ES2347559T3 - ALKALINE GLASSES WITH MODIFIED SURFACES AND PROCEDURE FOR PRODUCTION. - Google Patents
ALKALINE GLASSES WITH MODIFIED SURFACES AND PROCEDURE FOR PRODUCTION. Download PDFInfo
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- ES2347559T3 ES2347559T3 ES04730521T ES04730521T ES2347559T3 ES 2347559 T3 ES2347559 T3 ES 2347559T3 ES 04730521 T ES04730521 T ES 04730521T ES 04730521 T ES04730521 T ES 04730521T ES 2347559 T3 ES2347559 T3 ES 2347559T3
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- 239000011521 glass Substances 0.000 title claims abstract description 43
- 238000000034 method Methods 0.000 title claims abstract description 18
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 230000008569 process Effects 0.000 claims abstract description 7
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical class Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 21
- 239000012071 phase Substances 0.000 claims description 6
- 230000009466 transformation Effects 0.000 claims description 4
- 239000012808 vapor phase Substances 0.000 claims description 3
- 238000007664 blowing Methods 0.000 claims description 2
- 238000000859 sublimation Methods 0.000 claims description 2
- 230000008022 sublimation Effects 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 abstract description 8
- 239000011734 sodium Substances 0.000 abstract description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract description 7
- 229910052782 aluminium Inorganic materials 0.000 abstract description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 7
- 238000009792 diffusion process Methods 0.000 abstract description 3
- 229910052656 albite Inorganic materials 0.000 abstract description 2
- 230000015572 biosynthetic process Effects 0.000 abstract description 2
- 238000010438 heat treatment Methods 0.000 abstract description 2
- 239000007789 gas Substances 0.000 description 5
- 230000003301 hydrolyzing effect Effects 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 238000002425 crystallisation Methods 0.000 description 4
- 230000008025 crystallization Effects 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 239000000523 sample Substances 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 241000234282 Allium Species 0.000 description 1
- 235000002732 Allium cepa var. cepa Nutrition 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 239000010431 corundum Substances 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000007792 gaseous phase Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000005355 lead glass Substances 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000005368 silicate glass Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C21/00—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C21/00—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface
- C03C21/001—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C21/00—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface
- C03C21/007—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in gaseous phase
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C23/00—Other surface treatment of glass not in the form of fibres or filaments
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31—Surface property or characteristic of web, sheet or block
- Y10T428/315—Surface modified glass [e.g., tempered, strengthened, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Surface Treatment Of Glass (AREA)
- Glass Compositions (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Materials For Medical Uses (AREA)
- Re-Forming, After-Treatment, Cutting And Transporting Of Glass Products (AREA)
Abstract
Description
Vidrios alcalinos con superficies modificadas y procedimiento para su producción.Alkaline glasses with modified surfaces and Procedure for its production.
En el uso de los vidrios, las propiedades superficiales de éstos en relación con la interacción con el entorno desempeñan un papel esencial, debiendo mencionarse en este contexto en particular las propiedades químicas y mecánicas. Por diferentes motivos, relacionados entre otras cosas con la fusibilidad y la tecnología de fusión, frecuentemente son deseables unos contenidos de álcali relativamente altos, pero éstos conducen por otro lado a una reducción de la resistencia hidrolítica y las propiedades mecánicas. Una solución usual hasta la fecha a este dilema consiste en un tratamiento superficial definido en general mediante procesos de desalcalinización, tal como se presentan resumidos en [1: Glastechnische Fabrikationsfehler, H. J. Jebsen-Marwedel, R. Brückner: Editorial Springer 1980, páginas 507508] y en [2: Solicitud de Patente Oficina Alemana de Patentes y Marcas. Verfahren zur Herstellung von Emails, referencia 102 46 928.8]. En esta problemática de la desalcalinización, por ejemplo mediante influencia de vapor de agua sulfúrea, etc., surge un problema fundamental consistente en que para lograr una alta reactividad generalmente se requieren altas temperaturas de reacción, pero éstas pueden conducir a su vez a una retrodifusión de sodio del volumen en la superficie. Sobre todo en caso de procesos de tratamiento posteriores, como un procesamiento posterior bajo llama, que implica altas temperaturas, la retrodifusión de sodio del volumen provocada térmicamente puede conducir a una degradación significativa de las propiedades logradas en un principio.In the use of glasses, the properties superficial of these in relation to the interaction with the environment they play an essential role, and should be mentioned in this context in particular the chemical and mechanical properties. For different reasons, inter alia related to fusibility and fusion technology, contents are often desirable of relatively high alkali, but these lead on the other hand to a reduction in hydrolytic resistance and properties mechanical A usual solution to date to this dilemma is in a surface treatment defined in general by processes of desalkalization, as presented in [1: Glastechnische Fabrikationsfehler, H. J. Jebsen-Marwedel, R. Brückner: Springer Editorial 1980, pages 507508] and in [2: German Office Patent Application of Patents and Trademarks. Verfahren zur Herstellung von Emails, reference 102 46 928.8]. In this problem of desalkalization, for example by influence of water vapor sulfur, etc., a fundamental problem arises in that to achieve high reactivity, high levels are usually required reaction temperatures, but these can in turn lead to a sodium backscatter of surface volume. Specially in case of subsequent treatment processes, such as processing later under flame, which implies high temperatures, the sodium backscattering of the thermally caused volume can lead to a significant degradation of the properties achieved initially.
El documento US5510144 describe un método para impedir la retrodifusión de iones de plomo hacia la superficie de vidrio mediante tratamiento con vapores de sulfato de aluminio y hierro. El documento JP60176952 da a conocer un tratamiento superficial de vidrio para evitar la corrosión atmosférica con soluciones ácidas de sulfato de aluminio a 20-90ºC, que opcionalmente también pueden contener cloruro de aluminio.US5510144 describes a method for prevent back-diffusion of lead ions towards the surface of glass by treatment with aluminum sulfate vapors and iron. JP60176952 discloses a treatment surface glass to prevent atmospheric corrosion with acidic solutions of aluminum sulfate at 20-90 ° C, which may also optionally contain aluminum chloride.
El objetivo técnico de la invención consiste en estabilizar la superficie de vidrio modificada de tal modo que, a diferencia del estado actual de la técnica, se evite en gran medida una retrodifusión de sodio del volumen también a altas temperaturas, y en particular en caso de procesamientos posteriores con llama.The technical objective of the invention consists in stabilize the modified glass surface such that, at Unlike the current state of the art, it is largely avoided a sodium backscatter of the volume also at high temperatures, and in particular in case of subsequent processing with flame.
Sorprendentemente se comprobó que una superficie modificada de un vidrio alcalino es muy resistente a una retrodifusión de sodio del volumen a altas temperaturas si el mecanismo químico dentro de la superficie presenta una concentración de aluminio claramente mayor que la del volumen. La causa puede radicar en la altísima entalpia de formación negativa de fases de albita. El procedimiento según la invención se caracteriza porque la superficie de estos vidrios se pone en contacto con compuestos de cloruro de aluminio en fase de vapor.Surprisingly it was found that a surface modified from an alkaline glass is very resistant to a sodium backscattering of the volume at high temperatures if the chemical mechanism within the surface has a concentration Aluminum clearly larger than the volume. The cause can lay in the very high enthalpy of negative phase formation of albite. The method according to the invention is characterized in that the surface of these glasses is contacted with compounds of aluminum chloride in vapor phase.
