ES2195836T3 - Procedimiento para la preparacion de epoxidos. - Google Patents
Procedimiento para la preparacion de epoxidos.Info
- Publication number
- ES2195836T3 ES2195836T3 ES00202658T ES00202658T ES2195836T3 ES 2195836 T3 ES2195836 T3 ES 2195836T3 ES 00202658 T ES00202658 T ES 00202658T ES 00202658 T ES00202658 T ES 00202658T ES 2195836 T3 ES2195836 T3 ES 2195836T3
- Authority
- ES
- Spain
- Prior art keywords
- preparation
- hydrogen peroxide
- epoxids
- procedure
- olefin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- 150000001336 alkenes Chemical class 0.000 abstract 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- 229910021536 Zeolite Inorganic materials 0.000 abstract 1
- 239000007853 buffer solution Substances 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000010924 continuous production Methods 0.000 abstract 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 1
- 238000006735 epoxidation reaction Methods 0.000 abstract 1
- 150000007522 mineralic acids Chemical class 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 150000007524 organic acids Chemical class 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 239000010457 zeolite Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Epoxy Compounds (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
Un procedimiento continuo para la preparación de óxidos de olefinas por la epoxidación directa de una olefina con peróxido de hidrógeno o compuestos capaces de producir peróxido de hidrógeno bajo las condiciones de reacción, en un medio disolvente, en presencia de un sistema catalítico que consta de una zeolita que contiene átomos de titanio y un sistema amortiguador con un pH controlado que oscila entre valores de 5, 5 a 8, 0, que consta de una base nitrogenada y una sal de la misma con un ácido orgánico o inorgánico.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT1999MI001658A IT1313572B1 (it) | 1999-07-27 | 1999-07-27 | Procedimento per la preparazione di epossidi. |
ITMI99A1658 | 1999-07-27 |
Publications (2)
Publication Number | Publication Date |
---|---|
ES2195836T3 true ES2195836T3 (es) | 2003-12-16 |
ES2195836T5 ES2195836T5 (es) | 2009-03-01 |
Family
ID=11383422
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES00202658T Expired - Lifetime ES2195836T5 (es) | 1999-07-27 | 2000-07-24 | Procedimiento para la preparacion de epoxidos. |
Country Status (7)
Country | Link |
---|---|
US (1) | US6300506B1 (es) |
EP (1) | EP1072600B2 (es) |
JP (1) | JP4841719B2 (es) |
AT (1) | ATE236140T1 (es) |
DE (1) | DE60001881T3 (es) |
ES (1) | ES2195836T5 (es) |
IT (1) | IT1313572B1 (es) |
Families Citing this family (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1318549B1 (it) | 2000-06-01 | 2003-08-27 | Eni Spa | Processo per la produzioni in continuo di acqua ossigenata. |
IT1318680B1 (it) * | 2000-08-11 | 2003-08-27 | Enichem Spa | Processo per la produzione in continuo di ossidi olefinici. |
IT1318681B1 (it) * | 2000-08-11 | 2003-08-27 | Enichem Spa | Procedimento integrato per la preparazione di epossidi. |
US6498259B1 (en) † | 2001-10-19 | 2002-12-24 | Arco Chemical Technology L.P. | Direct epoxidation process using a mixed catalyst system |
EP1403259A1 (en) * | 2002-09-30 | 2004-03-31 | Degussa AG | Process for the epoxidation of olefins |
US7722847B2 (en) | 2002-09-30 | 2010-05-25 | Evonik Degussa Gmbh | Aqueous hydrogen peroxide solutions and method of making same |
US6838572B2 (en) | 2002-09-30 | 2005-01-04 | Degussa Ag | Process for the epoxidation of olefins |
EP1403219A1 (en) † | 2002-09-30 | 2004-03-31 | Degussa AG | Novel aqueous hydrogen peroxide solutions |
FR2846965B1 (fr) * | 2002-11-12 | 2006-10-13 | Procede de fabrication de 1,2-epoxy-3-chloropropane | |
US7169945B2 (en) | 2002-11-26 | 2007-01-30 | Degussa Ag | Process for the epoxidation of olefins |
US20050277542A1 (en) * | 2004-06-14 | 2005-12-15 | Kaminsky Mark P | Catalyst regeneration process |
