ES2566675B1 - Procedure for applying a coating to chrome, nickel plated or polished and varnish coating - Google Patents

Procedure for applying a coating to chrome, nickel plated or polished and varnish coating Download PDF

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ES2566675B1
ES2566675B1 ES201431500A ES201431500A ES2566675B1 ES 2566675 B1 ES2566675 B1 ES 2566675B1 ES 201431500 A ES201431500 A ES 201431500A ES 201431500 A ES201431500 A ES 201431500A ES 2566675 B1 ES2566675 B1 ES 2566675B1
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phase
weight
total
coating
varnish
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ES2566675A1 (en
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Iván CURESES MENÉNDEZ
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Racing Colors SL
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Racing Colors SL
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/29Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C30/00Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Paints Or Removers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

Procedimiento para la aplicación de un recubrimiento a cromados, niquelados o pulidos y barniz de revestimiento.#Comprende una primera fase en la que se limpia o desengrasa la superficie del cromado, niquelado o pulido a tratar, y porque comprende: una segunda fase en que se aplica un revestimiento sobre la superficie de un barniz del tipo poliuretano, acrílico o epoxi.Procedure for applying a coating to chrome, nickel plated or polished and coating varnish. # It comprises a first phase in which the surface of the chrome plating, nickel plating or polishing to be treated is cleaned or degreased, and because it comprises: a second phase in which a coating is applied on the surface of a varnish of the polyurethane, acrylic or epoxy type.

Description

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DESCRIPCIONDESCRIPTION

Procedimiento para la aplicacion de un recubrimiento a cromados, niquelados o pulidos y barniz de revestimiento.Procedure for applying a coating to chrome, nickel plated or polished and varnish coating.

Procedimiento para la aplicacion de un recubrimiento a cromados, niquelados o pulidos y barniz de revestimiento del tipo que comprende una primera fase en la que se limpia o desengrasa la superficie del cromado, niquelado o pulido a tratar, caracterizado porque comprende: una segunda fase en que se aplica un revestimiento sobre la superficie de un barniz del tipo poliuretano, acrilico o epoxi y comprende las siguientes proporciones: entre un 0,1-1% en peso del total de estirenos, entre un 1-5% en peso del total de tolueno, entre un 1-5% en peso del total de acetato de 1-metil-2-metoxietileno, entre un 30-60% en peso del total de 4-metil-2-pentanona, y entre un 30-60% en peso del total de una resina poliuretana, acrilica o epoxi, una tercera fase en la que se anade un catalizador entre el 1530% en peso en relacion al total del producto de la segunda fase y un disolvente tipo medio o lento entre el 15-30% en peso en relacion al total del producto de la segunda fase, una cuarta fase en la que se anaden unos tintes al disolvente concentrado, una quinta fase en la que se aplica el producto resultante de la tercera fase sobre la superficie, y una sexta fase, en la que el recubrimiento aplicado en la quinta fase se seca.Procedure for applying a coating to chrome, nickel plated or polished and coating varnish of the type comprising a first phase in which the surface of the chrome plating, nickel plating or polishing to be treated is cleaned or degreased, characterized in that it comprises: a second phase in that a coating is applied on the surface of a varnish of the polyurethane, acrylic or epoxy type and comprises the following proportions: between 0.1-1% by weight of total styrenes, between 1-5% by weight of total toluene, between 1-5% by weight of the total 1-methyl-2-methoxyethylene acetate, between 30-60% by weight of the total 4-methyl-2-pentanone, and between 30-60% in Total weight of a polyurethane, acrylic or epoxy resin, a third phase in which a catalyst is added between 1530% by weight in relation to the total of the product of the second phase and a medium or slow type solvent between 15-30 % by weight in relation to the total of the product of the second phase, a fourth phase in the that some dyes are added to the concentrated solvent, a fifth phase in which the resulting product of the third phase is applied on the surface, and a sixth phase, in which the coating applied in the fifth phase is dried.

