ES2389185T3 - Composiciones de emulsión explosiva y métodos de preparación de las mismas - Google Patents
Composiciones de emulsión explosiva y métodos de preparación de las mismas Download PDFInfo
- Publication number
- ES2389185T3 ES2389185T3 ES08774442T ES08774442T ES2389185T3 ES 2389185 T3 ES2389185 T3 ES 2389185T3 ES 08774442 T ES08774442 T ES 08774442T ES 08774442 T ES08774442 T ES 08774442T ES 2389185 T3 ES2389185 T3 ES 2389185T3
- Authority
- ES
- Spain
- Prior art keywords
- reactor
- emulsion
- phase
- crystallization temperature
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000839 emulsion Substances 0.000 title claims abstract description 175
- 239000000203 mixture Substances 0.000 title claims abstract description 118
- 239000002360 explosive Substances 0.000 title claims abstract description 114
- 238000000034 method Methods 0.000 title claims description 74
- 238000002360 preparation method Methods 0.000 title description 2
- 238000002425 crystallisation Methods 0.000 claims abstract description 116
- 230000008025 crystallization Effects 0.000 claims abstract description 116
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 111
- 230000007423 decrease Effects 0.000 claims abstract description 82
- 230000001590 oxidative effect Effects 0.000 claims abstract description 81
- 229910002651 NO3 Inorganic materials 0.000 claims abstract description 57
- 239000004312 hexamethylene tetramine Substances 0.000 claims abstract description 52
- 235000010299 hexamethylene tetramine Nutrition 0.000 claims abstract description 52
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 claims abstract description 52
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims abstract description 49
- 239000000446 fuel Substances 0.000 claims abstract description 49
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims abstract description 48
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 22
- 239000006185 dispersion Substances 0.000 claims abstract description 5
- 230000003247 decreasing effect Effects 0.000 claims description 38
- 230000008569 process Effects 0.000 claims description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- 239000003921 oil Substances 0.000 claims description 18
- 238000010924 continuous production Methods 0.000 claims description 13
- 239000003431 cross linking reagent Substances 0.000 claims description 10
- 239000002480 mineral oil Substances 0.000 claims description 7
- 235000010446 mineral oil Nutrition 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 5
- 239000000243 solution Substances 0.000 claims 9
- 239000007864 aqueous solution Substances 0.000 claims 1
- 238000010923 batch production Methods 0.000 claims 1
- 239000007800 oxidant agent Substances 0.000 abstract description 66
- BAZAXWOYCMUHIX-UHFFFAOYSA-M sodium perchlorate Chemical compound [Na+].[O-]Cl(=O)(=O)=O BAZAXWOYCMUHIX-UHFFFAOYSA-M 0.000 description 21
- 229910001488 sodium perchlorate Inorganic materials 0.000 description 21
- 238000001816 cooling Methods 0.000 description 18
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 18
- 238000005474 detonation Methods 0.000 description 17
- 230000000295 complement effect Effects 0.000 description 15
- 235000019198 oils Nutrition 0.000 description 15
- 238000003860 storage Methods 0.000 description 15
- 239000003638 chemical reducing agent Substances 0.000 description 14
- 239000007789 gas Substances 0.000 description 10
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 9
- 229910052782 aluminium Inorganic materials 0.000 description 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 9
- 150000001412 amines Chemical class 0.000 description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 9
- 238000000354 decomposition reaction Methods 0.000 description 9
- PTIUDKQYXMFYAI-UHFFFAOYSA-N methylammonium nitrate Chemical compound NC.O[N+]([O-])=O PTIUDKQYXMFYAI-UHFFFAOYSA-N 0.000 description 9
- 239000001301 oxygen Substances 0.000 description 9
- 229910052760 oxygen Inorganic materials 0.000 description 9
- 239000004317 sodium nitrate Substances 0.000 description 9
- 235000010344 sodium nitrate Nutrition 0.000 description 9
- 239000001993 wax Substances 0.000 description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 8
- -1 amine nitrate Chemical class 0.000 description 8
