ES2396536B1 - ELECTROMAGNETIC RADIATION TRANSMITTER COATING - Google Patents

ELECTROMAGNETIC RADIATION TRANSMITTER COATING Download PDF

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Publication number
ES2396536B1
ES2396536B1 ES201100285A ES201100285A ES2396536B1 ES 2396536 B1 ES2396536 B1 ES 2396536B1 ES 201100285 A ES201100285 A ES 201100285A ES 201100285 A ES201100285 A ES 201100285A ES 2396536 B1 ES2396536 B1 ES 2396536B1
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Prior art keywords
coating
layer
paint
radiation
electromagnetic radiation
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Expired - Fee Related
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ES201100285A
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Spanish (es)
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ES2396536A1 (en
Inventor
Javier VILLAR CLOQUELL
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JAVIER VILLAR CLOQUELL
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Kaparazoom SL
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Priority to ES201100285A priority Critical patent/ES2396536B1/en
Priority to PCT/ES2012/000100 priority patent/WO2012143584A1/en
Publication of ES2396536A1 publication Critical patent/ES2396536A1/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/004Reflecting paints; Signal paints

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Paints Or Removers (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention relates to a coating formed by at least one layer of transmitting paint. Said paint layers generate a dioptre with the air, and its refractive index can be adjusted as a function of the composition and surface finish thereof. By applying a light source to an object painted with this coating, the surface thereof will be illuminated, independently of its geometry. The invention is intended for use in the fields of lighting and signage and in hospital environments.

Description

Recubrimiento transmisor de radiación electromagnética. Transmitter coating of electromagnetic radiation.

Sector"de la técnica Sector "of the technique

S S
La presente invención se encuadra dentro del sector de la iluminación. Si bien es extensivo por su aplicación a la industria de la señalética o mediante aplicación de Ultravioleta e para esterilizar en el campo médico hospitalario. The present invention falls within the lighting sector. Although it is extensive because of its application to the signage industry or through the application of Ultraviolet e to sterilize in the hospital medical field.

Antecedentes de la Invención Background of the Invention

10 10
Son conocidos diferentes sistemas de transmisión de luz basados en fibra óptica ya sea en su forma convencional o en forma de lámina, obtenidos industrialmente mediante una preforma de fibra óptica que posteriormente sufre un proceso de estirado destinados a transmitir diferentes rangos del espectro electromagnético. La patente JP 11038232 describe una resina transparente con partlcutas destinada a crear una capa difusora sobre una pantalla de luz, tamizando ésta, consiguiendo el efecto que produce por ejemplo una lámina de cristal al ácido o glaseada. Different light transmission systems based on optical fiber are known, either in their conventional form or in the form of a sheet, obtained industrially by means of a fiber optic preform that subsequently undergoes a stretching process intended to transmit different ranges of the electromagnetic spectrum. JP 11038232 describes a transparent resin with particles intended to create a diffusing layer on a light screen, sifting it, achieving the effect that produces for example an acid or glazed glass sheet.

15 fifteen
No se conocen antecedentes de recubrimientos formados por capas de pintura ideados para transmitir y difundir la radiación lumlnica. There is no known history of coatings formed by layers of paint designed to transmit and diffuse light radiation.

Objeto de la invención Object of the invention

20 twenty
Poder iluminar cualquier superficie independientemente de su geometría, aplicando un nuevo recubrimiento formado al menos por una capa de pintura transmisora de la luz. Lo cual permitiría por ejemplo iluminar las paredes de un quirófano, mobiliario, electrodomésticos o paneles publicitarios. Be able to illuminate any surface regardless of its geometry, applying a new coating formed at least by a layer of light-transmitting paint. This would allow for example to illuminate the walls of an operating room, furniture, appliances or advertising panels.

Descripción de la invención Description of the invention

Existen numerosas aplicaciones donde se hace preciso iluminar determinadas superficies, ya There are numerous applications where it is necessary to illuminate certain surfaces, since

sea con fines decorativos, de señalización u otros. be it for decorative, signaling or other purposes.

la presente Invención propone una solución para iluminar un objeto, a través de un nuevo recubrimiento cuyas propiedades físico-ópticas le permitan crear un dioptría formado por el recubrimiento y el aire que permita transmitir una radiación de luz y difundirla desde la superficie del objeto pintado. The present invention proposes a solution to illuminate an object, through a new coating whose physical-optical properties allow it to create a diopter formed by the coating and the air that allows to transmit a radiation of light and diffuse it from the surface of the painted object.

