ES2264372B1 - SAFETY STRIP, SECURITY PAPER THAT INCLUDES SUCH STRIP AND SECURITY DOCUMENT AND TICKET THAT INCORPORATE SUCH PAPER. - Google Patents
SAFETY STRIP, SECURITY PAPER THAT INCLUDES SUCH STRIP AND SECURITY DOCUMENT AND TICKET THAT INCORPORATE SUCH PAPER. Download PDFInfo
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- ES2264372B1 ES2264372B1 ES200500563A ES200500563A ES2264372B1 ES 2264372 B1 ES2264372 B1 ES 2264372B1 ES 200500563 A ES200500563 A ES 200500563A ES 200500563 A ES200500563 A ES 200500563A ES 2264372 B1 ES2264372 B1 ES 2264372B1
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- 239000000835 fiber Substances 0.000 claims abstract description 44
- 239000000758 substrate Substances 0.000 claims abstract description 27
- 239000000049 pigment Substances 0.000 claims abstract description 26
- 238000004519 manufacturing process Methods 0.000 claims description 15
- 235000013311 vegetables Nutrition 0.000 claims description 12
- 239000000976 ink Substances 0.000 claims description 3
- 229920000914 Metallic fiber Polymers 0.000 claims description 2
- 229920002678 cellulose Polymers 0.000 claims description 2
- 239000001913 cellulose Substances 0.000 claims description 2
- 238000004040 coloring Methods 0.000 claims description 2
- 230000001788 irregular Effects 0.000 claims description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 238000000034 method Methods 0.000 description 14
- 238000010348 incorporation Methods 0.000 description 9
- 241000196324 Embryophyta Species 0.000 description 8
- 239000010410 layer Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000004922 lacquer Substances 0.000 description 4
- 239000000470 constituent Substances 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000007767 bonding agent Substances 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 230000005389 magnetism Effects 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- 240000000491 Corchorus aestuans Species 0.000 description 1
- 235000011777 Corchorus aestuans Nutrition 0.000 description 1
- 235000010862 Corchorus capsularis Nutrition 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000219146 Gossypium Species 0.000 description 1
- 240000006240 Linum usitatissimum Species 0.000 description 1
- 235000004431 Linum usitatissimum Nutrition 0.000 description 1
- 230000008275 binding mechanism Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 210000000481 breast Anatomy 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
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- 230000006866 deterioration Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 238000004020 luminiscence type Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000019612 pigmentation Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
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- 239000002356 single layer Substances 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 238000012549 training Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/40—Agents facilitating proof of genuineness or preventing fraudulent alteration, e.g. for security paper
- D21H21/42—Ribbons or strips
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
-
- B42D15/10—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/355—Security threads
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/40—Agents facilitating proof of genuineness or preventing fraudulent alteration, e.g. for security paper
- D21H21/44—Latent security elements, i.e. detectable or becoming apparent only by use of special verification or tampering devices or methods
- D21H21/48—Elements suited for physical verification, e.g. by irradiation
Landscapes
- Paper (AREA)
- Credit Cards Or The Like (AREA)
- Laminated Bodies (AREA)
Abstract
Tira de seguridad, papel de seguridad que incorpora dicha tira y documento de seguridad y billete que incorporan dicho papel. Tira de seguridad (1) y papel de seguridad (8) para la obtención de documentos de seguridad tales como billetes (9) de curso legal, talones o documentos de identificación, que comprende una banda de soporte (2) celulósico que queda completamente embebida en un sustrato (3) de masa de papel. Al estar tanto el sustrato (3) como la banda de soporte (2) formadas por fibras vegetales (4), se establecen entre las fibras (4) de ambos elementos una serie de uniones físico-químicas, quedando así la banda de soporte (2) perfectamente integrada en la masa de papel. La banda de soporte (2) celulósico presentará en ocasiones una serie de elementos de seguridad, tales como pigmentos (5), elementos sintéticos (6) y/o fibras de seguridad (7) de las normalmente utilizadas en este tipo de aplicación.Security strip, security paper that incorporates said strip and security document and ticket incorporating said paper. Security strip (1) and security paper (8) for obtaining security documents such as legal tender notes (9), heels or identification documents, comprising a cellulosic support band (2) that is completely embedded in a substrate (3) of paper mass. Being both the substrate (3) and the support band (2) formed by plant fibers (4), a series of physical-chemical bonds are established between the fibers (4), thus leaving the support band ( 2) perfectly integrated in the mass of paper. The cellulosic support band (2) will sometimes present a series of safety elements, such as pigments (5), synthetic elements (6) and / or security fibers (7) of those normally used in this type of application.
Description
Tira de seguridad, papel de seguridad que incorpora dicha tira y documento de seguridad y billete que incorporan dicho papel.Security strip, security paper that incorporates said strip and security document and ticket that incorporate said paper.
La presente invención se refiere a un papel de seguridad para la fabricación de documentos de valor (billetes bancarios, talones, etc.) o documentos de identificación (pasaportes, permisos de conducción, etc.), así como a la tira de seguridad que, comprendida en dicho papel, dificulta la falsificación del mismo.The present invention relates to a role of security for the manufacture of valuable documents (banknotes bank, heels, etc.) or identification documents (passports, driving licenses, etc.), as well as to the strip of security that, included in that role, hinders the counterfeit of it.
El papel de seguridad objeto de esta invención comprende un sustrato, que consiste en una masa de papel, en el que se embeben una serie de soportes celulósicos que a su vez pueden contener gran variedad de elementos de seguridad.The security paper object of this invention it comprises a substrate, which consists of a mass of paper, in which a series of cellulosic supports are embedded that in turn can Contain a variety of security features.
