ES2524909T3 - Una composición termoplástica, un método para producir la misma y artículos preparados a partir de ella - Google Patents

Una composición termoplástica, un método para producir la misma y artículos preparados a partir de ella Download PDF

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Publication number
ES2524909T3
ES2524909T3 ES13153683.1T ES13153683T ES2524909T3 ES 2524909 T3 ES2524909 T3 ES 2524909T3 ES 13153683 T ES13153683 T ES 13153683T ES 2524909 T3 ES2524909 T3 ES 2524909T3
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Prior art keywords
core
thermoplastic
thermoplastic composition
shell polymers
weight
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ES13153683.1T
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English (en)
Inventor
Paul Ralph Van Rheenen
Veera D. Nelliappan
Seth S. Stewart
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Rohm and Haas Co
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Rohm and Haas Co
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C08L25/08—Copolymers of styrene
    • C08L25/12—Copolymers of styrene with unsaturated nitriles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C08L25/08—Copolymers of styrene
    • C08L25/14—Copolymers of styrene with unsaturated esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/062—Copolymers with monomers not covered by C08L33/06
    • C08L33/066—Copolymers with monomers not covered by C08L33/06 containing -OH groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/18—Homopolymers or copolymers of nitriles
    • C08L33/20—Homopolymers or copolymers of acrylonitrile
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/53—Core-shell polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10—Homopolymers or copolymers of methacrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10—Homopolymers or copolymers of methacrylic acid esters
    • C08L33/12—Homopolymers or copolymers of methyl methacrylate

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

Una composición termoplástica que comprende el producto de mezclado en fundido de: un primer componente que comprende uno o más polímeros termoplásticos; y un segundo componente que comprende uno o más polímeros de núcleo/envoltura donde dicho uno o más polímeros de núcleo/envoltura comprenden un núcleo reticulado que comprende un copolímero de (met)acrilato que presenta una temperatura de transición vítrea igual o superior a 10ºC y entre 0,001 y 0,04 partes en peso por cada cien partes en peso del peso total del uno o más monómeros de (met)acrilato derivados de uno o más monómeros reticulantes y/o agentes de unión de injerto, y una o más envolturas termoplásticas, opcionalmente reticuladas, que presentan una Tg igual o superior a 60ºC donde la cantidad total de la una o más envolturas comprende entre un 5 y un 50% del peso total del uno o más polímeros de núcleo/envoltura, y donde la temperatura de transición vítrea se mide mediante calorimetría de barrido diferencial con una rampa de 10ºC/min desde temperatura ambiente y hasta 180ºC.
ES13153683.1T 2010-10-29 2011-10-24 Una composición termoplástica, un método para producir la misma y artículos preparados a partir de ella Active ES2524909T3 (es)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US40820310P 2010-10-29 2010-10-29
US408203P 2010-10-29
US201113270040 2011-10-10
US13/270,040 US9051459B2 (en) 2010-10-29 2011-10-10 Thermoplastic composition, method of producing the same, and articles made therefrom

Publications (1)

Publication Number Publication Date
ES2524909T3 true ES2524909T3 (es) 2014-12-15

Family

ID=44992565

Family Applications (2)

Application Number Title Priority Date Filing Date
ES11186303.1T Active ES2502543T3 (es) 2010-10-29 2011-10-24 Una composición termoplástica, un método para producir la misma y artículos preparados a partir de ella
ES13153683.1T Active ES2524909T3 (es) 2010-10-29 2011-10-24 Una composición termoplástica, un método para producir la misma y artículos preparados a partir de ella

Family Applications Before (1)

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ES11186303.1T Active ES2502543T3 (es) 2010-10-29 2011-10-24 Una composición termoplástica, un método para producir la misma y artículos preparados a partir de ella

Country Status (4)

