ES2188552T3 - Polimero. - Google Patents

Polimero.

Info

Publication number
ES2188552T3
ES2188552T3 ES00938502T ES00938502T ES2188552T3 ES 2188552 T3 ES2188552 T3 ES 2188552T3 ES 00938502 T ES00938502 T ES 00938502T ES 00938502 T ES00938502 T ES 00938502T ES 2188552 T3 ES2188552 T3 ES 2188552T3
Authority
ES
Spain
Prior art keywords
ethylenically
reaction
resulting product
difunctional
compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES00938502T
Other languages
English (en)
Inventor
Horst Mueller
Hans-Dieter Hille
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
PPG Industries Lacke GmbH
Original Assignee
PPG Industries Lacke GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE1999118137 external-priority patent/DE19918137A1/de
Priority claimed from DE1999118136 external-priority patent/DE19918136A1/de
Priority claimed from DE1999118133 external-priority patent/DE19918133A1/de
Application filed by PPG Industries Lacke GmbH filed Critical PPG Industries Lacke GmbH
Application granted granted Critical
Publication of ES2188552T3 publication Critical patent/ES2188552T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/006—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers provided for in C08G18/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F285/00—Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D151/003—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D17/00—Pigment pastes, e.g. for mixing in paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S525/902—Core-shell

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Graft Or Block Polymers (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Paints Or Removers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

Micropartículas de polímero dispersas en fase acuosa, cuyo exterior está completamente reticulado, que se pueden obtener por un procedimiento de polimerización de varias etapas, en el que a) en una primera etapa se realiza una polimerización en fase acuosa de una mezcla de monómeros a base de: i) 7, 5 a 93 % en peso de al menos un compuesto etilénicamente monofuncional; ii) 0, 3 a 47, 5 % en peso de al menos un compuesto etilénicamente difuncional o multifuncional; en presencia de un polímero elegido entre - un poliéster-poliol con un peso molecular medio numérico de 500 a 10.000, un índice de acidez entre 22 y 224 y un índice de OH entre 60 y 400; - un poliuretano con un peso molecular medio numérico de 500 a 20.000, un índice de acidez entre 25 y 150 y un índice de OH entre 50 y 350; presentando el poliuretano como media estadística al menos un grupo carboxilo libre procedente de un poliéster-poliol por molécula; y/o - un poliacrilato con un peso molecular medio numérico de 2.000 a 100.000, un índice de acidez entre 25 y 300 y un índice de OH entre 50 y 250; b) en una etapa siguiente se realiza una reacción del producto obtenido en la etapa a) con iii) 5 a 85 % en peso de al menos un compuesto etilénicamente monofuncional; ascendiendo la suma de las proporciones en peso de los componentes i) a iii) al 100 % en peso; seguido de una reacción del producto obtenido en la etapa b) con un reticulante.
ES00938502T 1999-04-21 2000-04-20 Polimero. Expired - Lifetime ES2188552T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE1999118137 DE19918137A1 (de) 1999-04-21 1999-04-21 Polymer
DE1999118136 DE19918136A1 (de) 1999-04-21 1999-04-21 Polymer
DE1999118133 DE19918133A1 (de) 1999-04-21 1999-04-21 Polymer

Publications (1)

Publication Number Publication Date
ES2188552T3 true ES2188552T3 (es) 2003-07-01

Family

ID=27219102

Family Applications (1)

Application Number Title Priority Date Filing Date
ES00938502T Expired - Lifetime ES2188552T3 (es) 1999-04-21 2000-04-20 Polimero.