El intento de falsificación de documentos de valor, especialmente billetes, es una actividad fraudulenta tan antigua como la propia existencia de dichos documentos.The attempted falsification of documents of value, especially tickets, is such a fraudulent activity Ancient as the very existence of such documents.
Englobados bajo el concepto de elemento de seguridad se entienden todos aquellos elementos que contribuyen a la autentificación del documento en cuestión o dificultan en la medida de lo posible su falsificación. Dichos elementos de seguridad consisten básicamente en un revestimiento particular en la superficie del sustrato o bien en un elemento comprendido o aplicado a la superficie del sustrato.Included under the concept of element of security are understood all those elements that contribute to the authentication of the document in question or hinder the as far as possible forgery. These elements of security basically consist of a particular coating in the surface of the substrate either in an element comprised or applied to the surface of the substrate.
Es conocida la utilización de procesos especiales de impresión que dotan a los documentos de seguridad de un relieve perceptible al tacto, tal y como el incorporado en algunos elementos de los actuales billetes de distintas denominaciones de euros. Estas marcas táctiles cumplen además la finalidad de ayudar a los invidentes a la identificación de dichos documentos.The use of processes is known printing specials that provide security documents with a touch perceptible relief, just like the one incorporated in some elements of the current bills of different denominations of euros. These touch marks also meet the purpose of helping blind people to identify said documents
En contraposición al método anterior, es conocida asimismo la incorporación de marcas de seguridad formadas por orificios, marcas que presentan, al igual que las anteriores, la ventaja de ser fácilmente verificables sin necesidad de utilizar un equipo especial. El documento ES 2 145 486 T3 describe un método para realizar marcas de este tipo utilizando luz de láser, método a partir del cual se obtienen orificios que tienen un diámetro tal que son invisibles cuando se les mira en reflexión mientras que son visibles a simple vista cuando se les mira en transmisión, es decir, cuando se mira a través de ellos frente a una fuente de luz.In contrast to the previous method, it is also known the incorporation of security marks formed through holes, brands that present, like the previous ones, the advantage of being easily verifiable without using A special team. Document ES 2 145 486 T3 describes a method to make marks of this type using laser light, method a from which holes are obtained that have such a diameter that are invisible when you look at them in reflection while they are visible to the naked eye when viewed in transmission, it is say, when you look through them in front of a source of light.
Los documentos de seguridad, especialmente los billetes bancarios, frecuentemente incorporan dispositivos ópticamente variables tales como hilos de seguridad, hologramas, elementos de capa de interferencia o materiales de cristal líquido que ofrecen distintos efectos de color dependiendo del ángulo de visión, dificultando enormemente la falsificación por fotocopiado del documento.Security documents, especially those banknotes, frequently incorporate devices optically variable such as security threads, holograms, interference layer elements or liquid crystal materials that offer different color effects depending on the angle of vision, making photocopying falsely difficult of the document.
Un elemento de seguridad habitual es la incorporación en los documentos de valor de las llamadas marcas de agua, que representan una figura o conjunto de caracteres solamente apreciables al mirar el documento a contraluz. La fabricación de papeles incorporando este tipo de marcas se realiza en máquinas para fabricar papel con tambor cilíndrico perforado, con lo cual las elevaciones o zonas impermeables al agua sobre la superficie de dicho tambor provocan la reducción del depósito de las fibras y por tanto el pliego de papel así fabricado presenta localmente distintos grosores.A common security element is the incorporation into the value documents of the so-called brands of water, representing a figure or set of characters only Appreciable when looking at the document in backlight. The manufacture of papers incorporating these types of brands are made in machines to make paper with perforated cylindrical drum, with which elevations or areas impervious to water on the surface of said drum cause the reduction of the deposit of the fibers and therefore the sheet of paper thus manufactured presents locally different thicknesses.
En cuanto a la incorporación de hologramas en los documentos de seguridad, el método habitual consiste en fabricar los llamados hologramas principales y a partir de ellos embutir los hologramas requeridos por copia en las matrices de prensado, obteniendo así grandes cantidades de hologramas. Los hologramas embutidos son normalmente fabricados como elementos de múltiples capas sobre un portador separado, de manera que se unen al documento en cuestión por medio de una capa de material adhesivo. Este método de fabricación presenta una deficiencia respecto a la seguridad del documento, ya que es posible retirar el holograma del documento por calentamiento del material adhesivo y por tanto transferir dicho holograma a un documento falso, pegándolo a él.Regarding the incorporation of holograms in Security documents, the usual method consists of manufacture the so-called main holograms and from them embed the holograms required by copy in the matrices of pressing, thus obtaining large amounts of holograms. The Inlaid holograms are normally manufactured as elements of multiple layers on a separate carrier, so that they join to the document in question through a layer of material adhesive. This manufacturing method has a deficiency regarding the security of the document, since it is possible to remove the document hologram by heating the adhesive material and therefore transfer said hologram to a false document, hitting him.