- 230000008901 benefit Effects 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- 230000035945 sensitivity Effects 0.000 description 8
- 239000004034 viscosity adjusting agent Substances 0.000 description 7
- 239000011324 bead Substances 0.000 description 6
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 230000035939 shock Effects 0.000 description 5
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 4
- 229910017604 nitric acid Inorganic materials 0.000 description 4
- 238000004806 packaging method and process Methods 0.000 description 4
- 239000007762 w/o emulsion Substances 0.000 description 4
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 239000000499 gel Substances 0.000 description 3
- 238000012544 monitoring process Methods 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 description 3
- 239000008158 vegetable oil Substances 0.000 description 3
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 230000003467 diminishing effect Effects 0.000 description 2
- 239000003673 groundwater Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000008041 oiling agent Substances 0.000 description 2
- 239000011049 pearl Substances 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000004781 supercooling Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 229910001963 alkali metal nitrate Inorganic materials 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- KZTZJUQNSSLNAG-UHFFFAOYSA-N aminoethyl nitrate Chemical class NCCO[N+]([O-])=O KZTZJUQNSSLNAG-UHFFFAOYSA-N 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 238000005422 blasting Methods 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 238000000586 desensitisation Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- QHDUJTCUPWHNPK-UHFFFAOYSA-N methyl 7-methoxy-2h-indazole-3-carboxylate Chemical compound COC1=CC=CC2=C(C(=O)OC)NN=C21 QHDUJTCUPWHNPK-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B47/00—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase
- C06B47/14—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase comprising a solid component and an aqueous phase
- C06B47/145—Water in oil emulsion type explosives in which a carbonaceous fuel forms the continuous phase
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B23/00—Compositions characterised by non-explosive or non-thermic constituents
- C06B23/006—Stabilisers (e.g. thermal stabilisers)
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Colloid Chemistry (AREA)
- Liquid Carbonaceous Fuels (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US770378 | 1991-10-03 | ||
| US11/770,378 US20120180915A1 (en) | 2007-06-28 | 2007-06-28 | Explosive emulsion compositions and methods of making the same |
| PCT/EP2008/058277 WO2009000915A2 (en) | 2007-06-28 | 2008-06-27 | Explosive emulsion compositions and methods of making the same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2389185T3 true ES2389185T3 (es) | 2012-10-24 |
Family
ID=40039821
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES08774442T Active ES2389185T3 (es) | 2007-06-28 | 2008-06-27 | Composiciones de emulsión explosiva y métodos de preparación de las mismas |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US20120180915A1 (pl) |
| EP (1) | EP2176197B1 (pl) |
| CN (1) | CN101801892B (pl) |
| AU (1) | AU2008267135B2 (pl) |
| BR (1) | BRPI0813219B1 (pl) |
| CA (1) | CA2700683C (pl) |
| CL (1) | CL2008001909A1 (pl) |
| ES (1) | ES2389185T3 (pl) |
| PE (1) | PE20090532A1 (pl) |
| PL (1) | PL2176197T3 (pl) |
| RU (1) | RU2469013C2 (pl) |
| WO (1) | WO2009000915A2 (pl) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101143853B1 (ko) * | 2009-09-23 | 2012-05-23 | 신경민 | 생체세포의 임피던스 변화에 따라 ｒｆ 출력을 제어하는 방법 및 시스템 |
| GB201202402D0 (en) * | 2012-02-10 | 2012-03-28 | Maxam Dantex South Africa Proprietary Ltd | Oxidizer solution |
| CN103848704A (zh) * | 2012-11-30 | 2014-06-11 | 陕西省汉阴华能新材料研究有限公司 | 回收油的应用 |
| CN103553850B (zh) * | 2013-10-11 | 2016-01-20 | 葛洲坝易普力股份有限公司 | 一种现场向上进行深孔填装制备乳化炸药的工艺方法 |
| CN104515843B (zh) * | 2014-12-23 | 2016-04-13 | 中煤科工集团淮北爆破技术研究院有限公司 | 乳化炸药产品质量在线监测方法 |
| CN106672283A (zh) | 2015-11-10 | 2017-05-17 | 迪博泰有限公司 | 适于低温爆炸物乳剂的具有尺寸设定心轴的包装系统 |
| CN111272971A (zh) * | 2020-03-10 | 2020-06-12 | 鞍钢矿业爆破有限公司 | 一种现场混装乳化炸药水相性能自动检测系统及方法 |