Country Status (17)

Country Link
US (1) US6770702B1 (es)
EP (1) EP1185568B1 (es)
JP (1) JP2002542350A (es)
KR (1) KR20020012181A (es)
CN (1) CN1355817A (es)
AT (1) ATE229043T1 (es)
AU (1) AU5388500A (es)
BR (1) BR0010692A (es)
CA (1) CA2370343A1 (es)
CZ (1) CZ20013782A3 (es)
DE (1) DE50000884D1 (es)
EA (1) EA200101057A1 (es)
ES (1) ES2188552T3 (es)
MX (1) MXPA01010621A (es)
PL (1) PL351110A1 (es)
PT (1) PT1185568E (es)
WO (1) WO2000063265A2 (es)

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DE10238349B4 (de) * 2002-08-16 2005-03-17 Ppg Industries Lacke Gmbh Polyurethan-Mikrogel
AU2003281951A1 (en) * 2002-10-14 2004-05-04 Bollig And Kemper Gmbh And Co. Kg Phosphonic acid-modified microgel dispersion
DE10336770A1 (de) * 2003-08-08 2005-03-10 Bollig & Kemper Gmbh & Co Kg Phosphonsäuremodifizierte Mikrogeldispersion
DE10357160A1 (de) * 2003-12-06 2005-07-07 Bayer Materialscience Ag Verfahren zur Aufarbeitung von Polymerdispersionen in Polyesterpolyolen
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US20080233300A1 (en) * 2007-03-19 2008-09-25 Cinoman Douglas S Thermosetting powders comprising curing agent adducts of polyesters and strong, flexible powder coatings made therefrom
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CN101845118B (zh) * 2010-04-27 2011-08-10 广东天银化工实业有限公司 羟基型含氟水性丙烯酸树脂-聚氨酯杂化体的制备方法
US9193877B2 (en) 2010-07-27 2015-11-24 Axalta Coating Systems Ip Co., Llc Waterborne base coat compositions having a special-effect color
CN101974132B (zh) * 2010-10-22 2012-10-03 南京长江涂料有限公司 基于改性丙烯酸树脂的高丰满度、高固体份常温快干汽车漆
PL2655458T3 (pl) 2010-12-20 2017-08-31 Basf Se Sposób wytwarzania hybrydowych dyspersji poliuretanowo-poliakrylanowych
CN102617824B (zh) * 2011-03-14 2013-08-14 惠州市长润发涂料有限公司 一种水性聚氨酯固化剂和水性聚氨酯分散体
US10100220B2 (en) * 2011-08-22 2018-10-16 BASF Japan, Ltd. Water-based coating composition and method for forming multilayer coating film using said composition
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CN105829462B (zh) * 2013-12-18 2019-10-11 巴斯夫涂料有限公司 包含混合聚合物的水分散体的颜料糊
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JP2018009080A (ja) * 2016-07-13 2018-01-18 三菱ケミカル株式会社 水性被覆材の製造方法、水性被覆材及び塗装物
JP2018009081A (ja) * 2016-07-13 2018-01-18 三菱ケミカル株式会社 水性被覆材の製造方法、水性被覆材及び塗装物
US20200102462A1 (en) * 2017-03-23 2020-04-02 Basf Coatings Gmbh Aqueous effect-pigment pastes containing a polymerizate, and basecoats produced therefrom
JP6953867B2 (ja) * 2017-07-28 2021-10-27 テクノＵｍｇ株式会社 複合ゴム質重合体、グラフト共重合体および熱可塑性樹脂組成物
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JP7433098B2 (ja) * 2020-03-19 2024-02-19 日本ペイント・オートモーティブコーティングス株式会社 水性塗料組成物および複層塗膜形成方法
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Also Published As

Publication number Publication date
WO2000063265A3 (de) 2001-07-19
EP1185568B1 (de) 2002-12-04
US6770702B1 (en) 2004-08-03
KR20020012181A (ko) 2002-02-15
CZ20013782A3 (en) 2002-09-11
EP1185568A2 (de) 2002-03-13
BR0010692A (pt) 2002-12-03
WO2000063265A2 (de) 2000-10-26
PL351110A1 (en) 2003-03-24
DE50000884D1 (en) 2003-01-16
AU5388500A (en) 2000-11-02
MXPA01010621A (es) 2003-09-04
CA2370343A1 (en) 2000-10-26
JP2002542350A (ja) 2002-12-10
PT1185568E (pt) 2003-04-30
CN1355817A (zh) 2002-06-26
ATE229043T1 (de) 2002-12-15
EA200101057A1 (ru) 2002-06-27

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