EP2103604A1 (de) * | 2008-03-17 | 2009-09-23 | Evonik Degussa GmbH | Verfahren zur Herstellung von Epichlorhydrin |
EP2149569A1 (en) * | 2008-08-01 | 2010-02-03 | Hexion Specialty Chemicals Research Belgium S.A. | Process for the manufacture of a 1,2-Epoxide |
EP2149570A1 (en) * | 2008-08-01 | 2010-02-03 | Hexion Specialty Chemicals Research Belgium S.A. | Process for the manufacture of epichlorohydrin using hydrogen peroxide and a manganese komplex |
JP2010083836A (ja) * | 2008-10-02 | 2010-04-15 | Nippon Kayaku Co Ltd | エポキシ化合物の製造方法及び触媒 |
US8524926B2 (en) | 2009-11-19 | 2013-09-03 | Dow Global Technologies Llc | Epoxidation of an olefin |
RU2576620C2 (ru) * | 2010-10-11 | 2016-03-10 | Чайна Петролеум Энд Кемикал Корпорейшн | Способ эпоксидирования олефина |
EP3117831A1 (en) | 2015-07-16 | 2017-01-18 | Nuritas Limited | Peptides for use in promoting transport of glucose into skeletal muscle |
BR112018000660A2 (pt) | 2015-07-16 | 2019-05-14 | Nuritas Limited | peptídeos anti-inflamatórios e seu uso |
EP3118216A1 (en) | 2015-07-16 | 2017-01-18 | Nuritas Limited | Cellular growth and proliferation promoting peptides, and uses thereof |
EP3862014A1 (en) | 2020-02-07 | 2021-08-11 | Nuritas Limited | Treatment of panx1 associated diseases |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2033693T3 (es) * | 1986-01-28 | 1993-04-01 | Eniricerche S.P.A. | Un procedimiento para la exposidacion de compuestos olefinicos. |
JPS62230778A (ja) * | 1986-03-19 | 1987-10-09 | エフ エム シ− コ−ポレ−シヨン | エポキシ化方法 |
DE4425672A1 (de) * | 1994-07-20 | 1996-01-25 | Basf Ag | Oxidationskatalysator, Verfahren zu seiner Herstellung und Oxidationsverfahren unter Verwendung des Oxidationskatalysators |
US5646314A (en) * | 1994-11-16 | 1997-07-08 | Arco Chemical Technology, L.P. | Process for titanium silicalite-catalyzed epoxidation |
DE19528219A1 (de) * | 1995-08-01 | 1997-02-06 | Degussa | Verfahren zur Herstellung von Epoxiden aus Olefinen |
US5591875A (en) † | 1995-08-02 | 1997-01-07 | Chang; Te | Epoxidation Process |
JPH11140068A (ja) * | 1997-11-07 | 1999-05-25 | Sumitomo Chem Co Ltd | プロピレンオキサイドの製造方法 |
IT1298337B1 (it) * | 1998-03-05 | 1999-12-20 | Enichem Spa | Procedimento per la preparazione di epossidi olefinici. |
BE1011851A3 (fr) * | 1998-03-24 | 2000-02-01 | Solvay | Procede de fabrication d'un oxiranne. |
JP2001509821A (ja) * | 1998-03-26 | 2001-07-24 | レプソル キミカ,ソシエダ アノニマ | 溶媒の存在下での過酸化水素によるオレフィン性化合物のエポキシ化方法 |
JPH11309378A (ja) * | 1998-04-28 | 1999-11-09 | Asahi Chem Ind Co Ltd | オレフィンの酸化用触媒 |
US6037484A (en) * | 1998-09-22 | 2000-03-14 | Arco Chemical Technology, L.P. | Epoxidation process |
DE19855858A1 (de) * | 1998-12-03 | 2000-06-08 | Degussa | Verfahren zur enantioselektiven Epoxidierung von C-C-Doppelbindungen |
US6194591B1 (en) * | 2000-04-27 | 2001-02-27 | Arco Chemical Technology, L.P. | Aqueous epoxidation process using modified titanium zeolite |
-
1999
- 1999-07-27 IT IT1999MI001658A patent/IT1313572B1/it active
-
2000
- 2000-07-24 DE DE60001881T patent/DE60001881T3/de not_active Expired - Lifetime
- 2000-07-24 AT AT00202658T patent/ATE236140T1/de not_active IP Right Cessation
- 2000-07-24 EP EP00202658A patent/EP1072600B2/en not_active Expired - Lifetime
- 2000-07-24 ES ES00202658T patent/ES2195836T5/es not_active Expired - Lifetime
- 2000-07-26 JP JP2000225897A patent/JP4841719B2/ja not_active Expired - Lifetime
- 2000-07-26 US US09/626,456 patent/US6300506B1/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
IT1313572B1 (it) | 2002-09-09 |
DE60001881T2 (de) | 2004-02-05 |
EP1072600A1 (en) | 2001-01-31 |
EP1072600B1 (en) | 2003-04-02 |
DE60001881T3 (de) | 2009-04-09 |
US6300506B1 (en) | 2001-10-09 |
DE60001881D1 (de) | 2003-05-08 |
EP1072600B2 (en) | 2008-08-13 |
ATE236140T1 (de) | 2003-04-15 |
JP2001072673A (ja) | 2001-03-21 |
JP4841719B2 (ja) | 2011-12-21 |
ITMI991658A1 (it) | 2001-01-27 |
ES2195836T5 (es) | 2009-03-01 |
ITMI991658A0 (it) | 1999-07-27 |
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