ES2237318B1 - PROCEDURE FOR OBTAINING AN ORGANIC ALUMINUM-BASED PRODUCT FOR THE SELF-DEFENSE OF PLANTS AGAINST PATHOGENS FOR ECOLOGICAL TRADITIONAL AGRICULTURE. - Google Patents

PROCEDURE FOR OBTAINING AN ORGANIC ALUMINUM-BASED PRODUCT FOR THE SELF-DEFENSE OF PLANTS AGAINST PATHOGENS FOR ECOLOGICAL TRADITIONAL AGRICULTURE.

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ES2237318B1
ES2237318B1 ES200302701A ES200302701A ES2237318B1 ES 2237318 B1 ES2237318 B1 ES 2237318B1 ES 200302701 A ES200302701 A ES 200302701A ES 200302701 A ES200302701 A ES 200302701A ES 2237318 B1 ES2237318 B1 ES 2237318B1
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aluminum
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ES2237318A1 (en
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Luis Carlos Espinosa Monteagudo
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Servalesa S L
SERVALESA SL
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Servalesa S L
SERVALESA SL
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Abstract

Procedimiento para la obtención de un producto a base de aluminio orgánico para la autodefensa de las plantas contra patógenos para la agricultura tradicional y ecológica que comprende un complejo estable de pectinato de aluminio, poligalacturonato de aluminio, galacturonato de aluminio y/o gluconato de aluminio, con un complejo formado en una matriz acuosa con una concentración de microelementos de cobre, manganeso y cinc, fitohormonas naturales, proteínas e hidratos de carbono de extracto de algas, introduciendo en tanque agitado, agua a temperatura a 40ºC, el 50% de pectina alimentaria y el 3% de pectinasa alimentaria con agitación de 6 horas, con un barrido posterior de aire por inyección de dióxido de carbono y 1% de reductasa, adicionando entre el 2 y el 25% de sulfato de aluminio, sintetizando la matriz que en reposo separa la fase sólida de la fase líquida sobrenadante de color pardo amarillo en un tiempo de 6 a 8 horas, cuya fase líquida trasvasada es el producto fertilizante.Procedure for obtaining a product based on organic aluminum for the self-defense of plants against pathogens for traditional and organic agriculture comprising a stable complex of aluminum pectinate, aluminum polygalacturonate, aluminum galacturonate and / or aluminum gluconate, with a complex formed in an aqueous matrix with a concentration of microelements of copper, manganese and zinc, natural phytohormones, proteins and carbohydrates of seaweed extract, introducing in a stirred tank, water at temperature at 40 ° C, 50% food pectin and 3% of food pectinase with stirring for 6 hours, with a subsequent air sweep by injection of carbon dioxide and 1% reductase, adding between 2 and 25% aluminum sulfate, synthesizing the matrix at rest separates the solid phase from the yellow brown supernatant liquid phase in a time of 6 to 8 hours, whose liquid phase is the product transferred fertilizer.

Description

Procedimiento para la obtención de un producto a base de aluminio orgánico para la autodefensa de las plantas contra patógenos para la agricultura tradicional ecológica.Procedure for obtaining a product to Organic aluminum base for plant self defense Pathogens for traditional organic farming.

El objeto de la presente invención trata sobre un producto obtenido con el correspondiente procedimiento a base de aluminio orgánico para la autodefensa de las plantas contra patógenos tanto para la agricultura tradicional como para la agricultura ecológica, cuya distribución podrá realizarse por pulverización y/o fertirrigación, de forma que dicha aportación signifique una dosis de un complejo estable de aluminio, consistente en pectinato de aluminio, poligalacturonato de aluminio, galacturonato de aluminio y/o gluconato de aluminio, de forma tal que dicho complejo permite combatir enfermedades en los cultivos causadas por hongos vasculares endógenos que germinan en el interior de los vasos y en las raíces, como por ejemplo, fitóftora, gomosis, verticilosis, yesca, eutipiosis y otros no especificados.The object of the present invention is about a product obtained with the corresponding procedure based on organic aluminum for plants self defense pathogens for both traditional agriculture and for organic farming, whose distribution may be carried out by spraying and / or fertirrigation, so that said contribution mean a dose of a stable aluminum complex, consisting of aluminum pectinate, polygalacturonate of aluminum, aluminum galacturonate and / or aluminum gluconate, of in such a way that said complex allows to fight diseases in the cultures caused by endogenous vascular fungi that germinate in the inside the vessels and at the roots, such as phytophthora, gomosis, verticilosis, tinder, eutipiosis and others not specified.