Se pueden evitar perjuicios ópticos si el material aluminifero de la fase gaseosa se condensa en superficie de vidrio y al mismo tiempo pasa a formar parte de los compuestos necesarios. El cloruro de aluminio se utiliza en una cantidad de al menos 0,1 g/m^{3} de volumen de contacto, preferentemente en una cantidad de 1 a 10 g/m^{3}. El limite superior está determinado por la presión de vapor de saturación. La temperatura de los compuestos de cloruro de aluminio oscila entre la temperatura de sublimación de 170ºC y hasta 600 K por encima de la temperatura de transformación del vidrio. La duración del contacto de los vidrios con compuestos de cloruro de aluminio de la fase gaseosa oscila entre al menos 0,1 segundos en caso de altas temperaturas y hasta una hora en caso de bajas temperaturas. El limite inferior de la temperatura de la muestra de la superficie de vidrio está determinado por la resistencia del vidrio al cambio de temperaturas. El limite superior puede estar hasta 600 K por encima de la temperatura de transformación del vidrio. Al trabajar con cloruros de aluminio en la fase gaseosa se pueden lixiviar fácilmente posibles residuos débiles. Al emplear cloruro de aluminio se ha de diferenciar entre el uso con agua de cristalización y sin agua de cristalización. Con agua de cristalización se produce una modificación superficial más intensa y un aumento de la resistencia hidrolítica y de la microdureza de los vidrios, sin perjuicio óptico. Cuando se utiliza cloruro de aluminio anhidro se observan más fácilmente perjuicios ópticos perceptibles.Optical damage can be avoided if the aluminum material of the gas phase condenses on the surface of glass and at the same time becomes part of the compounds necessary. Aluminum chloride is used in an amount of al minus 0.1 g / m3 of contact volume, preferably in a amount from 1 to 10 g / m 3. The upper limit is determined by saturation vapor pressure. The temperature of the Aluminum chloride compounds range from the temperature of sublimation of 170ºC and up to 600 K above the temperature of glass transformation The duration of the contact of the glasses with gaseous phase aluminum chloride compounds oscillates between at least 0.1 seconds in case of high temperatures and up to one hour in case of low temperatures. The lower limit of the sample temperature of the glass surface is determined by the resistance of the glass to changing temperatures. The upper limit can be up to 600 K above the glass transformation temperature. When working with chlorides Aluminum in the gas phase can be easily leached Possible weak waste. When using aluminum chloride, differentiate between use with water of crystallization and without water of crystallization. With crystallization water a more intense surface modification and increased resistance glass hydrolytic and microhardness, without prejudice optical. When anhydrous aluminum chloride is used, they are observed more easily noticeable optical damage.
El procedimiento según la invención también se puede emplear ventajosamente en la producción de vidrio para tubos. En la producción de vidrio para tubos, como medio de soplado con sobrepresión en el proceso de Vello o el proceso de Danner se conduce aire a las superficies interiores de los tubos de vidrio. Se puede utilizar aire calentado a más de 170ºC que contiene AlCl_{3} evaporado. De este modo en primer lugar se evita una condensación. Este gas entra entonces en contacto en forma de capas de cebolla con la superficie interior caliente del vidrio, pudiendo tener lugar entonces la modificación de la superficie de vidrio. El gas sale después por la abertura del tubo en el extremo frió del tubo continuo, por lo que dispone de un tiempo de hasta varios minutos y de altas temperaturas (hasta 600 K por encima de Tg) hasta el corte del vidrio para reaccionar con la superficie del vidrio. En este contexto, para evitar la condensación puede ser necesario mantener la temperatura de corte del tubo por encima de 170ºC.The process according to the invention is also It can be used advantageously in the production of glass for tubes. In the production of glass for tubes, as a means of blowing with overpressure in the Vello process or the Danner process is conducts air to the inner surfaces of the glass tubes. Be you can use heated air at more than 170 ° C containing AlCl 3 evaporated. In this way, condensation is avoided first. This gas then comes into contact in the form of onion layers with the hot inner surface of the glass, being able to take place Then the modification of the glass surface. Gas comes out then through the opening of the tube at the cold end of the tube continuous, so you have a time of up to several minutes and from high temperatures (up to 600 K above Tg) until cutting of the glass to react with the surface of the glass. In this context, to avoid condensation it may be necessary to maintain the cutting temperature of the tube above 170 ° C.