ANTECEDENTES DE LA INVENCIONBACKGROUND OF THE INVENTION

Pertenecen al estado de la tecnica la aplicacion de recubrimientos electrolrticos sobre todo tipo de metales, mediante un proceso conocido como proceso galvanico de niquelado y cromado, que consiste basicamente en las siguientes fases o etapasThe application of electrolytic coatings on all types of metals belong to the state of the art, by means of a process known as nickel plating and chromium plating process, which basically consists of the following phases or stages

1 Desengrase por ultrasonidos.1 Ultrasonic degreasing.

2 Enjuague en agua.2 Rinse in water.

3 Desengrase electrolrtico.3 Electrolytic degreasing.

4 Enjuague en agua.4 Rinse in water.

5 Neutralizado y decapado para preparation para niquelar.5 Neutralized and pickled for preparation to nickel.

6 Niquelado de 20 a 30 minutos, depositando aproximadamente una micra por minuto.6 Nickel plating for 20 to 30 minutes, depositing approximately one micron per minute.

7 Enjuague en agua de recuperation.7 Rinse in recovery water.

8 Enjuague en agua destilada.8 Rinse in distilled water.

9 Activado de niquel para cromar.9 Nickel activated for chrome.

10 Cromado, de 1 a 3 minutos, depositando 0.15^ por minuto.10 Chrome, 1 to 3 minutes, depositing 0.15 ^ per minute.

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11 Enjuague de recuperacion de bano de cromo11 Chrome bath recovery rinse

12 Neutralizado con bisulfito sodico.12 Neutralized with sodium bisulfite.

13 Enjuague con agua.13 Rinse with water.

14 Enjuague con agua destilada.14 Rinse with distilled water.

15 Secado por aire caliente.15 Hot air drying.

Se conoce la Patente Europea n° 2087147 (ES2366262T3) “PROCEDIMIENTO NO ELECTROLmCO PERFECCIONADO DE METALIZACION DE UN SUSTRATO POR REDUCCION DE SAL(ES) METALICA(S) Y POR PROYECCION DE AEROSOL(ES)”, del ano 2007, a nombre de JET METAL TECHNOLOGIES, que se refiere a un procedimiento no electrolrtico perfeccionado de metalizacion de al menos una parte de la superficie de un sustrato (a continuation denominada superficie que hay que metalizar), por proyeccion con medios adaptados de al menos un aerosol acuoso y/u organico que contienen al menos un metal en forma cationica (oxidante) y al menos un reductor, apto para transformar el cation metalico en metal, del tipo de los que consisten esencialmente en: a- eventualmente sensibilizar y/o activar la superficie que hay que metalizar; b- realizar la proyeccion de metalizacion de acuerdo con una sucesion de al menos dos fases de proyeccion, en alternancia con unas fases de relajacion: (i) fijando la duration Dp de las fases de proyeccion entre 10 -2 y 5 s, de preferencia entre 10 -1 y 3 s para una misma unidad de superficie, y la duracion Dr de las fases de relajacion entre 10 -2 y 10 s, de preferencia entre 2 x 10 -1 y 4 s para una misma unidad de superficie, siendo las duraciones Dp y Dr de estas fases de proyeccion y de relajacion iguales o diferentes entre si, (ii) y ajustando el (los) flujo(s) de proyeccion, de tal manera que la relation electronica Ox/Red este comprendida entre 0,01 y 15, de preferencia entre 0,5 y 8, y permitir de este modo la formation de una pelicula metalica quimicamente adherente al sustrato; c- interrumpir la proyeccion desde que se alcanza la tasa de deposito del metal prevista, caracterizado por el hecho de que el perfeccionamiento consiste en particular en que se preve:European Patent No. 2087147 (ES2366262T3) "PERFECTED METHODIZATION OF A SUBSTRATE FOR METALIZATION OF SALT (ES) METALLIC (S) AND AEROSOL PROJECTION (ES)", of the year 2007, in the name of JET METAL TECHNOLOGIES, which refers to an improved non-electrolytic process of metallization of at least a part of the surface of a substrate (then called the surface to be metallized), by projection with means adapted from at least one aqueous aerosol and / or organic containing at least one metal in cationic form (oxidant) and at least one reducer, suitable for transforming the metal cation into metal, of the type that consist essentially of: eventually sensitizing and / or activating the surface to be metallize; b- carry out the metallization projection according to a succession of at least two projection phases, in alternation with some relaxation phases: (i) setting the duration Dp of the projection phases between 10 -2 and 5 s, preferably between 10 -1 and 3 s for the same surface unit, and the duration Dr of the relaxation phases between 10 -2 and 10 s, preferably between 2 x 10 -1 and 4 s for the same surface unit, being the durations Dp and Dr of these projection and relaxation phases equal or different from each other, (ii) and adjusting the projection flow (s), such that the Ox / Red electronic ratio is between 0, 01 and 15, preferably between 0.5 and 8, and thus allow the formation of a chemically adherent metal film to the substrate; c- interrupt the projection since the expected metal deposit rate is reached, characterized by the fact that the improvement consists in particular in that it is foreseen:

