CN103556199A - Crystal film and coating technology thereof - Google Patents
Crystal film and coating technology thereof Download PDFInfo
- Publication number
- CN103556199A CN103556199A CN201310362311.8A CN201310362311A CN103556199A CN 103556199 A CN103556199 A CN 103556199A CN 201310362311 A CN201310362311 A CN 201310362311A CN 103556199 A CN103556199 A CN 103556199A
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- crystal
- film
- film coating
- crystal film
- coating method
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- 239000013078 crystal Substances 0.000 title claims abstract description 41
- 238000000576 coating method Methods 0.000 title claims abstract description 27
- 239000011248 coating agent Substances 0.000 title claims abstract description 21
- 238000005516 engineering process Methods 0.000 title abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 29
- 239000000919 ceramic Substances 0.000 claims abstract description 20
- 239000011521 glass Substances 0.000 claims abstract description 16
- 239000007788 liquid Substances 0.000 claims abstract description 15
- 238000005507 spraying Methods 0.000 claims abstract description 10
- 239000007888 film coating Substances 0.000 claims description 19
- 238000009501 film coating Methods 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 13
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 239000004615 ingredient Substances 0.000 claims description 10
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- SPAGIJMPHSUYSE-UHFFFAOYSA-N Magnesium peroxide Chemical compound [Mg+2].[O-][O-] SPAGIJMPHSUYSE-UHFFFAOYSA-N 0.000 claims description 4
- 229960004995 magnesium peroxide Drugs 0.000 claims description 4
- 230000002269 spontaneous effect Effects 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 239000000470 constituent Substances 0.000 claims description 3
- 239000000428 dust Substances 0.000 abstract description 4
- 229910010272 inorganic material Inorganic materials 0.000 abstract description 3
- 239000011147 inorganic material Substances 0.000 abstract description 3
- 239000003973 paint Substances 0.000 abstract description 2
- 230000001376 precipitating effect Effects 0.000 abstract 1
- 239000008399 tap water Substances 0.000 description 7
- 235000020679 tap water Nutrition 0.000 description 7
- CMHXYXQNKLCTDV-UHFFFAOYSA-N boric acid;silicon Chemical compound [Si].OB(O)O CMHXYXQNKLCTDV-UHFFFAOYSA-N 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 230000018109 developmental process Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 238000005868 electrolysis reaction Methods 0.000 description 2
- 238000009713 electroplating Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000013307 optical fiber Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 238000007747 plating Methods 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000003364 biologic glue Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
Images
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- Application Of Or Painting With Fluid Materials (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Chemically Coating (AREA)
Abstract
The invention provides a crystal film and a coating technology thereof, and belongs to the exterior spraying coating field. The coating technology comprises the following steps: introducing warm water into a ceramic magnetic core, and ionizing to obtain a coating agent and active water; uniformly mixing the coating agent with the active water according to a certain ratio to obtain a crystal coating liquid; injecting the crystal coating liquid to the surface of an object for processing through a high pressure cleaner, and precipitating a glass component; binding the glass component with the surface of the negatively charged object for processing, reacting with water in air, and naturally solidifying to form the crystal film. The crystal film is a pure inorganic material, is difficult to oxidize, realizes the 2-3 time prolongation of the life of a paint film, has a film thickness of 30-40nm, has an extremely good hydrophilic performance and can greatly reduce the adhesion capabilities of dust and organisms.
Description
Technical field
The present invention relates to a kind of exterior spraying coating process, be specifically related to a kind of crystal film and coating process thereof.
Background technology
Along with the development of scientific progress, industrial technology, to metal with nonmetallic surface is armor coated or ornament layer, by manual to industrial automation future development, and the degree of new technology development application is more and more higher, so plated film application is also more and more extensive.
Traditional coating process mainly comprises: one, adopt special fixtures and Special precision optical fiber filming equipment to carry out plated film; Two, organic solvent spraying method, wherein, technique one is because the price of special fixtures and Special precision optical fiber filming equipment is very high, cost is huge, and special fixtures is comparatively accurate, easy cleaning not, the easily problem such as damage and not applying; Organic solvent spraying method, this technique oxidation-resistance is poor, easily aging, hardness is low, wear no resistance, oil resistant, salt, acid, alkalescence are poor.
