ES2159224B1 - PROCEDURE FOR THE PREPARATION OF MESOPOROUS TITANOSILICATES TYPE MCM-48, AND ITS USE AS CATALYSTS IN SELECTIVE OXIDATION REACTIONS. - Google Patents
PROCEDURE FOR THE PREPARATION OF MESOPOROUS TITANOSILICATES TYPE MCM-48, AND ITS USE AS CATALYSTS IN SELECTIVE OXIDATION REACTIONS.Info
- Publication number
- ES2159224B1 ES2159224B1 ES9900214A ES9900214A ES2159224B1 ES 2159224 B1 ES2159224 B1 ES 2159224B1 ES 9900214 A ES9900214 A ES 9900214A ES 9900214 A ES9900214 A ES 9900214A ES 2159224 B1 ES2159224 B1 ES 2159224B1
- Authority
- ES
- Spain
- Prior art keywords
- preparation
- selective oxidation
- catalysts
- procedure
- oxidation reactions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/19—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic hydroperoxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
- B01J29/0308—Mesoporous materials not having base exchange properties, e.g. Si-MCM-41
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
- C01B37/005—Silicates, i.e. so-called metallosilicalites or metallozeosilites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/12—After treatment, characterised by the effect to be obtained to alter the outside of the crystallites, e.g. selectivation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/32—Reaction with silicon compounds, e.g. TEOS, siliconfluoride
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Epoxy Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Procedimiento para la preparación de titanosilicatos mesoporosos tipo MCM-48, y su uso como catalizador en reacciones de oxidación selectiva. La presente invención describe un método para la preparación de titanosilicatos mesoporosos tridireccionales tipo MCM-48, y su empleo en reacciones de oxidación selectiva de compuestos orgánicos o inorgánicos.Process for the preparation of mesoporous titanosilicates type MCM-48, and their use as a catalyst in selective oxidation reactions. The present invention describes a method for the preparation of three-way mesoporous titanosilicates type MCM-48, and their use in reactions of selective oxidation of organic or inorganic compounds.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ES9900214A ES2159224B1 (en) | 1999-01-29 | 1999-01-29 | PROCEDURE FOR THE PREPARATION OF MESOPOROUS TITANOSILICATES TYPE MCM-48, AND ITS USE AS CATALYSTS IN SELECTIVE OXIDATION REACTIONS. |
PCT/ES2000/000030 WO2000044670A1 (en) | 1999-01-29 | 2000-01-27 | Method for preparing mcm-48-type mesoporous titanosilicates and their use as catalysts in selective oxidation reactions |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ES9900214A ES2159224B1 (en) | 1999-01-29 | 1999-01-29 | PROCEDURE FOR THE PREPARATION OF MESOPOROUS TITANOSILICATES TYPE MCM-48, AND ITS USE AS CATALYSTS IN SELECTIVE OXIDATION REACTIONS. |
Publications (2)
Publication Number | Publication Date |
---|---|
ES2159224A1 ES2159224A1 (en) | 2001-09-16 |
ES2159224B1 true ES2159224B1 (en) | 2002-04-16 |
Family
ID=8307172
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES9900214A Expired - Fee Related ES2159224B1 (en) | 1999-01-29 | 1999-01-29 | PROCEDURE FOR THE PREPARATION OF MESOPOROUS TITANOSILICATES TYPE MCM-48, AND ITS USE AS CATALYSTS IN SELECTIVE OXIDATION REACTIONS. |
Country Status (2)
Country | Link |
---|---|
ES (1) | ES2159224B1 (en) |
WO (1) | WO2000044670A1 (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2179753B1 (en) * | 2000-10-11 | 2005-02-16 | Universidad Politecnica De Valencia | PROCESS AND CATALYSTS FOR THE ELIMINATION OF SULFUR COMPOUNDS FROM THE GASOLINE FRACTION. |
ES2183710B1 (en) * | 2001-04-12 | 2004-01-16 | Univ Valencia Politecnica | PROCESS AND CATALYSTS FOR THE ELIMINATION OF Sulfur Compounds from the FRACTION DIESEL. |
ES2192967B1 (en) * | 2001-11-20 | 2004-09-16 | Universidad Politecnica De Valencia. | PROCESS AND CATALYSTS FOR OXIDATION OF SULFUR COMPOUNDS FROM GASOLINE, CHEROSENE AND DIESEL FRACTIONS. |
CN102807538B (en) * | 2011-06-02 | 2014-08-06 | 中国石油化工股份有限公司 | Method for preparing propylene oxide |
CN112221537B (en) * | 2020-11-05 | 2021-07-06 | 大连理工大学 | Using white carbon black and TiCl4Method for preparing high-activity propylene and hydrogen peroxide gas phase epoxidation catalyst by gas-solid phase reaction |
-
1999
- 1999-01-29 ES ES9900214A patent/ES2159224B1/en not_active Expired - Fee Related
-
2000
- 2000-01-27 WO PCT/ES2000/000030 patent/WO2000044670A1/en active Application Filing
Also Published As
Publication number | Publication date |
---|---|
WO2000044670A1 (en) | 2000-08-03 |
ES2159224A1 (en) | 2001-09-16 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EC2A | Search report published |
Date of ref document: 20160120 Kind code of ref document: A1 Effective date: 20160120 |
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FD1A | Patent lapsed |
Effective date: 20050131 |