- poner en practica al menos una etapa previa - ap - de mojado del sustrato que consiste en poner a este ultimo en contacto con al menos un fluido de mojado, de tal manera que forme sobre al menos una parte de su superficie una pelicula liquida;- put into practice at least one previous stage - ap - of wetting the substrate which consists in putting the latter in contact with at least one wetting fluid, in such a way that it forms on at least a part of its surface a liquid film;

- y, a continuacion del mojado - ap -, comenzar la proyeccion de acuerdo con la etapa - b - en un maximo de 60 s, de preferencia en un maximo de 40 s, y de forma aun mas preferente, en un maximo de 20 s tras la finalization del mojado.- and, after the wet - ap -, start the projection according to stage - b - in a maximum of 60 s, preferably in a maximum of 40 s, and even more preferably, in a maximum of 20 s after the end of the wet.

BREVE DESCRIPCION DE LA INVENCIONBRIEF DESCRIPTION OF THE INVENTION

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La presente solicitud se enmarca dentro del sector de los procedimientos para el recubrimiento de cromados y niquelados.The present application is framed within the sector of the procedures for coating chrome and nickel plating.

El documento mas cercano es la patente Europea n° 2087147 (ES2366262). Este documento soluciona el problema de la fiabilidad de la adhesion al sustrato de las peliculas de metalizacion, mejorando a la patente FR2763962.The closest document is European Patent No. 2087147 (ES2366262). This document solves the problem of the reliability of the adhesion to the substrate of the metallization films, improving the patent FR2763962.

Esta patente tiene el inconveniente que no menciona para nada la posibilidad de aplicar y dar color al revestimiento, es decir, el color viene dado por la pelicula que se aplica y de los minerales que contenga, y no por la voluntad del comprador que lo puede querer en cualquier color existente en la actualidad.This patent has the disadvantage that does not mention at all the possibility of applying and giving color to the coating, that is, the color is given by the film that is applied and the minerals it contains, and not by the will of the buyer who can want in any color existing today.

Ademas en metales como la plata, ese color tiene una vida de 1 dia sin que pierda las caracteristicas esenciales, algo que para producciones grandes si es viable, pero que resulta por el contrario inviable para producciones pequenas.In addition to metals such as silver, that color has a life of 1 day without losing the essential characteristics, something that for large productions is viable, but which is otherwise unfeasible for small productions.

El inventor ha desarrollado un nuevo procedimiento y barniz que permite la aplicacion del color que se desee, es decir, desde la aplicacion de una tinta incolora que respetaria el color original de la superficie sobre la que se aplica el barniz, a diferentes colores metalicos o no.The inventor has developed a new procedure and varnish that allows the application of the desired color, that is, from the application of a colorless ink that would respect the original color of the surface on which the varnish is applied, to different metallic colors or no.

Asimismo, mediante el solicitado procedimiento, se obtiene un producto que es duradero en el tiempo, por ejemplo, en los primeros tests se ha conseguido dos meses de duracion para un barniz sobre plata, lo que lo hace tambien viable para producciones pequenas.Likewise, by means of the requested procedure, a product is obtained that is durable over time, for example, in the first tests two months have been achieved for a varnish on silver, which also makes it viable for small productions.