La técnica actual contempla la existencia de diversos productos fertilizantes para productos agrícolas, pero todos los medios existentes, tanto en su composición como en su aplicación son de diferentes características que el producto obtenido con el procedimiento que nos ocupa, en el que se ha tenido un especial cuidado en su elaboración, procurando obtener efectos altamente biológicos, eliminando cualquier efecto nocivo por eliminación espontánea de cualquier asomo de toxicidad.The current technique contemplates the existence of various fertilizer products for agricultural products, but all existing media, both in its composition and in its Application are of different characteristics than the product obtained with the procedure at hand, in which it has been a special care in its elaboration, trying to obtain effects highly biological, eliminating any harmful effects by spontaneous elimination of any hint of toxicity.

El producto fertilizante obtenido a través del procedimiento objeto del presente registro, consiste en un complejo estable de aluminio, consistente en pectinato de aluminio, poligalacturonato de aluminio, galacturonato de aluminio y/o gluconato de aluminio, dicho complejo estable estará formado en una matriz acuosa con una concentración variable de microelementos (cobre, manganeso y cinc), fitohormonas naturales, proteínas e hidratos de carbono provenientes de extracto de algas.The fertilizer product obtained through procedure object of the present registry, consists of a complex stable aluminum, consisting of aluminum pectinate, aluminum polygalacturonate, aluminum galacturonate and / or aluminum gluconate, said stable complex will be formed in a aqueous matrix with a variable concentration of microelements (copper, manganese and zinc), natural phytohormones, proteins and Carbohydrates from seaweed extract.

El proceso de fabricación del producto fertilizante de acuerdo con el procedimiento, será el siguiente:The product manufacturing process fertilizer according to the procedure, it will be the next:

1. - Síntesis del gluconato de aluminio1. - Synthesis of aluminum gluconate

La síntesis de gluconato de aluminio con los distintos componentes de aluminio, que son los componentes fundamentales del producto fertilizante a elaborar para agricultura tradicional y para agricultura ecológica, pasa por las siguientes etapas:The synthesis of aluminum gluconate with the different aluminum components, which are the components fundamentals of the fertilizer product to elaborate for agriculture Traditional and for organic farming, go through the following stages:

a) Selección y aprovisionamiento de las materias primas como pectina alimentaria proveniente de frutas y sulfato de aluminio tetradécahidrato.a) Selection and supply of materials premiums such as food pectin from fruits and sulfate Tetradecahydrate aluminum

b) En tanque agitado se introducen una cantidad M en Kg, de agua atemperada a 40ºC, el 50% de pectina alimentaria y 3% de pectinasa alimentaria, manteniéndose a continuación en agitación constante durante 6 horas para despolimerizar la pectina hasta obtener ácido galacturónico.b) A quantity M is introduced into a stirred tank in Kg, of water tempered at 40ºC, 50% of food pectin and 3% food pectinase, then kept in constant stirring for 6 hours to depolymerize the pectin until obtaining galacturonic acid.

c) Seguidamente se provoca un barrido del aire en el tanque por inyección de dióxido de carbono y se agrega 1% de reductasa para obtener ácido glucónico por reducción del ácido galacturónico, manteniendo la agitación 6 horas.c) An air sweep is then caused in the tank by injection of carbon dioxide and 1% of reductase to obtain gluconic acid by acid reduction galacturonic, keeping stirring 6 hours.

d) Por último se adiciona al tanque, entre 2 y el 25% de sulfato de aluminio tetradecahidrato y se continua la agitación durante 3 horas, tras lo cual se habrá obtenido una mezcla homogénea de complejos estables de aluminio denominados generalmente gluconato de aluminio y que son la composición fundamental del producto fertilizante para agricultura tradicional y para agricultura ecológica.d) Finally it is added to the tank, between 2 and 25% aluminum sulfate tetradecahydrate and the stirring for 3 hours, after which a homogeneous mixture of stable aluminum complexes called usually aluminum gluconate and that are the composition fundamental of the fertilizer product for traditional agriculture and for organic farming.

2. - Adición a la matriz de microelementos, fitohormonas, proteínas e hidratos de carbono2. - Addition to the matrix of microelements, phytohormones, proteins and carbohydrates

Para la adición de microelementos, tras la síntesis del gluconato de aluminio, en el mismo tanque agitado, se puede o no incorporar sulfato de cobre pentahidrato, sulfato de manganeso anhidro y sulfato de cinc heptahirato, en cantidad estequiométricamente calculada para que resulte una concentración garantizada de cobre, manganeso y cinc, agitando durante 2 horas constantemente tras la incorporación de todas estas sales.For the addition of microelements, after synthesis of aluminum gluconate, in the same agitated tank, is may or may not incorporate copper sulfate pentahydrate, sulfate anhydrous manganese and zinc sulfate heptahirate, in quantity stoichiometrically calculated to result in a concentration Guaranteed copper, manganese and zinc, stirring for 2 hours constantly after the incorporation of all these salts.