In view of above-mentioned problems of the prior art, the present invention, according to the characteristic of existing plated film, fundamentally improves existing technique, and a kind of coating process is provided, and strengthens its surface treatment intensity and Practical Performance.
Summary of the invention
The invention provides a kind of crystal film and coating process thereof, this crystal film is pure inorganic materials, it is oxidized to be difficult for, and has fabulous hydrophilicity, can significantly reduce dust, biological adhesive ability.
One of task of the present invention is to provide a kind of crystal film:
, this crystal film thickness is 30～40 nanometers, more than hardness reaches 3.0GPA, anti-scratch has very strong toughness simultaneously.
Two of task of the present invention is to provide the film coating method of above-mentioned crystal film:
This film coating method comprises the following steps:
A) water of 30～50 ℃ is passed into take after the ceramic magnetic core that piezoelectric ceramics and Magnesium peroxide be main component and ionize, obtain the step of film coating agent and active water;
B) above-mentioned film coating agent and active water are evenly mixed according to parts by weight 6～15:100, obtain the step of crystal coating liquid;
C) pending thing surface is processed and is made it electronegative, and the crystal coating liquid in step b) is ejected into pending thing surface by high-pressure washer, separates out the step of glass ingredient;
D) glass ingredient in above-mentioned positively charged crystal coating liquid and electronegative pending thing surface knot and, simultaneously and airborne moisture reacts, the step of spontaneous curing, formation crystal film.
Above-mentioned steps a) the effective constituent of middle film coating agent is Perhydropolysilazane.
Above-mentioned steps b) in, active water hydraulic pressure keeps 1.7～1.9Kg.
Above-mentioned steps c) pending thing is metal, ceramic tile or glass.
Above-mentioned steps c) high-pressure washer spraying pressure is 4.9MPa.
The useful technique effect that the present invention brings:
The invention provides a kind of crystal film and coating process thereof, compared with prior art, crystal film of the present invention is pure inorganic materials, is difficult for oxidizedly, extends 2～3 times of paint film life-spans; The water of 30～50 ℃ is passed into and be take after the ceramic magnetic core that piezoelectric ceramics and Magnesium peroxide be main component, and ceramic magnetic core makes water electrolysis, increases its activity, becomes the abstersive active water of tool; Then active water is mixed according to certain ratio with film coating agent, obtain crystal coating liquid, crystal coating liquid is ejected into electronegative pending thing surface by high-pressure washer, and the glass ingredient of separating out is after boric acid silicon molecule and electronegative pending thing surface bonding, ambient cure, to form the crystal film of high rigidity.Crystal film thickness of the present invention is 30～40 nanometers, has fabulous hydrophilicity, can significantly reduce the adhesive ability of dust, biology.
Accompanying drawing explanation
Below in conjunction with accompanying drawing and embodiment, the present invention will be further described:
Fig. 1 is Principle of plating figure of the present invention.
Embodiment
The invention provides a kind of crystal film and coating process thereof, in order to make object of the present invention, technical scheme and advantage clearer, clear and definite, below with reference to specific embodiment, the present invention is described in more detail.
Embodiment 1:
The film coating method of crystal film of the present invention comprises following four steps:
Step a:
First utilize automatic heating system, by tap water heating to 30 ℃, ceramic magnetic core is provided, it is main component that this ceramic magnetic core be take piezoelectric ceramics and Magnesium peroxide, it is the ceramic magnetic core of 220 volts that the tap water that is 30 ℃ by temperature passes into above-mentioned voltage, tap water ionizes, and forms and has dissolved in the film coating agent that has ceramic magnetic core to separate out, and the effective constituent of this film coating agent is Perhydropolysilazane; Ceramic core, for making water carry out electrolysis, increases its activity, becomes the abstersive active water of tool;
Step b:
Active water is chosen to be 1.7Kg, and film coating agent and active water are evenly mixed according to parts by weight 6:100, obtains crystal coating liquid;
Step c:
Metal, ceramic tile or glass surface are processed and made it electronegative, the present invention adopts the principle of plating to make pending thing surface with negative charge, crystal coating liquid in step b) is ejected into metal, ceramic tile or glass surface by high-pressure washer, the spraying pressure of high-pressure washer is 4.9MPa, after spraying, separate out glass ingredient, glass ingredient is boric acid silicon molecule;
Steps d:
Glass ingredient in positively charged crystal coating liquid and electronegative pending thing surface knot and, simultaneously and airborne moisture reacts, spontaneous curing, formation crystal film.