Es un objeto de la presente invencion un procedimiento para la aplicacion de un recubrimiento a cromados, niquelados o pulidos y barniz de revestimiento del tipo que comprende una primera fase en la que se limpia o desengrasa la superficie del cromado, niquelado o pulido a tratar, caracterizado porque comprende: una segunda fase en que se aplica un revestimiento sobre la superficie de un barniz del tipo poliuretano, acrilico o epoxi y comprende las siguientes proporciones: entre un 0,1-1% en peso del total de estirenos, entre un 1-5% en peso del total de tolueno, entre un 1-5% en peso del total de acetato de 1- metil-2-metoxietileno, entre un 30-60% en peso del total de 4-metil-2-pentanona, y entre un 30-60% en peso del total de una resina poliuretana, acrilica o epoxi, una tercera fase en la que se anade un catalizador entre el 15-30% en peso en relacion al total del producto de la segunda fase y un disolvente tipo medio o lento entre el 15-30% en peso en relacion al total del producto de la segunda fase, una cuarta fase en la que se anaden unos tintes alIt is an object of the present invention a process for the application of a coating to chrome, nickel plated or polished and coating varnish of the type comprising a first phase in which the surface of the chrome plating, nickel plating or polishing to be treated, is cleaned or degreased, characterized in that it comprises: a second phase in which a coating is applied on the surface of a varnish of the polyurethane, acrylic or epoxy type and comprises the following proportions: between 0.1-1% by weight of the total styrenes, between 1 -5% by weight of total toluene, between 1-5% by weight of total 1- methyl-2-methoxyethylene acetate, between 30-60% by weight of total 4-methyl-2-pentanone, and between 30-60% by weight of the total of a polyurethane, acrylic or epoxy resin, a third phase in which a catalyst is added between 15-30% by weight in relation to the total of the product of the second phase and a medium or slow type solvent between 15-30% by weight in relation to the total product or of the second phase, a fourth phase in which some dyes are added to the

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disolvente concentrado, una quinta fase en la que se aplica el producto resultante de la tercera fase sobre la superficie, y una sexta fase, en la que el recubrimiento aplicado en la quinta fase se seca.concentrated solvent, a fifth phase in which the product resulting from the third phase is applied on the surface, and a sixth phase, in which the coating applied in the fifth phase is dried.

Es un objeto adicional de la presente invencion un barniz de revestimiento de acuerdo con el procedimiento anterior, caracterizado porque es del tipo poliuretano, acrilico o epoxi y comprende las siguientes proporciones: entre un 0,1-1% en peso del total de estirenos, entre un 1-5% en peso del total de tolueno, entre un 1-5% en peso del total de acetato de 1- metil-2-metoxietileno, entre un 30-60% en peso del total de 4-metil-2-pentanona, y entre un 30-60% en peso del total de una resina poliuretana, acrilica o epoxi, con una densidad de 16 a 17 segundos Copa Ford 4 a 20°C, y; unos tintes al disolvente concentrado que se anaden a la composition anterior en proporciones segun el color e intensidad que se quieran obtener.It is a further object of the present invention a coating varnish according to the above procedure, characterized in that it is of the polyurethane, acrylic or epoxy type and comprises the following proportions: between 0.1-1% by weight of the total styrenes, between 1-5% by weight of total toluene, between 1-5% by weight of total 1- methyl-2-methoxyethylene acetate, between 30-60% by weight of total 4-methyl-2 -pentanone, and between 30-60% by weight of the total of a polyurethane resin, acrylic or epoxy, with a density of 16 to 17 seconds Ford Cup 4 at 20 ° C, and; concentrated solvent dyes that are added to the previous composition in proportions according to the color and intensity that they want to obtain.

CONCRETA REALIZACION DE LA PRESENTE INVENCIONCONCRETE REALIZATION OF THE PRESENT INVENTION

Asi, en una concreta realization, La tecnica de aplicacion consiste en la siguiente:Thus, in a concrete realization, the application technique consists of the following:

Antes de aplicar el barniz sobre la superficie de un cromado, niquelado o metal pulido, en una primera fase el operario se asegurara de que la superficie esta totalmente limpia y exenta de residuos. En caso de requerirse, se debe desengrasar o limpiar cuidadosamente. En una segunda fase un barniz del tipo poliuretano, acrilico o epoxi con las siguientes proporciones:Before applying the varnish on the surface of a chrome plating, nickel plating or polished metal, in an initial phase the operator will ensure that the surface is completely clean and free of debris. If required, it must be carefully degreased or cleaned. In a second phase a varnish of the polyurethane, acrylic or epoxy type with the following proportions:

- entre un 0,1-1% en peso del total de estirenos,- between 0.1-1% by weight of total styrenes,

- entre un 1-5% en peso del total de tolueno,- between 1-5% by weight of total toluene,