Tras la adición de microelementos, en el mismo tanque agitado, se puede o no, incorporar extracto de algas para que resulte una concentración determinada de fitohormonas, proteínas e hidratos de carbono.After the addition of microelements, in it stirred tank, may or may not, incorporate seaweed extract to that results in a certain concentration of phytohormones, proteins and carbohydrates.

Tras la adición de microelementos, fitohormonas, proteínas e hidratos de carbono, se obtiene la matriz que contiene aluminio orgánico para agricultura ecológica, mientras que la versión apropiada para obtener el producto fertilizante para agricultura tradicional, consiste en esa misma matriz a la que se incorpora una concentración variable de urea para conseguir una concentración garantizada de nitrógeno, para obtener la composición adecuada.After the addition of microelements, phytohormones, proteins and carbohydrates, the matrix containing organic aluminum for organic farming, while the appropriate version to obtain the fertilizer product for traditional agriculture, consists of that same matrix to which incorporates a variable concentration of urea to achieve a guaranteed nitrogen concentration, to obtain the composition adequate.

3. - Decantación y estabilización del producto3. - Decantation and stabilization of the product

La matriz sintetizada del aluminio orgánico en los dos casos contemplados, se mantiene en reposo hasta que se separe una fase sólida y una fase líquida de color pardo amarillo en la superficie sobrenadante, lo que suele durar de 6 a 8 horas, una vez obtenido este proceso, la fase sólida se desprecia, mientras que la fase líquida pardo amarilla, se trasvasa a otro tanque y se mantiene otro periodo es 6 a 8 horas, por si nuevamente se produjera más precipitación. El líquido pardo amarillo estable, con pH entre 2.6 y 3.4 unidades, es el producto fertilizante para agricultura tradicional y el líquido pardo amarillo estable, con pH entre 3.0 y 4.5 unidades, es el producto fertilizante para agricultura ecológica.The synthetic matrix of organic aluminum in the two cases contemplated, remain at rest until separate a solid phase and a yellow brown liquid phase on the supernatant surface, which usually lasts 6 to 8 hours, Once this process is obtained, the solid phase is neglected, while that the yellow brown liquid phase is transferred to another tank and maintains another period is 6 to 8 hours, in case again produce more precipitation. The stable yellow brown liquid, with pH between 2.6 and 3.4 units, it is the fertilizer product for Traditional agriculture and stable yellow brown liquid, with pH Between 3.0 and 4.5 units, it is the fertilizer product for ecological agriculture.

4. - El aluminio orgánico obtenido para agricultura tradicional y para agricultura biológica en fase líquida estable se envasará en forma independiente en garrafas de polietileno de 1,5 y 20 litros, para ser distribuidos y aplicado en el sector agrícola tradicional o ecológica.4. - The organic aluminum obtained for traditional agriculture and for organic farming in phase Stable liquid will be packaged independently in carafes of 1.5 and 20 liter polyethylene, to be distributed and applied in the traditional or ecological agricultural sector.

El aluminio orgánico en todos los casos, se aplicará por fertirrigación o por pulverización a las dosis adecuadas según el tipo de cultivo y de acuerdo con los periodos vegetativos.Organic aluminum in all cases, is apply by fertirrigation or spray at doses suitable according to the type of crop and according to the periods Vegetative

Una vez descritas ampliamente todas y cada una de las partes que constituyen el procedimiento para la obtención de aluminio orgánico para agricultura tradicional y para agricultura ecológica a que nos venimos refiriendo, solamente nos resta consignar la posibilidad de que los diferentes productos utilizados en su obtención, podrán variar en proporciones y volúmenes, pudiendo igualmente introducirse en su constitución, aquellas variaciones técnicas que la práctica aconseje, siempre y cuando las alteraciones realizadas, no sean capaces de alterar los puntos esenciales de que es objeto el presente registro de Patente de Invención.Once fully described each and every one of the parties that constitute the procedure for obtaining organic aluminum for traditional agriculture and for agriculture ecological that we are referring to, we only have to record the possibility that the different products used in their obtaining, they may vary in proportions and volumes, being able also to be introduced in its constitution, those technical variations that the practice advises, as long as the alterations made, are not able to alter the points Essentials of the present Patent Registration of Invention.