La figura 1 muestra resultados tipicos de la resistencia hidrolitica de botellas blancas de vidrio de silicato de sodio y cal con la siguiente composición: 71,0% SiO_{2}, 1,7% Al_{2}O_{3}, 0,02% Fe_{2}O_{3}, 1,3% K_{2}O, 15,5% Na_{2}O, 9,4% CaO, 2,7% MgO y 0,25 SO_{3}, habiéndose calentado las muestras en un horno a temperaturas de 550ºC con diferentes cantidades de AlCl_{3} * 6 H_{2}O y enfriado después en el mismo lugar. Las cantidades de cloruro de aluminio introducidas en el recipiente correspondían a una superficie de vidrio de 3814 mm y un volumen de 20 m., debiendo pasar el cloruro de aluminio anhidro a la fase gaseosa a 180ºC, o de acuerdo con algunas mediciones DTA el material con agua de cristalización no se descompone hasta alcanzar temperaturas de 203ºC. Los recipientes se colocaron encima del material de muestra y después de 15 minutos de tratamiento en el horno de mufla se enfriaron con el mismo. La tabla 1 muestra diferentes pasos de tratamiento y su efecto en la resistencia hidrolítica.Figure 1 shows typical results of the Hydrolytic resistance of white silicate glass bottles of sodium and lime with the following composition: 71.0% SiO2, 1.7% Al 2 O 3, 0.02% Fe 2 O 3, 1.3% K 2 O, 15.5% Na 2 O, 9.4% CaO, 2.7% MgO and 0.25 SO 3, having been heated samples in an oven at temperatures of 550ºC with different amounts of AlCl 3 * 6 H 2 O and then cooled therein place. The amounts of aluminum chloride introduced into the vessel corresponded to a glass surface of 3814 mm and a volume of 20 m., the anhydrous aluminum chloride must pass to the gas phase at 180 ° C, or according to some DTA measurements the material with water of crystallization does not decompose until it reaches temperatures of 203 ° C. The containers were placed on top of the sample material and after 15 minutes of treatment in the Muffle furnace cooled with it. Table 1 shows different treatment steps and their effect on resistance hydrolytic
Las figuras 2a (vidrio sin tratar) y 2b (vidrio tratado según la invención) muestran las exploraciones de linea registradas con una microsonda a lo largo de 30 \mum con las intensidades de señal especificas de elementos de este vidrio extrablanco analizado. Se puede ver claramente el enriquecimiento de aluminio en la superficie en un área menor de 1 \mum después del procedimiento según la invención.Figures 2a (untreated glass) and 2b (glass treated according to the invention) show the line scans recorded with a microwave over 30 µm with the specific signal intensities of elements of this glass extra white analyzed. You can clearly see the enrichment of surface aluminum in an area less than 1 µm after procedure according to the invention.
La figura 3 muestra estabilidad térmica de las capas y también los pasos de tratamiento. Una vez acabado el tratamiento, los vidrios fríos se sometieron a un tratamiento con llama. Se comprobó que la clara mejora de las resistencias hidrolíticas se mantenía de forma reproducible.Figure 3 shows thermal stability of the layers and also the treatment steps. Once the treatment, the cold glasses underwent a treatment with call. It was found that the clear improvement of the resistance Hydrolytic was kept reproducible.
En un horno de mufla se introdujo una cantidad definida (0,05 g y 0,15 g) de AlCl_{3} junto con una muestra de vidrio de plomo de 25 cm^{2} en un crisol de corindón, que se cubrió con lámina de aluminio. Después de un calentamiento a 470ºC y un tiempo de mantenimiento de 15 minutos, con desconexión final del horno de mufla y enfriamiento de las muestras en el crisol, se analizó la microdureza de los vidrios. Los resultados están representados en la figura 4 y muestran un aumento de más de un 100% de la microdureza después de una profundidad de penetración de 150 nm, y dicha microdureza puede adoptar valores incluso mucho mayores en caso de profundidades de penetración menores.A quantity was introduced in a muffle oven defined (0.05 g and 0.15 g) of AlCl 3 together with a sample of 25 cm2 lead glass in a corundum crucible, which is covered with aluminum foil. After heating at 470 ° C and a maintenance time of 15 minutes, with final disconnection of the muffle furnace and cooling the samples in the crucible, it analyzed the microhardness of the glasses. The results are represented in figure 4 and show an increase of more than 100% of the microhardness after a penetration depth of 150 nm, and said microhardness can adopt even much higher values in case of lower penetration depths.