Tras aplicar este recubrimiento (1) (figura 1) sobre un objeto (5) (figura 1), para que ilumine, se activará una fuente de luz (2) (figura 1) que transmite la radiación al interior (3) (figura 1) del recubrimiento. Esta fuente de radiación electromagnética puede tener un rango de longitud de onda desde los 50 micrómetros (infrarrojo) hasta los 400 nanómetros (ultravioleta). After applying this coating (1) (figure 1) on an object (5) (figure 1), so that it illuminates, a light source (2) will be activated (figure 1) that transmits the radiation to the interior (3) (figure 1) of the coating. This source of electromagnetic radiation can have a wavelength range from 50 micrometers (infrared) to 400 nanometers (ultraviolet).

El recubrimiento estará formado por al menos una capa de pintura de material base polimérico, silicona, poliuretano, fibra de vidrio, polímero acrílico, resina acrílica, poliéster, vinilo o epoxi, con una permeabilidad lumínica mayor del 80% y con un índice de refracción entre 1,2 y 1,9. The coating shall consist of at least one paint layer of polymeric base material, silicone, polyurethane, fiberglass, acrylic polymer, acrylic resin, polyester, vinyl or epoxy, with a light permeability greater than 80% and with a refractive index between 1.2 and 1.9.

Para que la radiación luminosa sea conducida por el interior del recubrimiento, el dioptrio formado por el recubrimiento y el aire, permite que no se supere el ángulo crítico de reflexión. In order for the light radiation to be conducted inside the coating, the diopter formed by the coating and the air allows the critical angle of reflection not to be exceeded.

la difusión (4) (figura 1) de la luz al exterior se puede conseguir con diferentes características del recubrimiento. De un lado, la modificación de la rugosidad superficial de 10 a 300 micrómetros actúa generando un cambio en el ángulo de salida de la radiación, superando el índice crítico de refracción y variando con esto la cantidad de luz difundida. De otro lado la difusión al exterior se puede conseguir mediante la anisotropía del recubrimiento, generado mediante la adición de micro o nano partículas (6) (figura 4), de nitruros, carburos, óxidos como óxido de silicio, titanio, zirconio, cerio, sales metálicas, y derivados halogenados, ya que la adición de estos componentes modifican las propiedades físico-ópticas del recubrimiento como el índice de refracción, el índice de reflexión, la atenuación y la permeabilidad lumínica. Provocando que parte de la luz transmitida por el interior del recubrimiento cambie su ángulo de refracción y se difunda al exterior (4) (figuras 1, 2, 3, 4 Y 5). The diffusion (4) (figure 1) of the light outside can be achieved with different coating characteristics. On the one hand, the modification of the surface roughness from 10 to 300 micrometers acts by generating a change in the radiation exit angle, exceeding the critical index of refraction and thereby varying the amount of diffused light. On the other hand, diffusion abroad can be achieved by anisotropy of the coating, generated by the addition of micro or nano particles (6) (figure 4), of nitrides, carbides, oxides such as silicon oxide, titanium, zirconium, cerium, metal salts, and halogenated derivatives, since the addition of these components modify the physical-optical properties of the coating such as the refractive index, the reflection index, the attenuation and the light permeability. Causing that part of the light transmitted through the interior of the coating change its angle of refraction and diffuse to the outside (4) (figures 1, 2, 3, 4 and 5).

Otra forma prevista para variar el índice del recubrimiento consiste en la inclusión de cargas o Another way to vary the coating index is to include loads or

aditivos como el AsGa, KH2P04, KDl P04 o liTaD], cuyos valores de refracción cambian cuando se aplica un campo eléctrico. additives such as AsGa, KH2P04, KDl P04 or liTaD], whose refractive values change when an electric field is applied.

Se han previsto versiones de este recubrimiento en la que se incorporan capas de pintura Versions of this coating are planned in which paint layers are incorporated

5 reflectante convencional (7) (figura 2). Esta capa está entre el objeto a recubrir (5) (figura 2) y la capa transmisora (8a) (figura 2) al objeto de mejorar la eficiencia de la transmisión de la fuente de luz. A su vez, esta capa evita las discontinuidades físico-ópticas del objeto de base, homogeneizando éste a un valor conocido. Y otras versiones en las que la capa de pintura reflectante (9) (figura 3) está situada en el exterior del recubrimiento, al objeto de minimizar 5 conventional reflective (7) (figure 2). This layer is between the object to be coated (5) (figure 2) and the transmitting layer (8a) (figure 2) in order to improve the transmission efficiency of the light source. In turn, this layer avoids the physical-optical discontinuities of the base object, homogenizing it to a known value. And other versions in which the reflective paint layer (9) (figure 3) is located on the outside of the coating, in order to minimize

10 las pérdidas por difusión en aquellas zonas donde no se quiere iluminar. 10 diffusion losses in those areas where you do not want to illuminate.