- entre un 1-5% en peso del total de acetato de 1-metil-2-metoxietileno,- between 1-5% by weight of the total 1-methyl-2-methoxyethylene acetate,

- entre un 30-60% en peso del total de 4-metil-2-pentanona, y- between 30-60% by weight of the total 4-methyl-2-pentanone, and

- entre un 30-60% en peso del total de una resina poliuretana, acrilica o epoxi,- between 30-60% by weight of the total of a polyurethane, acrylic or epoxy resin,

se aplica con una pistola de pintura aerografica. En esta realizacion se empleara este modelo de aplicacion aun cuando no es el unico, ya que se podrian igualmente emplear otras formas de aplicacion como la aplicacion a cortina o con la misma forma de aplicacion aerografica de manera automatizada. En estos casos se deberian ajustar las viscosidades para hacerlas compatibles con los sistemas de aplicacion.It is applied with a spray gun. In this embodiment, this application model will be used even when it is not the only one, since other forms of application such as curtain application or with the same form of automated air application could also be used. In these cases the viscosities should be adjusted to make them compatible with the application systems.

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En la tercera fase se anade al barniz de la segunda fase un catalizador entre el 15-30% en peso en relacion al total del producto de la segunda fase, y a continuacion un disolvente de tipo medio o lento entre el 15-30% en peso en relacion al total del producto de la segunda fase.In the third phase a catalyst between 15-30% by weight is added to the varnish of the second phase in relation to the total of the product of the second phase, and then a medium or slow type solvent between 15-30% by weight in relation to the total of the product of the second phase.

En la cuarta fase se anaden unos tintes al disolvente concentrado, para dar un determinado color. Luego, como se explicara mas adelante, dependiendo del objeto a cubrir, se precisaran una o mas capas de barniz.In the fourth phase dyes are added to the concentrated solvent, to give a certain color. Then, as explained below, depending on the object to be covered, one or more layers of varnish will be required.

Posteriormente, en la quinta fase, se aplica el producto resultante de la cuarta fase se aplica sobre la superficie (mediante una pistola de pintura aerografica) utilizando abierto al maximo o patron de traslapo mmimo del 75%. El paso de producto 1,5 vueltas, a una presion de unos 3 kilos.Subsequently, in the fifth phase, the product resulting from the fourth phase is applied and applied on the surface (by means of an air spray gun) using the maximum or maximum 75% overlap pattern. The product passes 1.5 laps, at a pressure of about 3 kilos.

La sexta fase es la fase de secado, que existen muchas alternativas, algunas de las cuales se mencionaran a continuacion.The sixth phase is the drying phase, there are many alternatives, some of which will be mentioned below.

Asi, se debe permitir que el revestimiento se estire y evapore bien durante 30-40 minutos antes de hornear a 60°C durante 1 hora. Posteriormente se dejara secar al aire durante varias horas. Este secado puede durar hasta 5-10 dias.Thus, the coating should be allowed to stretch and evaporate well for 30-40 minutes before baking at 60 ° C for 1 hour. It will then be allowed to air dry for several hours. This drying can last up to 5-10 days.

Para el secado al aire, se debe dejar 30 minutos en un ambiente recirculante de aire durante 30 minutos, y colocar despues en una zona libre de impurezas y polvo durante varias horas. El endurecimiento total se consigue a los 5-10 dias, pero a las 24 horas ya se puede manipular la pieza.For air drying, leave 30 minutes in an air recirculating environment for 30 minutes, and then place in an area free of impurities and dust for several hours. Total hardening is achieved after 5-10 days, but after 24 hours the piece can be handled.

En el caso que se aplicasen mas de 2 revestimientos o capas de barniz, se debe dejar algo mas de 24 horas antes de manipular, para conseguir un secado mas efectivo.In the case that more than 2 coatings or layers of varnish were applied, it should be left a little more than 24 hours before handling, to achieve a more effective drying.