| CN112939710B (zh) * | 2021-03-24 | 2022-04-22 | 葛洲坝易普力湖北昌泰民爆有限公司 | 一种用煤制油中间产品制备现场混装铵油炸药用油相及其制备方法 |
| KR102744525B1 (ko) * | 2021-12-29 | 2024-12-18 | 주식회사 한화 | 저비중 에멀젼 폭약 조성물 |
| PE20250051A1 (es) * | 2022-03-25 | 2025-01-10 | Enaex Servicios Sa | Nueva tecnologia de fabricacion para emulsiones de baja viscosidad |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2126921C3 (de) * | 1971-05-29 | 1981-07-16 | Dynamit Nobel Ag, 5210 Troisdorf | Energielieferndes, zur Herstellung von Sprengstoffen geeignetes eutektisches Gemisch mit niedrigem Erstarrungspunkt und seine Verwendung |
| JPS608998B2 (ja) * | 1980-03-12 | 1985-03-07 | 日本化薬株式会社 | 油中水滴型エマルジヨン爆薬 |
| NZ206983A (en) * | 1983-02-15 | 1988-02-29 | Ici Australia Ltd | Dynamite explosive composition |
| IE59303B1 (en) * | 1985-08-21 | 1994-02-09 | Ici Australia Ltd | Composition |
| JPH0637344B2 (ja) * | 1986-03-10 | 1994-05-18 | 日本油脂株式会社 | 油中水型エマルシヨン爆薬組成物 |
| JPH0684273B2 (ja) * | 1987-08-25 | 1994-10-26 | 日本油脂株式会社 | 油中水型エマルション爆薬組成物 |
| SE8800593L (sv) * | 1988-02-22 | 1989-08-23 | Nitro Nobel Ab | Spraengaemneskomposition |
| US5099763A (en) * | 1990-05-16 | 1992-03-31 | Eti Explosive Technologies International | Method of blasting |
| US5071496A (en) * | 1990-05-16 | 1991-12-10 | Eti Explosive Technologies International (Canada) | Low level blasting composition |
| US5159153A (en) * | 1990-06-07 | 1992-10-27 | Cranney Don H | Emulsion that is compatible with reactive sulfide/pyrite ores |
| CA2049628C (en) * | 1991-08-21 | 2002-02-26 | Clare T. Aitken | Vegetable oil emulsion explosive |
| ES2081744B1 (es) * | 1993-04-20 | 1997-01-16 | Espanola Explosivos | Composicion explosiva encartuchable en papel y su procedimiento de fabricacion. |
| US5608185A (en) * | 1995-01-31 | 1997-03-04 | Dyno Nobel Inc. | Method of reducing nitrogen oxide fumes in blasting |
| US6051086A (en) * | 1998-06-08 | 2000-04-18 | Orica Explosives Technology Pty Ltd. | Buffered emulsion blasting agent |
| AUPP600098A0 (en) * | 1998-09-17 | 1998-10-08 | Dyno Nobel Asia Pacific Limited | Explosive emulsion composition |
| DE19847868C2 (de) * | 1998-10-16 | 2003-09-25 | Clariant Gmbh | Sprengstoffe, enthaltend modifizierte Copolymere aus Polyisobutylen und Maleinsäureanhydrid als Emulgatoren |
| US6214140B1 (en) * | 1999-09-22 | 2001-04-10 | Universal Tech Corporation | Development of new high energy blasting products using demilitarized ammonium picrate |
| RU2277523C2 (ru) * | 2004-04-28 | 2006-06-10 | Открытое акционерное общество "Промсинтез" | Эмульсионный взрывчатый состав и способ его получения |
| US20060243362A1 (en) * | 2005-02-01 | 2006-11-02 | Houston Donald J | Explosive compositions |
-
2007
- 2007-06-28 US US11/770,378 patent/US20120180915A1/en not_active Abandoned
-
2008
- 2008-06-25 PE PE2008001083A patent/PE20090532A1/es active IP Right Grant
- 2008-06-27 PL PL08774442T patent/PL2176197T3/pl unknown
- 2008-06-27 BR BRPI0813219-4A patent/BRPI0813219B1/pt not_active IP Right Cessation
- 2008-06-27 RU RU2010102772/05A patent/RU2469013C2/ru active
- 2008-06-27 ES ES08774442T patent/ES2389185T3/es active Active
- 2008-06-27 CL CL2008001909A patent/CL2008001909A1/es unknown
- 2008-06-27 CN CN2008801033950A patent/CN101801892B/zh not_active Expired - Fee Related
- 2008-06-27 AU AU2008267135A patent/AU2008267135B2/en not_active Ceased
- 2008-06-27 WO PCT/EP2008/058277 patent/WO2009000915A2/en not_active Ceased
- 2008-06-27 CA CA2700683A patent/CA2700683C/en not_active Expired - Fee Related
- 2008-06-27 EP EP08774442A patent/EP2176197B1/en not_active Not-in-force
Also Published As
| Publication number | Publication date |
|---|---|
| CL2008001909A1 (es) | 2009-01-02 |
| PL2176197T3 (pl) | 2012-11-30 |
| EP2176197B1 (en) | 2012-06-06 |
| RU2010102772A (ru) | 2011-08-10 |
| EP2176197A2 (en) | 2010-04-21 |
| CN101801892B (zh) | 2012-11-14 |
| AU2008267135A1 (en) | 2008-12-31 |
| CN101801892A (zh) | 2010-08-11 |
| PE20090532A1 (es) | 2009-05-29 |
| US20120180915A1 (en) | 2012-07-19 |
| BRPI0813219A2 (pt) | 2014-12-23 |
| WO2009000915A3 (en) | 2009-05-28 |
| CA2700683C (en) | 2014-11-18 |
| WO2009000915A2 (en) | 2008-12-31 |
| BRPI0813219B1 (pt) | 2019-04-24 |
| RU2469013C2 (ru) | 2012-12-10 |
| CA2700683A1 (en) | 2008-12-31 |
| AU2008267135B2 (en) | 2011-12-08 |
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