El recubrimiento es aplicado en al menos una capa sobre el objeto que queremos iluminar mediante las técnicas convencionales de pintado, tanto manuales o industrializadas, como: rodillos. pincel, spray. pistola de pintado. cortina o electrodeposición. The coating is applied in at least one layer on the object that we want to illuminate using conventional painting techniques, both manual or industrialized, such as: rollers. brush, spray painted gun Curtain or electrodeposition.

BREVE DESCRIPCiÓN DE LOS DIBUJOS: BRIEF DESCRIPTION OF THE DRAWINGS:

Para la mejor comprensión de cuanto queda descrito en la presente memoria se acompañan unos dibujos tan sólo a título de ejemplo. For the best understanding of what is described herein, some drawings are attached by way of example only.

Descripción figuras Description figures

Figura 1: Recubrimiento aplicado sobre un objeto con la fuente de luz y la transmisión de radiación al exterior de las superficie. Descripción de los elementos: recubrimiento de una o varias capas de pintura (1), fuente emisora de radiación (2), radiación transmitida conducida en el interior del recubrimiento (3), radiación que difunde al exterior el recubrimiento (4), objeto a iluminar (5). Figure 1: Coating applied to an object with the light source and the radiation transmission to the surface outside. Description of the elements: coating of one or several layers of paint (1), radiation emitting source (2), transmitted radiation conducted inside the coating (3), radiation diffusing the coating (4) outside, object to light up (5).

Figura 2: Detalle del recubrimiento con una capa reflectante entre el recubrimiento y el objeto a iluminar. Descripción de los elementos: radiación transmitida o conducida en el interior del recubrimiento (3), radiación que difunde al exterior del recubrimiento (4), objeto a iluminar (5), capa de pintura reflectante (7), capa de pintura acrílica (Ba). Figure 2: Detail of the coating with a reflective layer between the coating and the object to be illuminated. Description of the elements: radiation transmitted or conducted inside the coating (3), radiation diffusing outside the coating (4), object to be illuminated (5), reflective paint layer (7), acrylic paint layer (Ba ).

Figura 3: Detalle del recubrimiento con una capa reflectante entre el recubrimiento y el aire. Descripción de los elementos: radiación transmitida o conducida en el interior del recubrimiento (3), radiación que difunde al exterior del recubrimiento (4), objeto a iluminar (5), capa de pintura acrílica con micro o nano partículas (Ba) y capas de pintura reflectante (9). Figure 3: Detail of the coating with a reflective layer between the coating and the air. Description of the elements: radiation transmitted or conducted inside the coating (3), radiation diffusing outside the coating (4), object to be illuminated (5), acrylic paint layer with micro or nano particles (Ba) and layers of reflective paint (9).

Figura 4: Detalle del recubrimiento con múltiples capas, con una capa con partículas para modificar la dirección de la radicación. Descripción de los elementos: recubrimiento de una o varias capas de pintura (1), radiación transmitida o conducida en el interior del recubrimiento (3), radiación que difunde al exterior del recubrimiento (4), nano o micro partículas incluidas en la pintura (6), capa de pintura reflectante (7), capa de de pintura acrílica con micro o nano Figure 4: Detail of the coating with multiple layers, with a layer with particles to modify the direction of the radiation. Description of the elements: coating of one or several layers of paint (1), radiation transmitted or conducted inside the coating (3), radiation diffusing outside the coating (4), nano or micro particles included in the paint ( 6), reflective paint layer (7), micro or nano acrylic paint layer

partículas (8a) y capa de pintura con base de siliconas (Bb). particles (8a) and silicone-based paint layer (Bb).

Figura 5: Ejemplo de aplicación en un equipamiento médico. Descripción de los elementos: recubrimiento de una o varias capas de pintura (l), fuente emisora de radiación (2), radiación que difunde al exterior del recubrimiento (4), objeto a iluminar (5) es un equipo médico Figure 5: Example of application in medical equipment. Description of the elements: coating of one or several layers of paint (l), radiation emitting source (2), radiation diffusing outside the coating (4), object to be illuminated (5) is a medical device

T.A.e. T.A.e.