Si fueran, por ejemplo, necesarias 2-3 capas para conseguir el color deseado sobre el objeto. Asi, se aplicaria la primera capa humeda. Posteriormente se esperaria unos 10 minutos y a continuacion se procederia con una segunda capa que cubriria el revestimiento ya dispuesto sobre la superficie. La segunda capa cubrira el revestimiento y producira un color mas intenso. La segunda capa puede aplicarse un poco mas concentrada, o bien en dos manos cruzadas y finas en la misma capa (igualmente humeda pero mas fina). Si se desea, se puede esta vez abrir un cuarto de vuelta mas el paso de producto.If, for example, 2-3 layers were necessary to achieve the desired color on the object. Thus, the first wet layer would be applied. Subsequently it would wait about 10 minutes and then proceed with a second layer that would cover the coating already arranged on the surface. The second layer will cover the lining and produce a more intense color. The second layer can be applied a little more concentrated, or in two hands crossed and thin in the same layer (equally moist but thinner). If desired, this time you can open a quarter of a turn plus the product step.

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Si se desea, se puede aplicar una tercera capa de revestimiento pero esperando otros 10 minutos adicionales.If desired, a third layer of coating can be applied but waiting another 10 additional minutes.

Luego vendrian las capas de secado antes explicadas.Then the drying layers explained above would come.

El barniz de revestimiento de acuerdo con el procedimiento anterior, es del tipo poliuretano, acrilico o epoxi y comprende las siguientes proporciones:The coating varnish according to the above procedure is of the polyurethane, acrylic or epoxy type and comprises the following proportions:

- entre un 0,1-1% en peso del total de estirenos,- between 0.1-1% by weight of total styrenes,

- entre un 1-5% en peso del total de tolueno,- between 1-5% by weight of total toluene,

- entre un 1-5% en peso del total de acetato de 1-metil-2-metoxietileno,- between 1-5% by weight of the total 1-methyl-2-methoxyethylene acetate,

- entre un 30-60% en peso del total de 4-metil-2-pentanona, y- between 30-60% by weight of the total 4-methyl-2-pentanone, and

- entre un 30-60% en peso del total de una resina poliuretana, acrilica o epoxi, con una densidad de 16 a 17 segundos Copa Ford 4 a 20°, y unos tintes al disolvente concentrado que se anaden al barniz anterior en proporciones segun el color e intensidad que se quieran obtener.- between 30-60% by weight of the total of a polyurethane, acrylic or epoxy resin, with a density of 16 to 17 seconds Ford Cup 4 at 20 °, and concentrated solvent dyes that are added to the previous varnish in proportions according to the color and intensity that you want to get.

Un ejemplo de realization del barniz contendria las siguientes proporciones:An example of varnish realization would contain the following proportions:

- un 0,7% en peso del total de estirenos,- 0.7% by weight of the total styrene,

- un 4% en peso del total de tolueno,- 4% by weight of total toluene,

- un 4% en peso del total de acetato de 1-metil-2-metoxietileno,- 4% by weight of the total 1-methyl-2-methoxyethylene acetate,

- un 35,10% en peso del total de 4-metil-2-pentanona, y- 35.10% by weight of the total 4-methyl-2-pentanone, and

- un 56,20% en peso del total de una resina poliuretana, acrilica o epoxi. con una densidad de 16 a 17 segundos Copa Ford 4 a 20°.- 56.20% by weight of the total of a polyurethane, acrylic or epoxy resin. with a density of 16 to 17 seconds Ford Cup 4 to 20 °.

Como se ha indicado anteriormente, el tema del color vendria determinado por el tinte al disolvente concentrado que se anada al barniz, que dependiendo del color y la intensidad escogida por la persona, variaran. Es decir, se puede escoger un tono a medida, dependiendo de como vaya quedando, se puede anadir un tinte al disolvente concentrado con una intensidad u otra.As indicated above, the theme of the color would be determined by the concentrated solvent dye that is added to the varnish, which will vary depending on the color and intensity chosen by the person. That is, a custom shade can be chosen, depending on how it remains, a dye can be added to the concentrated solvent with one intensity or another.

La presente patente de invention describe un procedimiento para la aplicacion de un recubrimiento a cromados, niquelados o pulidos y barniz de revestimiento. Los ejemplos aqu mencionados no son limitativos de la presente invencion, por ello podra tener distintasThe present invention patent describes a process for applying a coating to chrome, nickel plated or polished and coating varnish. The examples mentioned here are not limiting of the present invention, so it may have different

aplicaciones y/o adaptaciones, todas ellas dentro del alcance de las siguientes reivindicaciones.applications and / or adaptations, all of them within the scope of the following claims.