Claims (5)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10319708 | 2003-05-02 | ||
| DE10319708A DE10319708A1 (en) | 2003-05-02 | 2003-05-02 | Alkali-containing glasses with modified glass surfaces and process for their preparation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2347559T3 true ES2347559T3 (en) | 2010-11-02 |
Family
ID=33394055
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES04730521T Expired - Lifetime ES2347559T3 (en) | 2003-05-02 | 2004-04-30 | ALKALINE GLASSES WITH MODIFIED SURFACES AND PROCEDURE FOR PRODUCTION. |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US20070141349A1 (en) |
| EP (1) | EP1622842B1 (en) |
| JP (1) | JP2006525211A (en) |
| KR (1) | KR20060027313A (en) |
| CN (1) | CN100379700C (en) |
| AT (1) | ATE471304T1 (en) |
| AU (1) | AU2004234072B8 (en) |
| BR (1) | BRPI0410028A (en) |
| CA (1) | CA2524383A1 (en) |
| CO (1) | CO5660285A2 (en) |
| DE (2) | DE10319708A1 (en) |
| ES (1) | ES2347559T3 (en) |
| MX (1) | MXPA05011560A (en) |
| PL (1) | PL1622842T3 (en) |
| RU (1) | RU2005135867A (en) |
| WO (1) | WO2004096724A1 (en) |
| ZA (1) | ZA200508215B (en) |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL1753702T3 (en) * | 2004-05-07 | 2010-04-30 | Sklostroj Turnov Cz S R O | Method for treating the surface of glasses with metallic aluminium |
| DE102006019399A1 (en) * | 2006-04-24 | 2007-10-25 | Docter Optics Gmbh | Method for producing a headlight lens for a motor vehicle headlight |
| US20080022721A1 (en) * | 2006-07-25 | 2008-01-31 | Bernd Disteldorf | Method of making glass including surface treatment with aluminum chloride at or just prior to annealing lehr |
| US8677782B2 (en) | 2006-07-25 | 2014-03-25 | Guardian Industries Corp. | Method of making glass including surface treatment with aluminum chloride at or just prior to annealing LEHR |
| DE102006034431A1 (en) * | 2006-07-26 | 2008-01-31 | Technische Universität Bergakademie Freiberg | Production of an alkali-containing glass with a modified surface comprises contacting the hot surfaces of the glass with aluminum chloride compounds in the vapor phase at a reduced oxygen partial pressure |
| US7923063B2 (en) | 2007-12-10 | 2011-04-12 | Centre Luxembourgeois De Recherches Pour Le Verre Et La Ceramique S.A. (C.R.V.C.) | Method of making glass including surface treatment with aluminum chloride using combustion deposition prior to deposition of antireflective coating |
| DE102008046044A1 (en) | 2008-09-08 | 2010-03-11 | Technische Universität Bergakademie Freiberg | Producing thermally tempered glasses, comprises heating the glasses in a first process stage and then subjecting to a sudden cooling with media in a second process stage |
| DE102008062359A1 (en) | 2008-12-17 | 2010-06-24 | Technische Universität Bergakademie Freiberg | Manufacturing thermally hardened thin flat glasses, comprises portioning flat glass to glass plates after molding and/or forming the glass to glass plates by press molding, and subjecting the glass plates to strength-increasing treatments |
| DE102009031267B4 (en) * | 2009-06-30 | 2012-06-06 | Technische Universität Bergakademie Freiberg | Lubricant for hot glass processes and use of the lubricant for surface treatment of glass |
| TR201816041T4 (en) | 2009-06-30 | 2018-11-21 | Hessenkemper Heiko | The lubricant for hot glass processes and the use of the lubricant to improve the glass surface. |
