ES254089A1 - Process for activating clays with acid - Google Patents
Process for activating clays with acidInfo
- Publication number
- ES254089A1 ES254089A1 ES0254089A ES254089A ES254089A1 ES 254089 A1 ES254089 A1 ES 254089A1 ES 0254089 A ES0254089 A ES 0254089A ES 254089 A ES254089 A ES 254089A ES 254089 A1 ES254089 A1 ES 254089A1
- Authority
- ES
- Spain
- Prior art keywords
- clay
- liquor
- hydrogen chloride
- water
- slurry
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/12—Naturally occurring clays or bleaching earth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/16—Clays or other mineral silicates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/36—Silicates having base-exchange properties but not having molecular sieve properties
- C01B33/38—Layered base-exchange silicates, e.g. clays, micas or alkali metal silicates of kenyaite or magadiite type
- C01B33/40—Clays
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/36—Silicates having base-exchange properties but not having molecular sieve properties
- C01B33/38—Layered base-exchange silicates, e.g. clays, micas or alkali metal silicates of kenyaite or magadiite type
- C01B33/42—Micas ; Interstratified clay-mica products
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/36—Silicates having base-exchange properties but not having molecular sieve properties
- C01B33/46—Amorphous silicates, e.g. so-called "amorphous zeolites"
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Analytical Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
In a process for the activation of a clay, a slurry of clay and water is mixed with hydrochloric acid or hydrogen chloride gas is absorbed in the slurry, the mixture is digested at 100 DEG to 200 DEG C. for at least two hours, and, after separation of the activated clay from the resultant liquor, the chlorides contained in the liquor are converted to hydrogen chloride by steam decomposition at 500 DEG to 1000 DEG C., and recycled for the activation of further clay. The clay which may be montmorillonite, bentonite, illite or kaolinite, is milled and mixed with water to form a slurry containing 5 to 40% by weight of clay which is mixed with hydrochloric acid solution or contacted with hydrogen chloride in an absorption tower, or the clay may be mixed with hydrochloric acid solution and then milled. The digestion is carried out in a series of vessels and the liquor is separated from the activated clay by filtration, centrifuging or sedimentation, the clay being washed with water and a part of the washings added to the separated liquor. The chloride ion concentration in the liquor is increased by evaporation or by adding calcium chloride, and the liquor is subjected to steam decomposition by contacting a spray of the liquor with an oil or gas flame, to obtain hydrogen chloride vapour magnesium, aluminium, calcium and iron chlorides react with water vapour to form the oxides of these metals and hydrogen chloride, and the aluminium oxide reacts with calcium chloride and water vapour to form calcium aluminate and hydrogen chloride magnesium aluminate and iron aluminate are also formed. The hydrogen chloride is either absorbed by further clay slurry, or is absorbed in water and the hydrochloric acid added to further clay slurry. Specification 793,700 is referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB4109158A GB939937A (en) | 1958-12-19 | 1958-12-19 | Process for activating clays with acid |
Publications (1)
Publication Number | Publication Date |
---|---|
ES254089A1 true ES254089A1 (en) | 1960-04-16 |
Family
ID=34509261
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES0254089A Expired ES254089A1 (en) | 1958-12-19 | 1959-12-10 | Process for activating clays with acid |
Country Status (3)
Country | Link |
---|---|
ES (1) | ES254089A1 (en) |
FR (1) | FR1243615A (en) |
GB (1) | GB939937A (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2758551A1 (en) * | 1997-01-20 | 1998-07-24 | Henri Louis Marie Drean | Method for augmenting the porosity of clay supports such as sepiolite |
WO2000003798A1 (en) * | 1998-07-17 | 2000-01-27 | Cca Food Technologies (Uk) Plc | Treatment method and device for increasing clay porosity and use for producing absorbents |
CN116440855B (en) * | 2023-06-16 | 2023-09-05 | 格林斯达(北京)环保科技股份有限公司 | Purification material and preparation method and application thereof |
-
1958
- 1958-12-19 GB GB4109158A patent/GB939937A/en not_active Expired
-
1959
- 1959-12-10 ES ES0254089A patent/ES254089A1/en not_active Expired
- 1959-12-16 FR FR813200A patent/FR1243615A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
GB939937A (en) | 1963-10-16 |
FR1243615A (en) | 1960-10-14 |
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