Claims (4)

55 1010 15fifteen 20twenty 2525 3030 3535 REIVINDICACIONES 1. Procedimiento para la aplicacion de un recubrimiento a cromados, niquelados o pulidos, del tipo que comprende una primera fase en la que se limpia o desengrasa la superficie del cromado, niquelado o pulido a tratar, caracterizado porque comprende:1. Procedure for the application of a coating to chrome plated, nickel-plated or polished, of the type that comprises a first phase in which the surface of the chrome plated, nickel-plated or polished to be treated is cleaned or degreased, characterized in that it comprises: una segunda fase en que se aplica un revestimiento sobre la superficie de un barniz del tipo poliuretano, acrilico o epoxi y comprende las siguientes proporciones:a second phase in which a coating is applied on the surface of a varnish of the polyurethane, acrylic or epoxy type and comprises the following proportions: - entre un 0,1-1% en peso del total de estirenos,- between 0.1-1% by weight of total styrenes, - entre un 1-5% en peso del total de tolueno,- between 1-5% by weight of total toluene, - entre un 1-5% en peso del total de acetato de 1-metil-2-metoxietileno,- between 1-5% by weight of the total 1-methyl-2-methoxyethylene acetate, - entre un 30-60% en peso del total de 4-metil-2-pentanona, y- between 30-60% by weight of the total 4-methyl-2-pentanone, and - entre un 30-60% en peso del total de una resina poliuretana, acrilica o epoxi,- between 30-60% by weight of the total of a polyurethane, acrylic or epoxy resin, una tercera fase en la que se anade un catalizador entre el 15-30% en peso en relacion al total del producto de la segunda fase y un disolvente tipo medio o lento entre el 1530% en peso en relacion al total del producto de la segunda fase, una cuarta fase en la que se anaden unos tintes al disolvente concentrado, una quinta fase en la que se aplica el producto resultante de la tercera fase sobre la superficie, ya third phase in which a catalyst is added between 15-30% by weight in relation to the total of the product of the second phase and a medium or slow type solvent between 1530% by weight in relation to the total product of the second phase, a fourth phase in which dyes are added to the concentrated solvent, a fifth phase in which the product resulting from the third phase is applied on the surface, and una sexta fase, en la que el recubrimiento aplicado en la quinta fase se seca.a sixth phase, in which the coating applied in the fifth phase dries. 2. Procedimiento, de acuerdo con la reivindicacion 1, caracterizado porque en la cuarta fase se aplican diferentes capas de barniz con tintes al disolvente concentrado hasta alcanzar el color deseado.2. Method according to claim 1, characterized in that in the fourth phase different layers of varnish are applied with dyes to the concentrated solvent until reaching the desired color. 3. Procedimiento, de acuerdo con la reivindicacion 1, caracterizado porque la fase quinta de secado comprende una fase de horneado del recubrimiento sobre la superficie.3. Method according to claim 1, characterized in that the fifth drying phase comprises a baking phase of the coating on the surface. 4. Barniz de revestimiento de acuerdo con el procedimiento anterior, caracterizado porque es del tipo poliuretano, acrilico o epoxi y comprende las siguientes proporciones:4. Coating varnish according to the above procedure, characterized in that it is of the polyurethane, acrylic or epoxy type and comprises the following proportions: - entre un 0,1-1% en peso del total de estirenos,- between 0.1-1% by weight of total styrenes, - entre un 1-5% en peso del total de tolueno,- between 1-5% by weight of total toluene, - entre un 1-5% en peso del total de acetato de 1-metil-2-metoxietileno,- between 1-5% by weight of the total 1-methyl-2-methoxyethylene acetate, - entre un 30-60% en peso del total de 4-metil-2-pentanona, y- between 30-60% by weight of the total 4-methyl-2-pentanone, and 99 - entre un 30-60% en peso del total de una resina poliuretana, acrilica o epoxi, con una densidad de 16 a 17 segundos Copa Ford 4 a 20°C, y; unos tintes al disolvente concentrado que se anaden a la composicion anterior en proporciones segun el color e intensidad que se quieran obtener.- between 30-60% by weight of the total of a polyurethane, acrylic or epoxy resin, with a density of 16 to 17 seconds Ford Cup 4 at 20 ° C, and; concentrated solvent dyes that are added to the previous composition in proportions according to the color and intensity that they want to obtain. 55
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