| WO2013050363A1 (en) * | 2011-10-04 | 2013-04-11 | Agc Glass Europe | Glass article with improved chemical resistance |
| DE102013013377A1 (en) | 2013-08-10 | 2015-02-12 | Advanced Acoustic Sf Gmbh | Decentral structure of a wave field synthesis system |
| CN107108314B (en) | 2014-12-31 | 2020-03-31 | 康宁股份有限公司 | Method of treating glass articles |
| JP6827933B2 (en) | 2014-12-31 | 2021-02-10 | コーニング インコーポレイテッド | How to heat treat glass articles |
| KR102610962B1 (en) * | 2016-08-02 | 2023-12-08 | 삼성디스플레이 주식회사 | Method for treating glass substrate |
| US11826935B2 (en) | 2018-03-20 | 2023-11-28 | Docter Optics Se | Method for producing a lens element |
| DE102020109869A1 (en) | 2019-05-03 | 2020-11-05 | Docter Optics Se | Process for the production of an optical element from glass |
| DE102020115083A1 (en) | 2019-07-13 | 2021-01-14 | Docter Optics Se | Method for manufacturing a headlight lens for a vehicle headlight |
| US20220298050A1 (en) | 2019-07-13 | 2022-09-22 | Docter Optics Se | Method for producing an optical element from glass |
| WO2021104558A1 (en) | 2019-11-28 | 2021-06-03 | Docter Optics Se | Method for producing an optical element from glass |
| DE102020115079A1 (en) | 2020-06-05 | 2021-12-09 | Docter Optics Se | Process for the production of an optical element from glass |
| DE102020127639A1 (en) | 2020-10-20 | 2022-04-21 | Docter Optics Se | Process for manufacturing an optical element from glass |
| DE112021002952A5 (en) | 2020-10-20 | 2023-04-13 | Docter Optics Se | Process for manufacturing an optical element from glass |
| DE102020127638A1 (en) | 2020-10-20 | 2022-04-21 | Docter Optics Se | Glass optical element |
| DE102022101728A1 (en) | 2021-02-01 | 2022-08-04 | Docter Optics Se | Process for manufacturing an optical element from glass |
| DE102021105560A1 (en) | 2021-03-08 | 2022-09-08 | Docter Optics Se | Process for manufacturing an optical element from glass |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2455719A (en) * | 1945-06-01 | 1948-12-07 | Woldemar A Weyl | Glass manufacture |
| US3281225A (en) * | 1965-09-30 | 1966-10-25 | Brockway Glass Co Inc | Method of increasing the durability of glassware |
| US3537848A (en) * | 1967-10-20 | 1970-11-03 | Xerox Corp | Process of treating a xerographic glass binder plate and product |
| US3998617A (en) * | 1968-10-24 | 1976-12-21 | Jenaer Glaswerk Schott & Gen. | Method of improving the mechanical strength of glass |
| US3847643A (en) * | 1973-01-22 | 1974-11-12 | Gen Electric | Surface treatment of fluorescent lamp bulbs and other glass objects |
| US4164402A (en) * | 1978-02-27 | 1979-08-14 | Yamamura Glass Co., Ltd. | Strengthening of thin-walled, light glass containers |
| US4228206A (en) * | 1979-05-18 | 1980-10-14 | Gte Products Corporation | Method of processing glass tubing |
| US4276350A (en) * | 1979-08-13 | 1981-06-30 | Ppg Industries, Inc. | Fluorocarbon treatment for reducing the reactivity of a glass surface and product |
| JPS60176952A (en) * | 1984-02-23 | 1985-09-11 | Asahi Glass Co Ltd | Method for preventing weathering of glass |
| US4717607A (en) * | 1987-03-11 | 1988-01-05 | Gte Products Corporation | Method of making a fluorescent lamp |
| NL9100335A (en) * | 1991-02-26 | 1992-09-16 | Philips Nv | METHOD FOR MANUFACTURING TUBE GLASS. |
