ES2159224B1 - PROCEDURE FOR THE PREPARATION OF MESOPOROUS TITANOSILICATES TYPE MCM-48, AND ITS USE AS CATALYSTS IN SELECTIVE OXIDATION REACTIONS. - Google Patents

PROCEDURE FOR THE PREPARATION OF MESOPOROUS TITANOSILICATES TYPE MCM-48, AND ITS USE AS CATALYSTS IN SELECTIVE OXIDATION REACTIONS.

Info

Publication number
ES2159224B1
ES2159224B1 ES9900214A ES9900214A ES2159224B1 ES 2159224 B1 ES2159224 B1 ES 2159224B1 ES 9900214 A ES9900214 A ES 9900214A ES 9900214 A ES9900214 A ES 9900214A ES 2159224 B1 ES2159224 B1 ES 2159224B1
Authority
ES
Spain
Prior art keywords
preparation
selective oxidation
catalysts
procedure
oxidation reactions
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
ES9900214A
Other languages
Spanish (es)
Other versions
ES2159224A1 (en
Inventor
Canos Avelino Corma
Marcelo Eduardo Domine
Lopez Maria Lourdes Pena
Garcia Fernando Rey
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Consejo Superior de Investigaciones Cientificas CSIC
Universidad Politecnica de Valencia
Original Assignee
Consejo Superior de Investigaciones Cientificas CSIC
Universidad Politecnica de Valencia
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Consejo Superior de Investigaciones Cientificas CSIC, Universidad Politecnica de Valencia filed Critical Consejo Superior de Investigaciones Cientificas CSIC
Priority to ES9900214A priority Critical patent/ES2159224B1/en
Priority to PCT/ES2000/000030 priority patent/WO2000044670A1/en
Publication of ES2159224A1 publication Critical patent/ES2159224A1/en
Application granted granted Critical
Publication of ES2159224B1 publication Critical patent/ES2159224B1/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D301/00Preparation of oxiranes
    • C07D301/02Synthesis of the oxirane ring
    • C07D301/03Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/19Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic hydroperoxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/03Catalysts comprising molecular sieves not having base-exchange properties
    • B01J29/0308Mesoporous materials not having base exchange properties, e.g. Si-MCM-41
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/89Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/005Silicates, i.e. so-called metallosilicalites or metallozeosilites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/12After treatment, characterised by the effect to be obtained to alter the outside of the crystallites, e.g. selectivation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30After treatment, characterised by the means used
    • B01J2229/32Reaction with silicon compounds, e.g. TEOS, siliconfluoride

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Epoxy Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Procedimiento para la preparación de titanosilicatos mesoporosos tipo MCM-48, y su uso como catalizador en reacciones de oxidación selectiva. La presente invención describe un método para la preparación de titanosilicatos mesoporosos tridireccionales tipo MCM-48, y su empleo en reacciones de oxidación selectiva de compuestos orgánicos o inorgánicos.Process for the preparation of mesoporous titanosilicates type MCM-48, and their use as a catalyst in selective oxidation reactions. The present invention describes a method for the preparation of three-way mesoporous titanosilicates type MCM-48, and their use in reactions of selective oxidation of organic or inorganic compounds.

ES9900214A 1999-01-29 1999-01-29 PROCEDURE FOR THE PREPARATION OF MESOPOROUS TITANOSILICATES TYPE MCM-48, AND ITS USE AS CATALYSTS IN SELECTIVE OXIDATION REACTIONS. Expired - Fee Related ES2159224B1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
ES9900214A ES2159224B1 (en) 1999-01-29 1999-01-29 PROCEDURE FOR THE PREPARATION OF MESOPOROUS TITANOSILICATES TYPE MCM-48, AND ITS USE AS CATALYSTS IN SELECTIVE OXIDATION REACTIONS.
PCT/ES2000/000030 WO2000044670A1 (en) 1999-01-29 2000-01-27 Method for preparing mcm-48-type mesoporous titanosilicates and their use as catalysts in selective oxidation reactions

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES9900214A ES2159224B1 (en) 1999-01-29 1999-01-29 PROCEDURE FOR THE PREPARATION OF MESOPOROUS TITANOSILICATES TYPE MCM-48, AND ITS USE AS CATALYSTS IN SELECTIVE OXIDATION REACTIONS.

Publications (2)

Publication Number Publication Date
ES2159224A1 ES2159224A1 (en) 2001-09-16
ES2159224B1 true ES2159224B1 (en) 2002-04-16

Family

ID=8307172

Family Applications (1)

Application Number Title Priority Date Filing Date
ES9900214A Expired - Fee Related ES2159224B1 (en) 1999-01-29 1999-01-29 PROCEDURE FOR THE PREPARATION OF MESOPOROUS TITANOSILICATES TYPE MCM-48, AND ITS USE AS CATALYSTS IN SELECTIVE OXIDATION REACTIONS.

Country Status (2)

Country Link
ES (1) ES2159224B1 (en)
WO (1) WO2000044670A1 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2179753B1 (en) * 2000-10-11 2005-02-16 Universidad Politecnica De Valencia PROCESS AND CATALYSTS FOR THE ELIMINATION OF SULFUR COMPOUNDS FROM THE GASOLINE FRACTION.
ES2183710B1 (en) * 2001-04-12 2004-01-16 Univ Valencia Politecnica PROCESS AND CATALYSTS FOR THE ELIMINATION OF Sulfur Compounds from the FRACTION DIESEL.
ES2192967B1 (en) * 2001-11-20 2004-09-16 Universidad Politecnica De Valencia. PROCESS AND CATALYSTS FOR OXIDATION OF SULFUR COMPOUNDS FROM GASOLINE, CHEROSENE AND DIESEL FRACTIONS.
CN102807538B (en) * 2011-06-02 2014-08-06 中国石油化工股份有限公司 Method for preparing propylene oxide
CN112221537B (en) * 2020-11-05 2021-07-06 大连理工大学 Using white carbon black and TiCl4Method for preparing high-activity propylene and hydrogen peroxide gas phase epoxidation catalyst by gas-solid phase reaction

Also Published As

Publication number Publication date
WO2000044670A1 (en) 2000-08-03
ES2159224A1 (en) 2001-09-16

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