ES2153995T3 - Procedimiento para la preparacion de polimeros olefinicos empleando un catalizador de metaloceno. - Google Patents
Procedimiento para la preparacion de polimeros olefinicos empleando un catalizador de metaloceno.Info
- Publication number
- ES2153995T3 ES2153995T3 ES96941214T ES96941214T ES2153995T3 ES 2153995 T3 ES2153995 T3 ES 2153995T3 ES 96941214 T ES96941214 T ES 96941214T ES 96941214 T ES96941214 T ES 96941214T ES 2153995 T3 ES2153995 T3 ES 2153995T3
- Authority
- ES
- Spain
- Prior art keywords
- metallocene catalyst
- procedure
- preparation
- group
- preparing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
UN PROCESO MEJORADO PARA PREPARAR UN POLIMERO OLEFINICO DEL TIPO EN EL QUE SE POLIMERIZA UN MONOMERO OLEFINICO SOLO O CON UN COMONOMERO EN UN SOLVENTE HIDROCARBURO AROMATICO UTILIZANDO UN CATALIZADOR METALOCENO DE FORMULA (I) EN PRESENCIA DE UN COCATALIZADOR; DONDE LA MEJORA INCLUYE: PREPARAR EL POLIMERO OLEFINICO EN UN SOLVENTE HIDROCARBURO ALIFATICO UTILIZANDO UN CATALIZADO METALOCENICO MODIFICADO QUE SE OBTIENE INTRODUCIENDO AL MENOS UN SUSTITUYENTE ALQUILO C 5-20 EN EL LIGANDO PI , EL PUENTE ALQUILENO O EL PUENTE SILICONA DEL CATALIZADOR METALOCENICO DE FORMULA (I): L 1 L 2 MX 2 DONDE M ES TI, ZR O HF; X ES UN HALOGENO, O UN GRUPO ALQUILO C 1-3; Y L 1 Y L 2 SON CADA UNO UN LIGANDO PI SELECCIO NADO DEL GRUPO CONSISTENTE EN CICLOPENTADIENILO, INDENILO, FLUORENILO Y SUS DERIVADOS, Y ESTAN OPCIONALMENTE LIGADOS ENTRE SI POR UN PUENTE ALQUILENO C 1-4 OPCIONALMENTE SUSTITUIDO CON UN GRUPO HIDROCARBILO C 1-3 O POR UN PUENTE DE SILICONA OPCIONALMENTE SUSTITUIDO CON UN GRUPO HIDROCARBILO C 1-3 .
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR19950044344 | 1995-11-28 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2153995T3 true ES2153995T3 (es) | 2001-03-16 |
Family
ID=19436128
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES96941214T Expired - Lifetime ES2153995T3 (es) | 1995-11-28 | 1996-11-28 | Procedimiento para la preparacion de polimeros olefinicos empleando un catalizador de metaloceno. |
Country Status (8)
Country | Link |
---|---|
US (1) | US6255417B1 (es) |
EP (1) | EP0863920B1 (es) |
JP (1) | JPH11504674A (es) |
CN (1) | CN1097595C (es) |
AT (1) | ATE199093T1 (es) |
DE (1) | DE69611763T2 (es) |
ES (1) | ES2153995T3 (es) |
WO (1) | WO1997019960A1 (es) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7119153B2 (en) * | 2004-01-21 | 2006-10-10 | Jensen Michael D | Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength |
KR100999592B1 (ko) * | 2007-02-15 | 2010-12-08 | 주식회사 엘지화학 | 새로운 시클로펜타디에닐 리간드를 갖는 4족 전이금속화합물, 이의 제조방법 및 이를 이용한 올레핀계 중합체의제조방법 |
US8119553B2 (en) * | 2007-09-28 | 2012-02-21 | Chevron Phillips Chemical Company Lp | Polymerization catalysts for producing polymers with low melt elasticity |
US7799721B2 (en) * | 2007-09-28 | 2010-09-21 | Chevron Phillips Chemical Company Lp | Polymerization catalysts for producing polymers with high comonomer incorporation |
KR101084677B1 (ko) * | 2008-05-14 | 2011-11-22 | 주식회사 엘지화학 | 올레핀 중합체의 제조방법 |
SG176790A1 (en) * | 2009-06-16 | 2012-01-30 | Chevron Phillips Chemical Co | Oligomerization of alpha olefins using metallocene-ssa catalyst systems and use of the resultant polyalphaolefins to prepare lubricant blends |
WO2011044150A1 (en) * | 2009-10-06 | 2011-04-14 | Chevron Phillips Chemical Company Lp | Oligomerization of olefin waxes using metallocene-based catalyst systems |
DE102010000549A1 (de) * | 2010-02-25 | 2011-08-25 | Océ Printing Systems GmbH, 85586 | Vorrichtung und Verfahren zur Entwicklung von auf einem Zwischenbildträger erzeugten Potentialbilder bei einer elektrografischen Druck- oder Kopiereinrichtung |
US9732300B2 (en) | 2015-07-23 | 2017-08-15 | Chevron Phillipa Chemical Company LP | Liquid propylene oligomers and methods of making same |
JP6886858B2 (ja) * | 2017-05-09 | 2021-06-16 | Eneos株式会社 | オリゴマーの製造方法 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3726067A1 (de) * | 1987-08-06 | 1989-02-16 | Hoechst Ag | Verfahren zur herstellung von 1-olefinpolymeren |
DE4005947A1 (de) * | 1990-02-26 | 1991-08-29 | Basf Ag | Loesliche katalysatorsysteme zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)- bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alk-1-enen |
JP3048653B2 (ja) * | 1991-02-07 | 2000-06-05 | 三菱化学株式会社 | α‐オレフィン重合体の製造 |
US5416228A (en) * | 1991-10-07 | 1995-05-16 | Fina Technology, Inc. | Process and catalyst for producing isotactic polyolefins |
US5308817A (en) * | 1992-05-18 | 1994-05-03 | Fina Technology, Inc. | Metallocene catalyst component with good catalyst efficiency after aging |
JPH05339315A (ja) * | 1992-06-11 | 1993-12-21 | Mitsui Petrochem Ind Ltd | オレフィンの重合方法 |
-
1996
- 1996-11-28 US US09/077,278 patent/US6255417B1/en not_active Expired - Fee Related
- 1996-11-28 WO PCT/KR1996/000218 patent/WO1997019960A1/en active IP Right Grant
- 1996-11-28 EP EP96941214A patent/EP0863920B1/en not_active Expired - Lifetime
- 1996-11-28 CN CN96198640A patent/CN1097595C/zh not_active Expired - Fee Related
- 1996-11-28 AT AT96941214T patent/ATE199093T1/de not_active IP Right Cessation
- 1996-11-28 ES ES96941214T patent/ES2153995T3/es not_active Expired - Lifetime
- 1996-11-28 JP JP9520375A patent/JPH11504674A/ja active Pending
- 1996-11-28 DE DE69611763T patent/DE69611763T2/de not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
EP0863920A1 (en) | 1998-09-16 |
ATE199093T1 (de) | 2001-02-15 |
EP0863920B1 (en) | 2001-02-07 |
US6255417B1 (en) | 2001-07-03 |
DE69611763D1 (de) | 2001-03-15 |
JPH11504674A (ja) | 1999-04-27 |
CN1202910A (zh) | 1998-12-23 |
DE69611763T2 (de) | 2001-06-07 |
WO1997019960A1 (en) | 1997-06-05 |
CN1097595C (zh) | 2003-01-01 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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