Claims (4)

1. Procedimiento para la obtención de un producto a base de aluminio orgánico para la autodefensa de las plantas contra patógenos para la agricultura tradicional y ecológica, caracterizado por la formación en una matriz acuosa con una concentración variable de microelementos de cobre, manganeso y cinc, con fitohormonas naturales, proteínas e hidratos de carbono provenientes de extracto de algas, en cuya matriz acuosa, previamente se ha constituido un complejo estable de aluminio, consistente en pectinato de aluminio, poligalactúronato de aluminio, galacturonato de aluminio y/o gluconato de aluminio, para obtener el producto fertilizante tradicional y ecológico.1. Procedure for obtaining a product based on organic aluminum for the self-defense of plants against pathogens for traditional and organic agriculture, characterized by the formation in an aqueous matrix with a variable concentration of microelements of copper, manganese and zinc, with natural phytohormones, proteins and carbohydrates from algae extract, in whose aqueous matrix, a stable aluminum complex has previously been constituted, consisting of aluminum pectinate, aluminum polygalactúronate, aluminum galacturonate and / or aluminum gluconate, to obtain the traditional and ecological fertilizer product. 2. Procedimiento para la obtención de un producto a base de aluminio orgánico para la autodefensa de las plantas contra patógenos para la agricultura tradicional y ecológica según la anterior reivindicación, caracterizado porque para la obtención de la síntesis del gluconato de aluminio con sus diferentes componentes de aluminio, se procede a una selección y aprovisionamiento de las materias primas como pectina alimentaria proveniente de frutas y sulfato de aluminio tetradecahidrato, introduciéndose en tanque agitado una cantidad M en Kg, de agua atemperada a 40ºC, el 50% de pectina alimentaria y el 3% de pectinasa alimentaria, manteniéndose a continuación en agitación constante durante 6 horas para despolimerizar la pectina, hasta obtener ácido galacturónico, provocándose seguidamente un barrido del aire en el tanque por inyección de dióxido de carbono y se agrega 1% de reductasa para obtener ácido glucónico por reducción del ácido galacturónico, manteniendo la agitación 6 horas, adicionándose por último al tanque, entre 2 y el 25% de sulfato de aluminio tetradecahidrato y se continua la agitación durante 3 horas, tras lo cual, se habrá obtenido una mezcla homogénea de complejos estables de aluminio denominados en forma general, gluconato de aluminio y que son la composición fundamental del producto fertilizante para agricultura tradicional y ecológica.2. Procedure for obtaining a product based on organic aluminum for the self-defense of plants against pathogens for traditional and organic agriculture according to the preceding claim, characterized in that for obtaining the synthesis of aluminum gluconate with its different components of aluminum, a selection and supply of raw materials such as food pectin from fruits and aluminum sulfate tetradecahydrate are carried out, introducing in an agitated tank an amount M in Kg, of water tempered at 40 ° C, 50% of food pectin and 3 % of food pectinase, then kept under constant agitation for 6 hours to depolymerize the pectin, until obtaining galacturonic acid, then causing a sweep of the air in the tank by injection of carbon dioxide and 1% reductase is added to obtain gluconic acid by reduction of galacturonic acid, maintaining the stirring 6 hours, finally adding to the tank, between 2 and 25% aluminum sulfate tetradecahydrate and stirring is continued for 3 hours, after which, a homogeneous mixture of stable aluminum complexes generally called, will have been obtained, Aluminum gluconate and which are the fundamental composition of the fertilizer product for traditional and organic farming. 3. Procedimiento para la obtención de un producto a base de aluminio orgánico para la autodefensa de las plantas contra patógenos para la agricultura tradicional y ecológica según las anteriores reivindicaciones, caracterizado porque tras la síntesis del gluconato de aluminio y para la adición de microelementos en el mismo tanque agitado, se incorpora sulfato de cobre pentahidrato, sulfato de manganeso anhidro y sulfato de cinc heptahidrato, en cantidad estequiométricamente calculada para que resulte una concentración garantizada de cobre, manganeso y cinc, agitando durante 2 horas constantemente tras la incorporación de todas estas sales y tras la adición de microelementos, en el mismo tanque agitado, se incorpora extracto de algas para que resulte una concentración determinada de fitohormonas, proteínas e hidratos de carbono, obteniéndose la matriz que contiene el producto fertilizante para agricultura ecológica, y para obtener el producto fertilizante para agricultura tradicional en esa misma matriz, se incorpora una concentración variable de urea para conseguir una concentración garantizada de nitrógeno.3. Procedure for obtaining a product based on organic aluminum for the self-defense of plants against pathogens for traditional and organic agriculture according to the preceding claims, characterized in that after the synthesis of aluminum gluconate and for the addition of microelements in the same stirred tank, copper sulphate pentahydrate, anhydrous manganese sulfate and zinc sulfate heptahydrate are incorporated, in stoichiometrically calculated quantity so that a guaranteed concentration of copper, manganese and zinc results, stirring constantly for 2 hours after the incorporation of all these salts and after the addition of microelements, in the same agitated tank, seaweed extract is incorporated to result in a certain concentration of phytohormones, proteins and carbohydrates, obtaining the matrix containing the fertilizer product for organic farming, and to obtain the product fertilizer for agriculture Traditional in that same matrix, a variable concentration of urea is incorporated to achieve a guaranteed concentration of nitrogen. 4. Procedimiento para la obtención de un producto a base de aluminio orgánico para la autodefensa de las plantas contra patógenos para la agricultura tradicional y ecológica según las anteriores reivindicaciones, caracterizado porque la matriz sintetizada del producto fertilizante contemplada se mantiene en reposo hasta que se separa una fase sólida y una fase líquida de color pardo amarillo en la superficie sobrenadante, en un tiempo entre 6 y 8 horas, y una vez obtenido este proceso, la fase sólida se desprecia, mientras que la fase líquida pardo amarilla, se trasvasa a otro tanque y se mantiene durante otro periodo de 6 a 8 horas, por si nuevamente se produjera más precipitación, de forma que, el líquido pardo amarillo estable con pH entre 2.6 y 3.4 unidades, es el producto fertilizante para agricultura tradicional y el líquido pardo amarillo estable, con pH entre 3.0 y 4.5 unidades es el producto fertilizante para agricultura ecológica.4. Procedure for obtaining a product based on organic aluminum for the self-defense of plants against pathogens for traditional and organic agriculture according to the preceding claims, characterized in that the synthesized matrix of the fertilizer product contemplated is kept at rest until it separates a solid phase and a yellow-brown liquid phase on the supernatant surface, in a time between 6 and 8 hours, and once this process is obtained, the solid phase is neglected, while the yellow brown liquid phase is transferred to another tank and is maintained for another period of 6 to 8 hours, in case there is more precipitation again, so that the stable yellow brown liquid with a pH between 2.6 and 3.4 units, is the fertilizer product for traditional agriculture and the yellow brown liquid stable, with pH between 3.0 and 4.5 units is the fertilizer product for organic farming.
ES200302701A 2003-11-19 2003-11-19 PROCEDURE FOR OBTAINING AN ORGANIC ALUMINUM-BASED PRODUCT FOR THE SELF-DEFENSE OF PLANTS AGAINST PATHOGENS FOR ECOLOGICAL TRADITIONAL AGRICULTURE. Expired - Fee Related ES2237318B1 (en)