El documento EP 0 338 378 B1 describe un proceso de fabricación de documentos de seguridad incluyendo hologramas que soluciona el inconveniente anterior, pues en este caso el holograma se embute directamente sobre el material constitutivo del documento, imprimiendo el papel en primer lugar por ambas caras y dotando posteriormente a dicho papel de una estructura holográfica en determinadas zonas. El proceso consiste en transferir simultáneamente al papel constitutivo del documento de seguridad tanto la laca para embutición como la estructura de relieve del holograma, recubriendo la estructura superficial de la matriz de la prensa con una laca curable. Una vez la matriz y el papel se ponen en contacto la laca queda adherida, tras su curado, a la superficie del papel, presentando una estructura holográfica en relieve. Posteriormente se aplica en vacío una delgada capa metalizada que permite la observación por reflexión de la información holográfica. El inconveniente de este proceso de fabricación radica en la necesidad de curar la laca mediante radiación de electrones, curado que resulta complejo, perjudicial para el papel y que implica elevados costes.EP 0 338 378 B1 describes a process of security document manufacturing including holograms which solves the previous problem, because in this case the hologram is embedded directly on the constituent material of the document, printing the paper first on both sides and subsequently providing said paper with a holographic structure in certain areas. The process consists of transferring simultaneously to the constituent role of the security document both the lacquer for drawing and the relief structure of the hologram, covering the surface structure of the matrix of the Press with a curable lacquer. Once the matrix and the paper are put in contact the lacquer is adhered, after curing, to the paper surface, presenting a holographic structure in relief. Subsequently a thin layer is applied under vacuum metallized that allows observation by reflection of the holographic information. The inconvenience of this process of manufacturing lies in the need to cure lacquer by electron radiation, curing that is complex, harmful for paper and that implies high costs.
En vista de lo anterior el objetivo de la presente invención es desarrollar un papel constitutivo de documentos de seguridad que permita la incorporación de diversos elementos de seguridad que no puedan desprenderse fácilmente de dichos documentos y que impidan en gran medida su falsificación, siendo deseable asimismo que el papel obtenido presente superficies homogéneas y sea estable a todos los efectos.In view of the above the objective of the The present invention is to develop a constitutive role of security documents that allow the incorporation of various security elements that cannot be easily detached from such documents and that largely prevent their falsification, it is also desirable that the paper obtained has surfaces homogeneous and be stable for all purposes.
La invención consiste en una tira de seguridad que comprende una banda de soporte celulósico formada por fibras vegetales.The invention consists of a safety strip comprising a cellulosic support band formed by fibers vegetables.
Las fibras vegetales que pueden ser empleadas para la fabricación de dicha banda de soporte provienen de la madera o bien se trata de fibras que provienen directamente de las plantas y se extraen del tronco, ramas, corteza, raíces, hojas, tallos, etc. El algodón, el lino, el cáñamo y el yute son algunas de estas plantas productoras de celulosa, si bien no se descarta la posibilidad de obtener las fibras de otras muchas plantas o incluso de la paja de los cereales. Una vez obtenidas las fibras vegetales se fabrica una banda continua de dimensiones variables en función de su aplicación final, si bien en la mayoría de los casos presentará una sección básicamente rectangular de pequeñas dimensiones. El tipo de papel que conforma esta banda de soporte celulósico es un papel especial de gramaje (hasta 80 g/m^{2}) y espesor reducido adecuados para esta aplicación.Vegetable fibers that can be used for the manufacture of said support band come from the wood or fibers that come directly from the plants and are extracted from the trunk, branches, bark, roots, leaves, stems, etc. Cotton, flax, hemp and jute are some of these cellulose producing plants, although the possibility of obtaining the fibers of many other plants or even of cereal straw. Once the fibers are obtained vegetables a continuous band of variable dimensions is manufactured in function of your final application, although in most cases present a basically rectangular section of small dimensions. The type of paper that makes up this support band Cellulosic is a special paper of weight (up to 80 g / m2) and reduced thickness suitable for this application.
La tira de seguridad objeto de esta invención comprende al menos una banda de soporte celulósico tal y como se ha descrito anteriormente, si bien puede incorporar dicha tira de seguridad otros elementos, tales como los elementos de seguridad normalmente utilizados en este tipo de aplicación, elementos cuya finalidad es dificultar en la medida de lo posible la falsificación de dicha tira de seguridad. Entre los elementos de seguridad que pueden ser incorporados en la mencionada tira, y que se detallarán más adelante, se contempla el uso de pigmentos de seguridad, elementos sintéticos y fibras de seguridad, tanto de manera individual como combinando elementos de los diferentes tipos en una misma tira de seguridad.The security strip object of this invention it comprises at least one cellulosic support band as it has been described above, although you can incorporate said strip of security other elements, such as security elements normally used in this type of application, elements whose purpose is to make counterfeit as much as possible of said security strip. Among the security elements that they can be incorporated in the mentioned strip, and that will be detailed later, the use of safety pigments is contemplated, synthetic elements and security fibers, both so individual as combining elements of different types in a Same security strip.
El objeto de la invención sin embargo no se limita exclusivamente a la tira de seguridad anteriormente descrita sino que comprende además el papel de seguridad que la contiene. Dicho papel de seguridad comprende un sustrato y al menos una tira de seguridad.The object of the invention however is not limited exclusively to the security strip described above It also includes the security paper that contains it. Said security paper comprises a substrate and at least one strip of security.
El sustrato consiste en una masa de papel que comprende fibras vegetales de las normalmente utilizadas para la fabricación de este tipo de papel, es decir, se trata de fibras higroscópicas que absorben la humedad. El proceso de fabricación de este sustrato es el habitual en la obtención de papel, mezclando las fibras en las proporciones requeridas y formando la pasta acuosa que contiene las fibras vegetales.The substrate consists of a mass of paper that comprises plant fibers of those normally used for manufacture of this type of paper, that is, it is fibers hygroscopic that absorb moisture. The manufacturing process of This substrate is the usual one in obtaining paper, mixing the fibers in the required proportions and forming the paste aqueous that contains plant fibers.