DESCRIPCiÓN DE UNA FORMA DE REALIZACiÓN PREFERIDA: DESCRIPTION OF A PREFERRED EMBODIMENT:

S S
Se cita a modo de ejemplo una forma de realización preferida siendo independiente del objeto de la invención los materiales empleados en la fabricación de los componentes de la pintura, las capas que la forman y los métodos de aplicación y todos los detalles accesorios que puedan presentarse, siempre V cuando no afecten a su esencialidad. An example of a preferred embodiment is cited, being independent of the object of the invention the materials used in the manufacture of the components of the paint, the layers that form it and the methods of application and all the accessory details that may arise, always V when they do not affect their essentiality.

10 10
l a forma de realización descrita, comprende un recubrimiento (1) (figuras 4 y 5) transmisor de la radiación electromagnética más concretamente en su rango ultravioleta C. Esta radiación tiene conocidos efectos esterilizantes. Este recubrimiento es aplicado sobre un objeto a iluminar (5) (figuras 4 y S) en este caso un equipo de Tomografía Axial Computarizada (T.A.C.), cuya geometría compleja y de difícil acceso precisa de un método de esterilización eficaz. The described embodiment comprises a coating (1) (figures 4 and 5) that transmits electromagnetic radiation more specifically in its ultraviolet C range. This radiation has known sterilizing effects. This coating is applied on an object to be illuminated (5) (figures 4 and S) in this case a computerized axial tomography (T.A.C.) equipment, whose complex geometry and difficult access requires an effective sterilization method.

15 fifteen
Primeramente se procede a la aplicación mediante una pistola de una primera capa de pintura reflectante convencional (7) (figura 4) como por ejemplo una pintura blanca formulada con dióxido de titanio anatasa dado su elevado índice de reflexión. Esto permite homogeneizar la superficie del objeto y a su vez minimiza la atenuación de la radiación. First, a first layer of conventional reflective paint (7) (Figure 4) is applied by means of a spray gun, such as a white paint formulated with anatase titanium dioxide given its high reflection index. This allows the surface of the object to be homogenized and in turn minimizes radiation attenuation.

20 twenty
Tras su secado se aplica una segunda ca pa de pintura transmisora de base acrílica (8a) (figura 4) por su rápido secado con una transmisión luminosa mayor del 90% y con un índice de refracción característico de 1,49. Esta segunda capa de pintura está formulada con micro partículas de óxidos metálicos como óxidos de cerio. Provocando que parte de la luz transmitida por el interior del recubrimiento incidencia en las micro partículas (6) (figura 4) cambiando su ángulo de refracción y se difunda al exterior (4) (figuras 4 y 5). After drying, a second layer of acrylic-based transmitter paint (8a) is applied (figure 4) due to its rapid drying with a light transmission greater than 90% and with a characteristic refractive index of 1.49. This second layer of paint is formulated with micro particles of metal oxides such as cerium oxides. Causing that part of the light transmitted through the interior of the coating affects the micro particles (6) (figure 4) changing its angle of refraction and diffuses to the outside (4) (figures 4 and 5).

25 25
Por último se aplica una tercera capa de una pintura con bases de siliconas (8b) (figura 4) con una transmisión luminosa mayor del 60% y un índice de refracción característico menor a 1,4. El dioptria formado por la segunda y tercera capa permitirá conformar una estructura de salto de índice de refracción para el guiado de la radiación. la radiación ultravioleta se transmite siguiendo una trayectoria en zig-zag (3) (figura 4). Y su difusión será resultado de la anisotropia de la segunda capa de pintura creada con la adición de las partículas de óxidos metálicos. Finally, a third layer of a silicone-based paint (8b) (figure 4) with a light transmission greater than 60% and a characteristic refractive index of less than 1.4 is applied. The diopter formed by the second and third layers will allow the formation of a refractive index jump structure for radiation guidance. ultraviolet radiation is transmitted following a zigzag path (3) (figure 4). And its diffusion will be the result of the anisotropy of the second layer of paint created with the addition of the metal oxide particles.

