ES236109A1 - Method for the manufacture of methyl acrylate and methyl methacrylate monomers - Google Patents
Method for the manufacture of methyl acrylate and methyl methacrylate monomersInfo
- Publication number
- ES236109A1 ES236109A1 ES0236109A ES236109A ES236109A1 ES 236109 A1 ES236109 A1 ES 236109A1 ES 0236109 A ES0236109 A ES 0236109A ES 236109 A ES236109 A ES 236109A ES 236109 A1 ES236109 A1 ES 236109A1
- Authority
- ES
- Spain
- Prior art keywords
- methyl methacrylate
- kgs
- vapours
- dimethyl ether
- methyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/34—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping with one or more auxiliary substances
- B01D3/40—Extractive distillation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D5/00—Condensation of vapours; Recovering volatile solvents by condensation
- B01D5/0003—Condensation of vapours; Recovering volatile solvents by condensation by using heat-exchange surfaces for indirect contact between gases or vapours and the cooling medium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D5/00—Condensation of vapours; Recovering volatile solvents by condensation
- B01D5/0003—Condensation of vapours; Recovering volatile solvents by condensation by using heat-exchange surfaces for indirect contact between gases or vapours and the cooling medium
- B01D5/0012—Vertical tubes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D5/00—Condensation of vapours; Recovering volatile solvents by condensation
- B01D5/0027—Condensation of vapours; Recovering volatile solvents by condensation by direct contact between vapours or gases and the cooling medium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D5/00—Condensation of vapours; Recovering volatile solvents by condensation
- B01D5/0078—Condensation of vapours; Recovering volatile solvents by condensation characterised by auxiliary systems or arrangements
- B01D5/009—Collecting, removing and/or treatment of the condensate
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/48—Separation; Purification; Stabilisation; Use of additives
- C07C67/58—Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
- C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
- C07C69/54—Acrylic acid esters; Methacrylic acid esters
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Methyl acrylate monomer or methyl methacrylate monomer, free from polymers is obtained by treating directly in a single stage the aseotropic mixture of vapours coming from an esterification column, with that quantity of water or an aqueous solution of an alkali metal or alkaline earth metal salt which will condense the vapours and give an organic phase substantially free from dimethyl ether. In a typical example, the vapours of a methyl methacrylate esterification column were condensed with water containing 0.025% of hydroquinone. The temperature of the uncondensed vapours was 70-72 DEG C. and there were introduced into the distillation apparatus at the rate of 14.9 Kgs of methyl methacrylate, 9.6 Kgs of methanol, 3.8 Kgs of water and 1 Kg of dimethyl ether per hour. After cooling to 20-25 DEG C. 13.1 Kgs were collected per hour of an organic phase having 95.3% by weight of methyl methacrylate free from polymer, and 63 Kgs of an aqueous phase containing 14.6% methanol, 3.9% methyl methacrylate and 0.8% of dimethyl ether. The aqueous solution may contain 270 to 465 grams of calcium chloride per litre.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR716831A FR1152406A (en) | 1956-06-18 | 1956-06-18 | Process for separating azeotropic mixtures and device for its realization and its applications |
Publications (1)
Publication Number | Publication Date |
---|---|
ES236109A1 true ES236109A1 (en) | 1957-12-16 |
Family
ID=34400682
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES0236109A Expired ES236109A1 (en) | 1956-06-18 | 1957-06-17 | Method for the manufacture of methyl acrylate and methyl methacrylate monomers |
Country Status (5)
Country | Link |
---|---|
BE (1) | BE558358A (en) |
DE (1) | DE1179195B (en) |
ES (1) | ES236109A1 (en) |
FR (1) | FR1152406A (en) |
GB (1) | GB842025A (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB905510A (en) * | 1958-03-11 | 1962-09-12 | Electro Chimie Metal | Improvements in the manufacture of methyl methacrylate |
JPS51146418A (en) * | 1975-06-10 | 1976-12-16 | Nippon Zeon Co Ltd | Purification of methacrylic esters |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE852851C (en) * | 1948-02-09 | 1952-10-20 | Goodrich Co B F | Process for the preparation of alkyl esters ª ‡, ª ‰ -unsaturated monocarboxylic acids |
-
1956
- 1956-06-18 FR FR716831A patent/FR1152406A/en not_active Expired
-
1957
- 1957-06-13 BE BE558358A patent/BE558358A/en unknown
- 1957-06-14 GB GB1889857A patent/GB842025A/en not_active Expired
- 1957-06-17 ES ES0236109A patent/ES236109A1/en not_active Expired
- 1957-06-18 DE DE1957S0053925 patent/DE1179195B/en active Pending
Also Published As
Publication number | Publication date |
---|---|
GB842025A (en) | 1960-07-20 |
BE558358A (en) | 1960-03-25 |
FR1152406A (en) | 1958-02-17 |
DE1179195B (en) | 1964-10-08 |
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