La tira de seguridad, como se ha indicado anteriormente, comprende al menos una banda de soporte celulósico. Dicha banda, obtenida independientemente del sustrato, se introduce en la máquina de papel en la que se está fabricando el sustrato, concretamente en el momento en el que se está formando la hoja de papel húmeda. Por medio de un sistema de aplicación electromecánico, consistente en un sistema de alimentación de la banda específico para esta aplicación, compuesto por un conjunto de desbobinado y un sistema regulador de tensión, se introducen tantas bandas de soporte celulósico como se desee, bien en la formación de la hoja de papel con una única capa o bien en la formación de la hoja de papel utilizando dos capas de papel que se unen en la etapa de formación de la hoja, de manera que el resultado final es una sola hoja de papel. Se pueden introducir tantas bandas de soporte celulósico como se desee, con la anchura de banda que se determine y aplicándola en los puntos que se consideren adecuados según la aplicación posterior que vaya a darse al papel de seguridad obtenido. También es posible introducir la o las bandas en la masa de papel según distintas orientaciones, es decir, paralelas, perpendiculares o formando un determinado ángulo respecto del eje principal de la hoja de papel que se está fabricando.The safety strip, as indicated previously, it comprises at least one cellulosic support band. Said band, obtained independently of the substrate, is introduced in the paper machine where the substrate is being manufactured, specifically at the moment when the sheet is forming wet paper Through an application system electromechanical, consisting of a power system of the specific band for this application, consisting of a set of unwind and a voltage regulator system, so many are introduced cellulosic support bands as desired, either in the formation of the sheet of paper with a single layer or in the formation of the sheet of paper using two layers of paper that are joined at the stage sheet formation, so that the end result is a single sheet of paper You can enter as many support bands cellulosic as desired, with the bandwidth determined and applying it in the points that are considered appropriate according to the subsequent application to be given to the security paper obtained. It is also possible to introduce the band or bands into the dough of paper according to different orientations, that is, parallel, perpendicular or forming a certain angle to the axis Main sheet of paper being manufactured.
Al tratarse de fibras vegetales, tanto las constitutivas de la banda de soporte como las del sustrato, las uniones físico-químicas son similares, puesto que el mecanismo de unión de fibras es prácticamente el mismo independientemente del origen de las fibras vegetales. Al ser su estructura compatible y tratarse además de fibras higroscópicas, al introducirse las bandas de soporte celulósico en el sustrato de masa de papel en formación, el soporte celulósico es absorbido por afinidad dentro de la hoja de fibras con agua y ya dentro de ese seno (hoja de papel húmeda) pierde su sequedad inicial, pasando sus propias fibras celulósicas a combinarse y formar uniones físico-químicas con el resto de fibras de la hoja en formación. Estas uniones se ven a su vez reforzadas por los efectos de los agentes encolantes que se incorporan en el proceso de fabricación del sustrato, ya sea dicha incorporación en masa o en superficie. Se continúa posteriormente con el proceso habitual de formación de hoja, con los elementos de desgote y prensado comúnmente utilizados, perdiendo la hoja final paulatinamente el agua y pasando por la fase de sequería, llegando así hasta el final del proceso y obteniéndose un papel de seguridad homogéneo, estable y con sus superficies lisas, es decir, la banda de soporte celulósico no es apreciable al tacto puesto que queda perfectamente integrada en el cuerpo de la hoja.Since they are vegetable fibers, both constitutive of the support band such as the substrate, physical-chemical unions are similar, since the fiber binding mechanism is practically the same regardless of the origin of plant fibers. Being his compatible structure and be treated in addition to hygroscopic fibers, when insert the cellulosic support bands into the substrate of mass of paper in formation, the cellulosic support is absorbed by affinity within the fiber sheet with water and already within that breast (wet sheet of paper) loses its initial dryness, passing its own cellulosic fibers to combine and form joints physicochemical with the rest of the fibers of the leaf In training. These unions are in turn reinforced by the effects of the bonding agents that are incorporated into the process of manufacturing the substrate, either said mass incorporation or on the surface The usual process is continued later sheet forming, with the elements of drainage and pressing commonly used, losing the final sheet gradually the water and going through the drying phase, thus reaching the end of the process and obtaining a homogeneous, stable security role and with its smooth surfaces, that is, the support band cellulosic is not appreciable to the touch since it fits perfectly integrated in the body of the leaf.
Según este método se consigue que la banda de soporte celulósico quede embebida en el sustrato de masa de papel, es decir, las superficies de dicha banda quedan recubiertas completamente por el sustrato, pudiendo ser el grosor de la capa de masa de papel que cubre la banda distinto en cada una de sus superficies inferior y superior, por lo que no se limita la invención a un posicionamiento centrado de dicha banda dentro del sustrato, sino que la misma puede estar desplazada superior o inferiormente.According to this method, the band of cellulosic support is embedded in the paper dough substrate, that is, the surfaces of said band are coated completely by the substrate, being able to be the thickness of the layer of mass of paper covering the different band in each of its lower and upper surfaces, so the invention to a centered positioning of said band within the substrate, but it may be displaced higher or inferiorly.
Tal y como se ha adelantado anteriormente, la tira de seguridad que comprende una banda de soporte celulósico puede comprender además una serie de elementos de seguridad. Estos elementos de seguridad pueden encontrarse adheridos a las superficies de dicha banda o bien contenidos en su interior, soportados por las fibras vegetales constitutivas de la banda de soporte celulósico. Estos elementos, que son los propios de este tipo de aplicaciones, evitan o dificultan en la medida de lo posible la falsificación de los documentos que se obtienen a partir del papel de seguridad fabricado.As previously advanced, the safety strip comprising a cellulosic support band It can also comprise a series of security elements. These security elements may be attached to the surfaces of said band or contained within it, supported by the constituent plant fibers of the band of cellulosic support. These elements, which are typical of this type of applications, avoid or hinder as far as possible forgery of documents obtained from of manufactured security paper.