| FR2700764B1 (en) * | 1993-01-26 | 1995-04-14 | Lalique | Method for the surface treatment of glass articles, in particular crystal and articles thus obtained. |
| FR2744440B1 (en) * | 1996-02-07 | 1998-03-20 | Saint Gobain Vitrage | PROCESS FOR TREATING GLASS SUBSTRATES |
| GB2329382A (en) * | 1997-09-23 | 1999-03-24 | Glaverbel | Chemical treatment of vitreous material |
| DE10045923C2 (en) * | 1999-09-15 | 2002-08-14 | Schott Rohrglas Gmbh | Method and device for producing internally tempered glass tubes and their use |
| AUPQ872800A0 (en) * | 2000-07-12 | 2000-08-03 | Heart Research Institute, The | Compositions and methods for treating cardiovascular disorders |
| US6462214B1 (en) * | 2002-03-05 | 2002-10-08 | Dow Corning Corporation | Method of preparing silacycloalkanes |
| DE10246928A1 (en) | 2002-10-08 | 2004-04-22 | Tu Bergakademie Freiberg | To coat a surface with an enamel, the enamel surface is treated during firing with sulfur gases or fluorides and/or steam to prevent a back dispersion of alkali |
| AU2004232803C1 (en) * | 2003-04-22 | 2010-05-13 | The Coca-Cola Company | Method and apparatus for strengthening glass |
-
2003
- 2003-05-02 DE DE10319708A patent/DE10319708A1/en not_active Withdrawn
-
2004
- 2004-04-30 RU RU2005135867/03A patent/RU2005135867A/en unknown
- 2004-04-30 BR BRPI0410028-0A patent/BRPI0410028A/en not_active IP Right Cessation
- 2004-04-30 WO PCT/EP2004/004642 patent/WO2004096724A1/en active Application Filing
- 2004-04-30 PL PL04730521T patent/PL1622842T3/en unknown
- 2004-04-30 MX MXPA05011560A patent/MXPA05011560A/en unknown
- 2004-04-30 CN CNB200480011839XA patent/CN100379700C/en not_active Expired - Fee Related
- 2004-04-30 JP JP2006505352A patent/JP2006525211A/en not_active Ceased
- 2004-04-30 US US10/553,011 patent/US20070141349A1/en not_active Abandoned
- 2004-04-30 EP EP04730521A patent/EP1622842B1/en not_active Expired - Lifetime
- 2004-04-30 KR KR1020057020719A patent/KR20060027313A/en not_active Application Discontinuation
- 2004-04-30 CA CA002524383A patent/CA2524383A1/en not_active Abandoned
- 2004-04-30 ES ES04730521T patent/ES2347559T3/en not_active Expired - Lifetime
- 2004-04-30 DE DE502004011283T patent/DE502004011283D1/en not_active Expired - Lifetime
- 2004-04-30 AT AT04730521T patent/ATE471304T1/en active
- 2004-04-30 AU AU2004234072A patent/AU2004234072B8/en not_active Ceased
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2005
- 2005-10-11 ZA ZA200508215A patent/ZA200508215B/en unknown
- 2005-12-01 CO CO05121911A patent/CO5660285A2/en not_active Application Discontinuation
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| KR20060027313A (en) | 2006-03-27 |
| US20070141349A1 (en) | 2007-06-21 |
| MXPA05011560A (en) | 2006-03-09 |
| PL1622842T3 (en) | 2010-09-30 |
| CN1784365A (en) | 2006-06-07 |
| DE10319708A1 (en) | 2004-11-25 |
| ZA200508215B (en) | 2006-06-28 |
| JP2006525211A (en) | 2006-11-09 |
| RU2005135867A (en) | 2006-06-10 |
| EP1622842A1 (en) | 2006-02-08 |
| WO2004096724A1 (en) | 2004-11-11 |
| AU2004234072B2 (en) | 2009-08-20 |
| EP1622842B1 (en) | 2010-06-16 |
| BRPI0410028A (en) | 2006-04-25 |
| ATE471304T1 (en) | 2010-07-15 |
| DE502004011283D1 (en) | 2010-07-29 |
| CO5660285A2 (en) | 2006-07-31 |
| AU2004234072B8 (en) | 2009-09-17 |
| AU2004234072A1 (en) | 2004-11-11 |
| CA2524383A1 (en) | 2004-11-11 |
| CN100379700C (en) | 2008-04-09 |
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