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ES200302701A ES2237318B1 (en) 2003-11-19 2003-11-19 PROCEDURE FOR OBTAINING AN ORGANIC ALUMINUM-BASED PRODUCT FOR THE SELF-DEFENSE OF PLANTS AGAINST PATHOGENS FOR ECOLOGICAL TRADITIONAL AGRICULTURE.

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2576749B1 (en) * 1985-02-05 1987-04-30 Goemar Lab Sa PRODUCT BASED ON ALGAE AND ALUMINUM CHLORIDE, APPLICATION AS FUNGICIDE OR BACTERICIDE AND METHOD FOR TREATING PLANTS USING SUCH A PRODUCT
IL117458A (en) * 1996-03-13 2000-07-16 Leket Bar Chemicals Ltd Plant fungicidal and bactericidal composition comprising aluminum ions
FR2762189B1 (en) * 1997-04-18 1999-08-13 Goemar Lab Sa COMPOSITION AND METHOD FOR STIMULATING THE NATURAL DEFENSES OF PLANTS, ESPECIALLY CEREALS AND PARTICULARLY WHEAT AND POTATO
ATE298508T1 (en) * 1998-04-16 2005-07-15 Bayer Cropscience Sa NEW USE OF ANTIFUNGAL, ANTIBACTERIAL AND/OR ANTIVIRAL COMPOSITIONS

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
GILB, Latin American Workshops 1. Complementing Resistence to late blight (Phytophora infestans) in the Andes. Febrero 13-16, 2001, Cochabamba, Bolivia. E.N. Fernández-Northcote [en línea] [recuperado el 07.06.2005]. Recuperado de Internet: <URL:http://gilb.cip.cgiar.org/modules.php?name=News&file= article&sid=239> *

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