Los elementos de seguridad pueden consistir en la incorporación en la banda de soporte de pigmentos de seguridad, elementos sintéticos de seguridad, fibras de seguridad o cualquier otro material o producto que se considere adecuado. Se contempla la posibilidad de que una misma banda de soporte incorpore distintos elementos de seguridad, pertenecientes o no al mismo grupo de los definidos según la clasificación anterior.The security elements may consist of the incorporation into the safety pigment support band, synthetic safety elements, security fibers or any other material or product deemed appropriate. The possibility that the same support band incorporates different security elements, belonging or not to the same group of defined according to the previous classification.
Los pigmentos podrán ser integrados en la masa de la banda o formar parte de una tinta con la que se impriman caracteres (alfanuméricos, símbolos, figuras, puntos, códigos de barras, etc.) sobre la superficie de la banda, considerándose igualmente la posibilidad de que una misma banda comprenda pigmentos integrados en su masa así como caracteres impresos en su superficie. Así, se contemplan pigmentos utilizados normalmente en la coloración del papel, en la fabricación de tintas y todos aquellos que se utilizan con algún rasgo de seguridad añadido como son fluorescentes, fosforescentes, luminiscentes, termosensibles, magnéticos, expandibles, etc.The pigments can be integrated into the dough of the band or be part of an ink with which they are printed characters (alphanumeric, symbols, figures, points, codes bars, etc.) on the surface of the band, considering also the possibility that the same band understands pigments integrated in its mass as well as characters printed on its surface. Thus, pigments normally used in the coloring of the paper, in the manufacture of inks and all those that are used with some added security feature like they are fluorescent, phosphorescent, luminescent, heat sensitive, magnetic, expandable, etc.
La incorporación de elementos sintéticos en la banda de soporte como elemento de seguridad ofrece múltiples posibilidades, pues se pueden incluir en dichos elementos pigmentos como los anteriormente descritos que confieren al propio elemento características de color, fluorescencia, fosforescencia, luminiscencia, termosensibilidad, magnetismo, expansibilidad, etc. Bajo el nombre genérico de elementos sintéticos se engloban esferas, fibrillas y en general cuerpos de cualquier forma, regulares o irregulares, que en ocasiones pueden contener pigmentos de seguridad. Se contempla la posibilidad de que una única banda de soporte celulósico comprenda elementos sintéticos de distinto tipo (por ejemplo esferas y fibrillas), tanto solos como combinados con pigmentos de seguridad en la masa de la banda o impresos sobre su superficie, como se ha descrito previamente.The incorporation of synthetic elements in the Support band as security element offers multiple possibilities, since pigments can be included in these elements as described above that confer on the element itself color characteristics, fluorescence, phosphorescence, luminescence, thermosensitivity, magnetism, expandability, etc. Under the generic name of synthetic elements are included spheres, fibrils and in general bodies of any shape, regular or irregular, which may sometimes contain pigments of security. The possibility of a single band of cellulosic support comprises synthetic elements of different types (for example spheres and fibrils), both alone and in combination with security pigments in the mass of the band or printed on its surface, as previously described.
Entre las posibles fibras de seguridad comprendidas en la banda de soporte, además de las sintéticas con pigmentación que se encuadran en la descripción del párrafo anterior, se consideran las fibras metálicas y/o con características de magnetismo, de diferente geometría y medidas. Al igual que en los casos anteriores, la incorporación de fibras de seguridad de cualquiera de estos tipos puede ir acompañada por la inclusión de pigmentos y/o elementos sintéticos de seguridad.Among the possible security fibers included in the support band, in addition to the synthetic ones with pigmentation that fall within the description of the paragraph above, metallic fibers and / or with characteristics of magnetism, of different geometry and measurements. To the as in the previous cases, the incorporation of fibers of security of any of these types can be accompanied by the inclusion of pigments and / or synthetic safety elements.
La invención contempla también el documento de seguridad que comprende el papel de seguridad descrito anteriormente. El documento de seguridad se obtiene a partir de dicho papel, cortándolo según las dimensiones deseadas para el documento en cuestión e imprimiendo sobre el mismo los caracteres y dibujos en cuestión. Los documentos de seguridad que pueden obtenerse a partir del papel de seguridad se clasifican fundamentalmente en documentos de valor (billetes de curso legal, talones, cheques, etc.) y documentos de identificación (pasaportes, documentos de identidad, etc.), si bien se contempla la posibilidad de que el documento en cuestión tenga cualquier otra finalidad para la que se considere adecuado incorporar elementos de seguridad que impidan la falsificación del mismo.The invention also contemplates the document of security comprising the security role described previously. The security document is obtained from said paper, cutting it according to the desired dimensions for the document in question and printing on it the characters and Drawings in question. The security documents that can Obtained from the security paper are classified mainly in value documents (legal tender, heels, checks, etc.) and identification documents (passports, identity documents, etc.), although it is contemplated the possibility that the document in question has any other purpose for which it is considered appropriate to incorporate elements of security that prevent the falsification of it.
Una de las aplicaciones específicas de la invención consiste en la utilización del papel de seguridad conteniendo la tira de seguridad descrito anteriormente para la obtención de billetes de curso legal, puesto que tales billetes son habitualmente objeto de intento de falsificación debido al valor monetario que representan. El billete así obtenido presenta un elevado grado de seguridad y además presenta ventajas frente a los billetes conocidos, por ejemplo en el hecho de que, al quedar la tira de seguridad comprendiendo los elementos de seguridad completamente embebida en la masa de papel, es imposible proceder a su separación sin que ello conlleve la destrucción del billete en cuestión, lo que dificulta su falsificación.One of the specific applications of the invention involves the use of security paper containing the security strip described above for the obtaining legal tender tickets, since such tickets are usually subject to attempted forgery due to value monetary they represent. The ticket thus obtained presents a high degree of security and also has advantages over known bills, for example in the fact that, when the safety strip comprising the security elements completely embedded in the mass of paper, it is impossible to proceed to their separation without this entailing the destruction of the ticket in issue, which hinders its falsification.