Country Link
US (2) US9051459B2 (es)
EP (2) EP2447321B1 (es)
CN (1) CN102558896B (es)
ES (2) ES2502543T3 (es)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9505930B2 (en) 2014-07-11 2016-11-29 Sabic Global Technologies B.V. Low gloss thermoplastic compositions, method of manufacture thereof and articles comprising the same
EP3497393A4 (en) 2016-08-08 2020-03-18 Ticona LLC THERMALLY CONDUCTIVE POLYMER COMPOSITION FOR HEAT DISSIPATOR
US20190337201A1 (en) * 2016-12-28 2019-11-07 Bando Chemical Industries, Ltd. Method for producing container for foods
WO2018236735A1 (en) * 2017-06-20 2018-12-27 Dow Global Technologies Llc VINYL POLYCHLORIDE COMPOSITIONS CONTAINING SHOCK RESISTANT AGENTS AND CALCIUM CARBONATE
EP4000922A1 (en) * 2020-11-20 2022-05-25 Dow Global Technologies LLC Multilayer films having at least one matte surface

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3415796A (en) 1966-03-24 1968-12-10 Rohm & Haas Extruded matte finish acrylic film
US4000216A (en) 1970-09-22 1976-12-28 Rohm And Haas Company Surface altering agent for thermoplastic polymers
CA1233590A (en) 1982-10-28 1988-03-01 Kazuo Kishida Delustering thermoplastic resin composition
US5237004A (en) 1986-11-18 1993-08-17 Rohm And Haas Company Thermoplastic and thermoset polymer compositions
JP2561881B2 (ja) * 1992-02-26 1996-12-11 旭化成工業株式会社 ポリアセタール樹脂組成物
KR950009111B1 (ko) 1992-09-08 1995-08-14 주식회사럭키 광택 조절용 수지의 제조방법
US5574110A (en) 1993-04-22 1996-11-12 Lucky Limited Processes for preparing polymeric gloss modifiers and thermoplastic resin compounds containing same
DE69422335T2 (de) 1993-05-28 2000-09-07 Mitsubishi Rayon Co Matte, thermoplastische Harzzusammensetzung und Laminat daraus, Mattierungsmittel dafür sowie Verfahren zur Mattierung eines thermoplastischen Harzes
DE4331805A1 (de) 1993-09-18 1995-03-23 Basf Ag Matte, transparente Thermoplastharze
KR20010007235A (ko) * 1999-06-17 2001-01-26 마크 에스. 아들러 내후성, 감소된 광택 및 고충격을 제공하는 캡스톡 조성물및 그 제조방법
GB9919304D0 (en) * 1999-08-17 1999-10-20 Ici Plc Acrylic composition
DE10043868A1 (de) * 2000-09-04 2002-04-04 Roehm Gmbh PMMA Formmassen mit verbesserter Schlagzähigkeit
JP4484381B2 (ja) 2001-02-28 2010-06-16 株式会社カネカ アクリル系艶消し熱可塑性樹脂フィルムとその製造方法
DE10354379A1 (de) 2003-11-20 2005-06-23 Röhm GmbH & Co. KG Formmasse, enthaltend ein Mattierungsmittel
KR101537130B1 (ko) * 2008-01-28 2015-07-15 카네카 코포레이션 지환식 에폭시 수지 조성물, 그 경화물, 및 그 제조 방법, 그리고 고무 형상 중합체 함유 수지 조성물

Also Published As

Publication number Publication date
US20120108751A1 (en) 2012-05-03
EP2594605B1 (en) 2014-10-08
US20150232655A1 (en) 2015-08-20
EP2447321A3 (en) 2012-07-25
EP2447321B1 (en) 2014-08-13
US9399710B2 (en) 2016-07-26
US9051459B2 (en) 2015-06-09
CN102558896A (zh) 2012-07-11
EP2594605A2 (en) 2013-05-22
CN102558896B (zh) 2016-02-10
EP2594605A3 (en) 2013-07-03
EP2447321A2 (en) 2012-05-02
ES2502543T3 (es) 2014-10-03

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