ES2200698B1 - Catalizador para la polimerizacion de estireno y dienos, procedimiento de preparacion y utilizacion. - Google Patents
Catalizador para la polimerizacion de estireno y dienos, procedimiento de preparacion y utilizacion.Info
- Publication number
- ES2200698B1 ES2200698B1 ES200201622A ES200201622A ES2200698B1 ES 2200698 B1 ES2200698 B1 ES 2200698B1 ES 200201622 A ES200201622 A ES 200201622A ES 200201622 A ES200201622 A ES 200201622A ES 2200698 B1 ES2200698 B1 ES 2200698B1
- Authority
- ES
- Spain
- Prior art keywords
- catalyst
- polymerization
- styrene
- preparation
- use procedure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F12/02—Monomers containing only one unsaturated aliphatic radical
- C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F12/06—Hydrocarbons
- C08F12/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
- C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic System
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
Catalizador para la polimerización de estireno y dienos, procedimiento de preparación y utilización. Se trata de un catalizador para la polimerización de 1,4-dienos, de estireno, y para la copolimerización ambos monómeros. Presenta como características un alto grado de estereoselectividad, actividad catalítica y tolerancia a la presencia de impurezas polares. Este catalizador une las características propias de los catalizadores de polimerización de dienos basados en Ni (elevada estereoselectividad y yactividad catalítica) a su carácter bien definido y su tolerancia a la presencia de sustancias polares. Su preparación es además sencilla, facilitando su uso en la práctica.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ES200201622A ES2200698B1 (es) | 2002-07-10 | 2002-07-10 | Catalizador para la polimerizacion de estireno y dienos, procedimiento de preparacion y utilizacion. |
PCT/ES2003/000349 WO2004007602A2 (es) | 2002-07-10 | 2003-07-10 | Catalizador para polimerización de estireno y dienos, procedimiento de preparación y utilización |
AU2003280964A AU2003280964A1 (en) | 2002-07-10 | 2003-07-10 | Catalyst for polymerisation of styrene and dienes, preparation method thereof and use of same |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ES200201622A ES2200698B1 (es) | 2002-07-10 | 2002-07-10 | Catalizador para la polimerizacion de estireno y dienos, procedimiento de preparacion y utilizacion. |
Publications (2)
Publication Number | Publication Date |
---|---|
ES2200698A1 ES2200698A1 (es) | 2004-03-01 |
ES2200698B1 true ES2200698B1 (es) | 2005-06-01 |
Family
ID=30011363
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES200201622A Expired - Fee Related ES2200698B1 (es) | 2002-07-10 | 2002-07-10 | Catalizador para la polimerizacion de estireno y dienos, procedimiento de preparacion y utilizacion. |
Country Status (3)
Country | Link |
---|---|
AU (1) | AU2003280964A1 (es) |
ES (1) | ES2200698B1 (es) |
WO (1) | WO2004007602A2 (es) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP6269940B2 (ja) * | 2014-02-12 | 2018-01-31 | 国立研究開発法人産業技術総合研究所 | ニッケル錯体化合物、触媒組成物、及び有機ケイ素化合物の製造方法 |
EP3042786B1 (en) | 2014-12-19 | 2017-11-22 | The Goodyear Tire & Rubber Company | Functionalized elastomer |
US10081694B2 (en) | 2014-12-19 | 2018-09-25 | The Goodyear Tire & Rubber Company | Functionalized elastomer containing a boron group |
EP3181592B1 (en) | 2015-12-18 | 2018-08-22 | The Goodyear Tire & Rubber Company | Functionalized elastomer containing a sulfur group |
EP3181603B1 (en) | 2015-12-18 | 2018-07-18 | The Goodyear Tire & Rubber Company | Functionalized elastomer containing boron group |
EP3181593B1 (en) | 2015-12-18 | 2018-07-18 | The Goodyear Tire & Rubber Company | Functionalized elastomer containing a nitrogen group |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2488259B1 (fr) * | 1980-08-08 | 1986-08-08 | Centre Nat Rech Scient | Nouveaux complexes allyliques du nickel, procedes pour les preparer et utilisation de ces complexes comme catalyseurs d'oligomerisation ou de polymerisation |
US5892101A (en) * | 1996-11-18 | 1999-04-06 | E. I. Du Pont De Nemours And Company | Cross-dimerization of olefins |
KR100517852B1 (ko) * | 1997-01-14 | 2005-09-30 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 올레핀 중합반응 |
-
2002
- 2002-07-10 ES ES200201622A patent/ES2200698B1/es not_active Expired - Fee Related
-
2003
- 2003-07-10 AU AU2003280964A patent/AU2003280964A1/en not_active Abandoned
- 2003-07-10 WO PCT/ES2003/000349 patent/WO2004007602A2/es not_active Application Discontinuation
Non-Patent Citations (2)
Title |
---|
J. CAMPORA et al. "Synthesis of pi-Aryloxide Complexes of Nickel and Palladium", Organometallics, 2000, Vol. 19, Nº 16, páginas 2950-2952, en particular, compuesto 4. * |
P.D. HAMPTON et al. "Synthesis of Allylnickel Aryloxides and Arenethiolates: Study of their Dynamic Isomerization and 1,3-Diene Polymerization Activity", Organometallics, 1994, Vol. 13, Nº 5, páginas 2066-2074, en particular, compuestos 1,2. * |
Also Published As
Publication number | Publication date |
---|---|
AU2003280964A1 (en) | 2004-02-02 |
WO2004007602A3 (es) | 2004-03-18 |
AU2003280964A8 (en) | 2004-02-02 |
WO2004007602A2 (es) | 2004-01-22 |
ES2200698A1 (es) | 2004-03-01 |
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Legal Events
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EC2A | Search report published |
Date of ref document: 20040301 Kind code of ref document: A1 |
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