Una vez secado el recubrimiento, aplicaremos una fuente de luz ultravioleta e (2) (figura SI, Once the coating has dried, we will apply an ultraviolet light source e (2) (figure SI,

de forma que esta radiación penetre en el interior de la segunda capa de pintura con lo que la radiación y sus efectos esterilizantes se transmitirán a 10 largo del recubrimiento difundiendo so that this radiation penetrates into the second layer of paint so that the radiation and its sterilizing effects will be transmitted along the coating spreading

(4) (figura 5) parte de ésta en toda la superficie del objeto. (4) (figure 5) part of it on the entire surface of the object.

s s

Claims (3)

REIVINDICACIONES 1. Recubrimiento para la transmisión de radia ción del rango infrarrojo al 1. Coating for infrared range radiation transmission to S ultravioleta procedente de una fuente de luz externa caracterizado por estar constituido por una capa de pintura (1) que conduce la radiación electromagnética del rango de 50 micrómetros a 400 nanómetros por su interior, compuesto por al menos una capa de pintura (8a) de material base polimérico, silicona, poliuretano, fibra de vidrio, polímero acrílico, resina acrílica, poliéster, Ultraviolet S from an external light source characterized by being constituted by a layer of paint (1) that conducts electromagnetic radiation from the range of 50 micrometers to 400 nanometers inside, consisting of at least one layer of paint (8a) of polymeric base material, silicone, polyurethane, fiberglass, acrylic polymer, acrylic resin, polyester, 10 vinilo. epoxi o PET, con una permeabilidad lumfnica mayor del 60%, con un índice de refracción entre 1,3 V 1,9, V con una rugosidad superficial de 10 a 300 micrómetros. 10 vinyl epoxy or PET, with a luminous permeability greater than 60%, with a refractive index between 1.3 V 1.9, V with a surface roughness of 10 to 300 micrometers. 2. Recubrimiento de acuerdo a la definición de la re ivindicación 1 caracterizado por incluir anisatropía en la capa mediante la adición de micro o nano partículas (6) 2. Coating according to the definition of claim 1 characterized by including anisatropia in the layer by the addition of micro or nano particles (6) 15 de nitruras, carburos, óxidos como óxido de silicio, óxido de titanio, óxido de zirconio, óxido de cerio, sales metálicas, y derivados halogenados. 15 nitrides, carbides, oxides such as silicon oxide, titanium oxide, zirconium oxide, cerium oxide, metal salts, and halogenated derivatives. 3. Recubrimiento de acuerdo a la definición de las reivindicaciones 1 y 2, caracterizado por que al menos una de las capas del recubrimiento (1) incluye cargas o aditivos de AsGa, KH 2P04, KD2P04 o liTaOl. 3. Coating according to the definition of claims 1 and 2, characterized in that at least one of the layers of the coating (1) includes fillers or additives of AsGa, KH 2P04, KD2P04 or liTaOl.
ES201100285A 2011-04-19 2011-04-19 ELECTROMAGNETIC RADIATION TRANSMITTER COATING Expired - Fee Related ES2396536B1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
ES201100285A ES2396536B1 (en) 2011-04-19 2011-04-19 ELECTROMAGNETIC RADIATION TRANSMITTER COATING
PCT/ES2012/000100 WO2012143584A1 (en) 2011-04-19 2012-04-17 Coating that can transmit electromagnetic radiation

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES201100285A ES2396536B1 (en) 2011-04-19 2011-04-19 ELECTROMAGNETIC RADIATION TRANSMITTER COATING

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ES2396536A1 ES2396536A1 (en) 2013-02-22
ES2396536B1 true ES2396536B1 (en) 2013-12-26

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111518467A (en) * 2020-03-27 2020-08-11 浙江大学 Preparation method of high-functionality polyurethane acrylate-silicon dioxide composite hardened coating

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE8514365U1 (en) * 1985-05-15 1985-06-27 Röhm GmbH, 6100 Darmstadt Multi-layer sheet with improved light transmission
JPH0642518B2 (en) * 1985-09-30 1994-06-01 三菱電機株式会社 Semiconductor device
ATE177773T1 (en) * 1993-12-22 1999-04-15 Sekisui Chemical Co Ltd TRANSPARENT CONDUCTIVE COATING COMPOSITION AND TRANSPARENT ANTISTATIC MOLDED BODY
US5789476A (en) * 1995-03-03 1998-08-04 Seiko Epson Corporation Film-forming coating solution and synthetic resin lens
AU2001254707A1 (en) * 2000-04-11 2001-10-23 Merck Patent G.M.B.H Transparent medium having angle-selective transmission or reflection properties and/or absorption properties
WO2007032217A1 (en) * 2005-09-16 2007-03-22 Matsushita Electric Industrial Co., Ltd. Composite material and optical component using the same
US7749593B2 (en) * 2006-07-07 2010-07-06 Certainteed Corporation Solar heat responsive exterior surface covering
TWI506104B (en) * 2009-03-11 2015-11-01 旭化成電子材料股份有限公司 Coating composition, coating film, laminate and method for preparing laminate

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