Para complementar la descripción que se está realizando y con objeto de ayudar a una mejor comprensión de las características de la invención, de acuerdo con un ejemplo preferente de realización práctica de la misma, se acompaña como parte integrante de dicha descripción, un juego de dibujos en donde con carácter ilustrativo y no limitativo, se ha representado lo siguiente:To complement the description that is being performing and in order to help a better understanding of the characteristics of the invention, according to an example preferred practical implementation of it, is accompanied as integral part of that description, a set of drawings where with an illustrative and non-limiting nature, what has been represented next:
Figura 1.- Muestra una vista en perspectiva de una tira de seguridad según la invención.Figure 1.- Shows a perspective view of a safety strip according to the invention.
Figura 2.- Muestra una vista en perspectiva de una hoja de papel de seguridad comprendiendo varias bandas de soporte celulósico.Figure 2.- Shows a perspective view of a sheet of security paper comprising several bands of cellulosic support.
Figura 3.- Muestra una vista en detalle de la banda de soporte celulósico conteniendo elementos de seguridad comprendida en el papel de seguridad.Figure 3.- Shows a detailed view of the cellulosic support band containing safety elements included in the security paper.
Figura 4.- Muestra una vista en perspectiva de un billete de curso legal según la invención.Figure 4.- Shows a perspective view of a legal tender according to the invention.
A la vista de las figuras, se puede observar en las mismas un ejemplo de realización de la invención, que consiste en una tira de seguridad (1) que comprende una banda de soporte (2) celulósico formada por fibras vegetales (4). Dicha tira de seguridad (1) es de aplicación en la fabricación de papel destinado a la obtención de documentos de seguridad tales como billetes (9) de curso legal, talones o pasaportes, entre otros.In view of the figures, it can be seen in an exemplary embodiment of the invention, consisting of in a safety strip (1) comprising a support band (2) cellulosic formed by plant fibers (4). Said security strip (1) is applicable in the manufacture of paper intended for obtaining security documents such as tickets (9) from legal course, heels or passports, among others.
En la figura 1 se ha representado una realización concreta de la tira de seguridad (1) objeto de esta invención. En este caso la tira representada comprende elementos de seguridad tales como pigmentos de seguridad (5) impresos en su superficie, elementos sintéticos de seguridad (6) y fibras de seguridad (7) comprendidos en la banda de soporte (2) celulósico.In Figure 1 a concrete realization of the safety strip (1) object of this invention. In this case the strip represented comprises elements of security such as security pigments (5) printed on your surface, synthetic safety elements (6) and fibers of safety (7) included in the support band (2) cellulosic
La figura 2 muestra una vista en perspectiva de una hoja de papel de seguridad (8) tal y como se obtiene tras el paso por los rodillos que confieren al papel la tersura y espesor adecuados, previamente a su paso por la bobinadora que enrollará la hoja de papel. El papel representado comprende un sustrato (3) consistente en una masa de papel constituido a partir de fibras vegetales (4), agua y otros componentes habitualmente adicionados durante el proceso y varias bandas de soporte (2) celulósico completamente embebidas en dicho sustrato (3), quedando dichas bandas, como puede observarse en la figura, perfectamente integradas en la masa de papel. En esta realización concreta se han introducido las bandas de soporte (2) perpendicularmente a la dirección principal de la hoja de papel, considerando como dirección principal aquella según la cual la hoja sale de la máquina. No se descarta sin embargo la posibilidad de disponer dichas bandas en cualquier otra dirección, así como se contempla también la posibilidad de que no afecten a la anchura total de la hoja si la aplicación posterior del papel obtenido así lo requiere.Figure 2 shows a perspective view of a sheet of security paper (8) as obtained after the pass through the rollers that give the paper the smoothness and thickness suitable, before passing through the winder that will wind the paper sheet. The represented paper comprises a substrate (3) consisting of a mass of paper made from fibers vegetables (4), water and other components usually added during the process and several support bands (2) cellulosic completely embedded in said substrate (3), being said bands, as can be seen in the figure, perfectly integrated into the mass of paper. In this specific embodiment they have introduced the support bands (2) perpendicular to the main address of the sheet of paper, considering as main address that according to which the sheet leaves the machine. However, the possibility of having said bands in any other direction, as well as contemplated also the possibility that they do not affect the total width of the sheet if the subsequent application of the paper thus obtained requires
Tal y como se observa con mayor detalle en la figura 3, las fibras vegetales (4) comprendidas en el sustrato (3) de masa de papel y las comprendidas en la banda de soporte (2) celulósico se combinan entre sí y forman uniones físico-químicas entre ellas reforzadas por los efectos de los agentes encolantes que se incorporan en el proceso de fabricación del sustrato (3) ya sea dicha incorporación en masa o en superficie, quedando entonces el sustrato (3) y la banda de soporte (2) perfectamente unidos, de manera que la banda de soporte (2) se integra completamente en dicha masa de papel pero no desaparece como elemento independiente. Esta integración de la banda de soporte (2) celulósico en la masa de papel se debe a que las fibras comprendidas en ambos elementos son fibras vegetales (4) y por tanto su estructura es similar, favoreciendo la aparición de uniones en la zona de contacto banda soporte (2) sustrato (3), además, al tratarse de fibras vegetales y por tanto higroscópicas, es decir, que absorben la humedad, las fibras vegetales (4) de ambos elementos tienden a hincharse, soltándose las fibras (4) adyacentes pertenecientes a un mismo elemento (banda soporte (2) o sustrato (3) de masa de papel) y uniéndose con las fibras (4) adyacentes del otro elemento, dando lugar así a multitud de nuevas uniones entre fibras (4).As seen in more detail in the Figure 3, the vegetable fibers (4) included in the substrate (3) of mass of paper and those included in the support strip (2) cellulosic combine with each other and form joints physicochemical among them reinforced by effects of the bonding agents that are incorporated into the process of manufacturing the substrate (3) either said mass incorporation or on the surface, leaving then the substrate (3) and the band of support (2) perfectly attached, so that the support band (2) is fully integrated into said mass of paper but not It disappears as an independent element. This integration of the support band (2) cellulosic in the paper mass is because the fibers included in both elements are vegetable fibers (4) and therefore its structure is similar, favoring the appearance of joints in the contact area support band (2) substrate (3), in addition, since they are vegetable fibers and therefore hygroscopic, that is, they absorb moisture, the vegetable fibers (4) of both elements tend to swell, releasing the fibers (4) adjacent belonging to the same element (support band (2) or substrate (3) of paper mass) and joining with the fibers (4) adjacent to the other element, thus giving rise to a multitude of new fiber joints (4).