Embodiment 2:
Difference from Example 1 is: step a tap water temperature is heated to 40 ℃, and active water is chosen to be 1.8Kg.
Embodiment 3:
Difference from Example 1 is: step a tap water temperature is heated to 50 ℃, and active water is chosen to be 1.9Kg.
With reference to above-described embodiment 1 step a, b, c, d, plated film mechanism of the present invention as shown in Figure 1:
As shown in Figure 1a: the water by ceramic magnetic core is active water, become weakly alkaline, neutralize the organic compositions such as chlorine element in former tap water, simultaneously by after the ceramic magnetic core of 220 volts, tap water ionizes, and becoming very little molecular water is active water, and active water has cleaning action, the ability of cleaning improves, with reference to step c, after spraying, separate out glass ingredient;
As shown in Figure 1 b: the impact electronics that utilizes crystal coating liquid to occur to time on outer wall with high pressure spraying, according to the principle of electroplating, make pending thing surface band negative charge, make it with positively charged crystal coating liquid in glass ingredient combine, simultaneously and water in air vapor reaction and form molten mass, molten mass is the water surface film after uncured;
As shown in Fig. 1 c: according to the principle of electroplating, the protective layer molecule of pending thing and the molecule of boric acid silicon can be closely linked, and after above-mentioned molten mass spontaneous curing, finally obtain crystal film of the present invention.
The property indices of crystal film is as shown in table 1:
Table 1
Crystal film thickness of the present invention is 30～40 nanometers, and more than hardness reaches 3.0GPA, anti-scratch has very strong toughness simultaneously, has fabulous hydrophilicity, can significantly reduce the adhesive ability of dust, biology.
Should be understood that; those of ordinary skill in the art is under enlightenment of the present invention; not departing from the scope situation that the claims in the present invention protect, can also make the various deformation such as replacement, simple combination, the scope of asking for protection of the present invention should be as the criterion with claims.
Claims (6)
1. a crystal film, is characterized in that: described crystal film thickness is 30～40 nanometers, more than hardness reaches 3.0GPA.
2. the film coating method of crystal film as claimed in claim 1, is characterized in that described film coating method comprises the following steps:
A) water of 30～50 ℃ is passed into take after the ceramic magnetic core that piezoelectric ceramics and Magnesium peroxide be main component and ionize, obtain the step of film coating agent and active water;
B) above-mentioned film coating agent and active water are evenly mixed according to parts by weight 6～15:100, obtain the step of crystal coating liquid;
C) pending thing surface is processed and is made it electronegative, and the crystal coating liquid in step b) is ejected into pending thing surface by high-pressure washer, separates out the step of glass ingredient;
D) glass ingredient in above-mentioned positively charged crystal coating liquid and electronegative pending thing surface knot and, simultaneously and airborne moisture reacts, the step of spontaneous curing, formation crystal film.
3. film coating method according to claim 2, is characterized in that: in described step a), the effective constituent of film coating agent is Perhydropolysilazane.
4. film coating method according to claim 3, is characterized in that: in described step b), active water hydraulic pressure keeps 1.7～1.9Kg.
5. according to the film coating method described in claim 2 or 3, it is characterized in that: the pending thing of described step c) is metal, ceramic tile or glass.
