-07-20 |
| NL259400A (es) | |
| NL128229C (es) | |
| BE598453A (es) | |
| FR1280835A (fr) | 1962-01-08 |
| GB897472A (en) | 1962-05-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3541063A (en) | Process for the polymerization of diolefins with a catalyst comprising alkylaluminum compounds,group iii-b organo metal compounds and organoaluminum fluoride compounds | |
| US3066126A (en) | Diene polymerization catalyst | |
| ES230044A1 (es) | UN MÉTODO PARA LA POLIMERIZACIoN DE HIDROCARBUROS ETILÉNICAMENTE NO SATURADOS | |
| GB828201A (en) | Process for the manufacture of polyethylene | |
| US2965624A (en) | Carbon-alkali metal compounds as polymerization catalyst | |
| ES263221A1 (es) | Un procedimiento de producir un polimero | |
| US3215682A (en) | Process and catalyst for production of rubbery polymers | |
| US3409604A (en) | Polymerization of butadiene | |
| GB813797A (en) | Improvements in or relating to the polymerisation of ethylene | |
| US3205213A (en) | Production of cis-1, 4 polybutadiene with a titanium tetrachloride-aluminum alkyl-iodine catalyst | |
| GB827464A (en) | Polymerisation process | |
| GB1238929A (es) | ||
| US3317502A (en) | Polymerization of olefins in the presence of a coordination catalyst and carbonyl sulfide | |
| US3256259A (en) | Polymers of reduced molecular weight | |
| US3734900A (en) | Polymerization of conjugated diolefins | |
| US3180858A (en) | Molecular weight control of cis-polyisoprene | |
| GB783487A (en) | Improvements in or relating to the polymerization of ethylene | |
| GB872142A (en) | A process for polymerizing alpha-olefines | |
| US3067188A (en) | Polymerization of 1, 3-butadiene with a tici-mocl-znr catalyst | |
| US3223693A (en) | Fluidization of reaction mixture of organoaluminum-titanium tetrachloride polymerized isoprene by addition of an organometallic compound | |
| GB972106A (en) | A process for polymerising buta-1,3-diene | |
| US2999089A (en) | Polymerization of conjugated dienes with polynuclear hydrocarbons as polymerization promoters | |
| GB840165A (en) | Method of preparing 1,4 trans polyisoprene | |
| GB933418A (en) | Polymerization of butadiene | |
| US3557076A (en) | Process for polymerizing isoprene in contact with a three-component catalyst prepared from ticl4,alr2cl and particular silanes |