En este caso representado en la figura 3 la banda de soporte (2) celulósico comprende distintos elementos de seguridad, tales como pigmentos de seguridad (5) impresos en una de sus superficies, elementos sintéticos (6) o fibras de seguridad (7) de características especiales para esta aplicación. Estos elementos de seguridad permanecen en la banda de soporte (2) a pesar de que ésta se integre completamente en el sustrato (3).In this case represented in figure 3 the support band (2) cellulosic comprises different elements of security, such as security pigments (5) printed on one of their surfaces, synthetic elements (6) or security fibers (7) of special features for this application. This elements of safety remain in the support band (2) even though it integrates completely into the substrate (3).
Una vez se ha obtenido la hoja de papel de seguridad (8) objeto de esta invención se procede normalmente al corte e impresión de la misma para que dicho papel sirva como base para la obtención de documentos de seguridad de todo tipo, tanto documentos de valor como documentos de identificación. En la figura 4 se ha representado una vista en perspectiva de un billete (9) de curso legal que comprende el papel de seguridad (8) descrito anteriormente. Tal y como se observa en dicha figura, la banda de soporte (2) celulósico que comprende diversos elementos de seguridad queda completamente embebida dentro del papel, siendo el billete (9) obtenido homogéneo (la tira de seguridad (1) no es apreciable al tacto).Once the sheet of paper has been obtained from security (8) object of this invention is usually proceed to cutting and printing it so that said paper serves as the basis for obtaining security documents of all kinds, both valuable documents as identification documents. In the figure 4 a perspective view of a bill (9) of legal course that includes the security role (8) described previously. As can be seen in this figure, the band of cellulosic support (2) comprising various elements of security is completely embedded inside the paper, being the banknote (9) obtained homogeneously (the security strip (1) is not appreciable to the touch).
La fabricación de billetes (9) y otros documentos en base a este papel de seguridad (8) dificulta enormemente la posibilidad de desprender la tira de seguridad (1) para proceder a su falsificación, reduciéndose asimismo el deterioro de dicha tira de seguridad (1) que, en el caso de que se estuviera adherida a una de las superficies del papel, sufriría multitud de desperfectos como consecuencia de su exposición directa al exterior.The manufacture of banknotes (9) and others documents based on this security paper (8) makes it difficult greatly the possibility of detaching the safety strip (1) to proceed to counterfeiting, also reducing the deterioration of said security strip (1) which, in the event that if it adhered to one of the surfaces of the paper, it would suffer multitude of damages as a result of its direct exposure To the exterior.
Claims (14)
Priority Applications (19)
Application Number | Priority Date | Filing Date | Title |
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ES200500563A ES2264372B1 (en) | 2005-03-10 | 2005-03-10 | SAFETY STRIP, SECURITY PAPER THAT INCLUDES SUCH STRIP AND SECURITY DOCUMENT AND TICKET THAT INCORPORATE SUCH PAPER. |
EP12180651.7A EP2527159B1 (en) | 2005-03-10 | 2005-12-30 | Security strip and security paper |
EP05850062.0A EP1872965B2 (en) | 2005-03-10 | 2005-12-30 | Security paper |
ES05850062T ES2516645T5 (en) | 2005-03-10 | 2005-12-30 | security paper |
PT58500620T PT1872965E (en) | 2005-03-10 | 2005-12-30 | Security strip and security paper |
CA002600620A CA2600620A1 (en) | 2005-03-10 | 2005-12-30 | Security strip and security paper |
US11/908,255 US10745861B2 (en) | 2005-03-10 | 2005-12-30 | Security strip and security paper |
ES12180651.7T ES2528908T3 (en) | 2005-03-10 | 2005-12-30 | Security strip and security paper |
PL05850062.0T PL1872965T5 (en) | 2005-03-10 | 2005-12-30 | Security strip and security paper |
RU2007137497/12A RU2397874C2 (en) | 2005-03-10 | 2005-12-30 | Protective strip and counterfeit-protected paper |
PT121806517T PT2527159E (en) | 2005-03-10 | 2005-12-30 | Security strip and security paper |
PCT/ES2005/000712 WO2006095033A1 (en) | 2005-03-10 | 2005-12-30 | Security strip and security paper |
KR1020077020741A KR20080005916A (en) | 2005-03-10 | 2005-12-30 | Security strip and security paper |
PL12180651T PL2527159T3 (en) | 2005-03-10 | 2005-12-30 | Security strip and security paper |