6. according to the film coating method described in claim 2 or 3, it is characterized in that: described step c) high-pressure washer spraying pressure is 4.9MPa.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310362311.8A CN103556199B (en) | 2013-08-19 | 2013-08-19 | A kind of crystal film and coating process thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310362311.8A CN103556199B (en) | 2013-08-19 | 2013-08-19 | A kind of crystal film and coating process thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103556199A true CN103556199A (en) | 2014-02-05 |
| CN103556199B CN103556199B (en) | 2016-08-10 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310362311.8A Active CN103556199B (en) | 2013-08-19 | 2013-08-19 | A kind of crystal film and coating process thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN103556199B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107525766A (en) * | 2017-08-03 | 2017-12-29 | 天津中环电炉股份有限公司 | The device and method of object thermal imaging under a kind of high temperature |
| CN114751657A (en) * | 2022-05-26 | 2022-07-15 | 武汉市汉泓福玻璃有限公司 | Coated toughened glass and production process thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101080282A (en) * | 2004-12-17 | 2007-11-28 | 国立大学法人德岛大学 | Method for modifying surface of base material, base material having modified surface, and method for producing same |
| CN101835847A (en) * | 2007-10-26 | 2010-09-15 | Az电子材料（日本）株式会社 | Composition containing polysilazane compound, which can provide dense siliceous film |
| CN102732926A (en) * | 2012-01-20 | 2012-10-17 | 曹博钇 | High-molecular crystal sprayed film |
-
2013
- 2013-08-19 CN CN201310362311.8A patent/CN103556199B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101080282A (en) * | 2004-12-17 | 2007-11-28 | 国立大学法人德岛大学 | Method for modifying surface of base material, base material having modified surface, and method for producing same |
| CN101835847A (en) * | 2007-10-26 | 2010-09-15 | Az电子材料（日本）株式会社 | Composition containing polysilazane compound, which can provide dense siliceous film |
| CN102732926A (en) * | 2012-01-20 | 2012-10-17 | 曹博钇 | High-molecular crystal sprayed film |
Non-Patent Citations (2)
| Title |
|---|
| 张宗波等: "全氢聚硅氮烷的应用及产业化", 《精细与专用化学品》 * |
| 肖凤艳等: "全氢聚硅氮烷制备 SiOx 涂层及其性能研究", 《稀有金属材料与工程》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107525766A (en) * | 2017-08-03 | 2017-12-29 | 天津中环电炉股份有限公司 | The device and method of object thermal imaging under a kind of high temperature |
| CN114751657A (en) * | 2022-05-26 | 2022-07-15 | 武汉市汉泓福玻璃有限公司 | Coated toughened glass and production process thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103556199B (en) | 2016-08-10 |
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| C41 | Transfer of patent application or patent right or utility model | ||
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Effective date of registration: 20160615 Address after: 266000 Shandong province Qingdao city Licang District Road No. 1020 Laoshan two unit 302 Applicant after: Li Shulan Address before: 266400 No. 788 Lingang Road, Huangdao District, Shandong, Qingdao Applicant before: QINGDAO JOWON MECHANICAL AND ELECTRICAL Co.,Ltd. |
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| CB03 | Change of inventor or designer information |
Inventor after: Cao Junsheng Inventor before: Zhang Bing Inventor before: Meng Xiangdong Inventor before: Li Maotao Inventor before: Li Yong Inventor before: Sun Pengfei |
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Effective date of registration: 20170525 Address after: 528400, No. 2, No. three, Ruyi Road, Fu Sha town, Guangdong, Zhongshan (A storey 1) Patentee after: ZHONGSHAN HONGXIANG PHOTOELECTRIC TECHNOLOGY Co.,Ltd. Address before: 266000 Shandong province Qingdao city Licang District Road No. 1020 Laoshan two unit 302 Patentee before: Li Shulan |
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Effective date of registration: 20210923 Address after: 528400 floor 2, building B, No. 13, Jingye Road, Torch Development Zone, Zhongshan City, Guangdong Province Patentee after: Fuyuan (Zhongshan) Photoelectric Technology Co.,Ltd. Address before: 528400 No.3, Ruyi Road, Fusha Town, Zhongshan City, Guangdong Province (1st floor, building a) Patentee before: ZHONGSHAN HONGXIANG PHOTOELECTRIC TECHNOLOGY Co.,Ltd. |
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| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
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Denomination of invention: A crystal film and its coating process Granted publication date: 20160810 Pledgee: Science and Technology Branch of Torch Development Zone of Zhongshan Rural Commercial Bank Co.,Ltd. Pledgor: Fuyuan (Zhongshan) Photoelectric Technology Co.,Ltd. Registration number: Y2024980013671 |