BRPI0520044-0A BRPI0520044A2 (en) | 2005-03-10 | 2005-12-30 | security strip, security paper, security document and legal tender note |
EGNA2007000957 EG25229A (en) | 2005-03-10 | 2007-09-10 | Security strip an security paper. |
MA30279A MA29382B1 (en) | 2005-03-10 | 2007-10-08 | SAFETY BAND AND SECURITY PAPER |
HK08106573.4A HK1117108A1 (en) | 2005-03-10 | 2008-06-13 | Security strip and security paper |
HK13105186.8A HK1178127A1 (en) | 2005-03-10 | 2013-04-29 | Security strip and security paper |
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EP3231938B1 (en) * | 2006-10-27 | 2021-08-04 | Crane & Co., Inc. | A soil and/or moisture resistant secure document |
FR2907947B1 (en) * | 2006-10-31 | 2009-03-20 | Arjowiggins Soc Par Actions Si | METHOD OF AUTHENTICATING AND / OR IDENTIFYING A SECURITY AND / OR VALUE DOCUMENT |
JP5343357B2 (en) * | 2008-01-08 | 2013-11-13 | 凸版印刷株式会社 | Method for producing anti-counterfeit paper medium |
FR2927841A1 (en) * | 2008-02-26 | 2009-08-28 | Arjowiggins Licensing Soc Par | SAFETY SHEET COMPRISING A PELABLE TAPE FOR REVEALING A MASKED INFORMATION, AND METHOD OF MANUFACTURING THE SAME |
FR2952193B1 (en) | 2009-10-30 | 2012-04-20 | Arjowiggins Security | SECURITY ELEMENT COMPRISING AN ADHESIVE AND A SUBSTRATE CARRYING AN OPTICAL STRUCTURE, AND ASSOCIATED METHOD. |
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FR2978580B1 (en) * | 2011-07-28 | 2013-08-16 | Arjowiggins Security | METHOD FOR CONTROLLING THE PHYSICAL STATE OF A DOCUMENT |
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FR2984799A1 (en) | 2011-12-22 | 2013-06-28 | Arjowiggins Security | MULTILAYER STRUCTURE COMPRISING AT LEAST ONE DIFFUSING LAYER |
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FR2838228B1 (en) * | 2002-04-03 | 2005-03-25 | Arjo Wiggins | SECURITY DOCUMENT WITH MARKER |
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ES2299011T3 (en) † | 2004-04-29 | 2008-05-16 | Nv Bekaert Sa | INTEGRATION OF SECURITY PARTICLES IN VALUE DOCUMENTS OR VALUE PRODUCTS. |
ES2606489T5 (en) * | 2004-09-15 | 2022-03-02 | Crane & Co Inc | Security device and new anti-counterfeiting product employing the same |
-
2005
- 2005-03-10 ES ES200500563A patent/ES2264372B1/en active Active
- 2005-12-30 WO PCT/ES2005/000712 patent/WO2006095033A1/en active Application Filing
- 2005-12-30 CA CA002600620A patent/CA2600620A1/en not_active Abandoned
- 2005-12-30 PL PL12180651T patent/PL2527159T3/en unknown
- 2005-12-30 KR KR1020077020741A patent/KR20080005916A/en active Search and Examination
- 2005-12-30 ES ES12180651.7T patent/ES2528908T3/en active Active
- 2005-12-30 ES ES05850062T patent/ES2516645T5/en active Active
- 2005-12-30 PT PT121806517T patent/PT2527159E/en unknown
- 2005-12-30 EP EP05850062.0A patent/EP1872965B2/en active Active
- 2005-12-30 PL PL05850062.0T patent/PL1872965T5/en unknown
- 2005-12-30 BR BRPI0520044-0A patent/BRPI0520044A2/en active IP Right Grant
- 2005-12-30 PT PT58500620T patent/PT1872965E/en unknown
- 2005-12-30 RU RU2007137497/12A patent/RU2397874C2/en active
- 2005-12-30 US US11/908,255 patent/US10745861B2/en active Active
- 2005-12-30 EP EP12180651.7A patent/EP2527159B1/en active Active
-
2007
- 2007-09-10 EG EGNA2007000957 patent/EG25229A/en active
- 2007-10-08 MA MA30279A patent/MA29382B1/en unknown
-
2008
- 2008-06-13 HK HK08106573.4A patent/HK1117108A1/en active IP Right Maintenance
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2013
- 2013-04-29 HK HK13105186.8A patent/HK1178127A1/en unknown
Also Published As
Publication number | Publication date |
---|---|
EP1872965A1 (en) | 2008-01-02 |
RU2007137497A (en) | 2009-04-20 |
KR20080005916A (en) | 2008-01-15 |
CA2600620A1 (en) | 2006-09-14 |
WO2006095033A1 (en) | 2006-09-14 |
ES2516645T5 (en) | 2022-05-12 |
EP2527159A2 (en) | 2012-11-28 |
HK1117108A1 (en) | 2009-01-09 |
EP1872965B2 (en) | 2022-03-23 |
EP2527159A3 (en) | 2013-04-24 |
US20090302595A1 (en) | 2009-12-10 |
PL2527159T3 (en) | 2015-05-29 |
PT2527159E (en) | 2015-02-06 |
EP1872965B1 (en) | 2014-09-24 |
EP1872965A4 (en) | 2010-03-03 |
US10745861B2 (en) | 2020-08-18 |
RU2397874C2 (en) | 2010-08-27 |
ES2264372A1 (en) | 2006-12-16 |
HK1178127A1 (en) | 2013-09-06 |
ES2528908T3 (en) | 2015-02-13 |
ES2516645T3 (en) | 2014-10-31 |
PL1872965T5 (en) | 2023-01-02 |
PL1872965T3 (en) | 2015-02-27 |
EG25229A (en) | 2011-11-17 |
EP2527159B1 (en) | 2014-11-12 |
PT1872965E (en) | 2014-10-15 |
MA29382B1 (en) | 2008-04-01 |
BRPI0520044A2 (en) | 2009-04-14 |
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