ES2153018T3 - METHOD OF POLYMERIZATION OF OLIGOMER COMPOSITIONS OF MACROCICLIC POLYESTER. - Google Patents
METHOD OF POLYMERIZATION OF OLIGOMER COMPOSITIONS OF MACROCICLIC POLYESTER.Info
- Publication number
- ES2153018T3 ES2153018T3 ES95307616T ES95307616T ES2153018T3 ES 2153018 T3 ES2153018 T3 ES 2153018T3 ES 95307616 T ES95307616 T ES 95307616T ES 95307616 T ES95307616 T ES 95307616T ES 2153018 T3 ES2153018 T3 ES 2153018T3
- Authority
- ES
- Spain
- Prior art keywords
- macrociclic
- polyester
- polymerization
- oligomer compositions
- polyesters
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920000728 polyester Polymers 0.000 title abstract 4
- 238000000034 method Methods 0.000 title 1
- 239000000203 mixture Substances 0.000 title 1
- 238000006116 polymerization reaction Methods 0.000 title 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- -1 2,2DIMETHYL-1,3-PROPYLENE Chemical class 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Polyesters Or Polycarbonates (AREA)
Abstract
OLIGOMEROS DE POLIESTER MACROCICLICOS SE CONVIERTEN EN POLIESTERES LINEALES MEDIANTE EL CONTACTO A UNA TEMPERATURA DE ALREDEDOR DE 160-300 C CON UN CATALIZADOR DE TITANIO CICLICO COMO DI-(1-BUTIL)-2,2-DIMETILPROPANO-1,3-DIOXITITANATO, BS TITANATO DE (2,2DIMETIL-1,3-PROPILENO) O 1-(1-BUTOXI)-4-METILO-2,6,7TRIOXA-1-TITANABICICLO[2.2.2]OCTANO. TALES CATALIZADORES TIENEN ALTA ACTIVIDAD Y PRODUCEN POLIESTERES LINEALES O RAMIFICADOS DE PESO MOLECULAR MUY ALTO.MACROCICLIC POLYESTER OLIGOMERS BECOME LINEAR POLYESTERS THROUGH CONTACT AT A TEMPERATURE OF AROUND 160-300 C WITH A CYCLICAL TITANIUM CATALYST AS DI- (1-BUTIL) -2,2-DIMETHYLPROPANE-1,3-DIOXYTITANATE TITANATE OF (2,2DIMETHYL-1,3-PROPYLENE) OR 1- (1-BUTOXI) -4-METHYL-2,6,7TRIOXA-1-TITANABICICLO [2.2.2] OCTANO. SUCH CATALYSTS HAVE HIGH ACTIVITY AND PRODUCE VERY HIGH MOLECULAR LINEAR OR RAMIFIED POLYESTERS.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/371,715 US5527976A (en) | 1995-01-12 | 1995-01-12 | Method for polymerizing macrocyclic poly(alkylene dicarboxylate) oligomers |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2153018T3 true ES2153018T3 (en) | 2001-02-16 |
Family
ID=23465126
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES95307616T Expired - Lifetime ES2153018T3 (en) | 1995-01-12 | 1995-10-26 | METHOD OF POLYMERIZATION OF OLIGOMER COMPOSITIONS OF MACROCICLIC POLYESTER. |
Country Status (5)
Country | Link |
---|---|
US (2) | US5527976A (en) |
EP (1) | EP0725098B1 (en) |
JP (2) | JP3441272B2 (en) |
DE (1) | DE69519624T2 (en) |
ES (1) | ES2153018T3 (en) |
Families Citing this family (44)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5661214A (en) * | 1996-08-05 | 1997-08-26 | General Electric Company | Titanate esters useful as polymerization initiators for macrocylic polyester oligomers |
US6728784B1 (en) * | 1996-08-21 | 2004-04-27 | Netspeak Corporation | Collaborative multimedia architecture for packet-switched data networks |
US6420047B2 (en) | 2000-01-21 | 2002-07-16 | Cyclics Corporation | Macrocyclic polyester oligomers and processes for polymerizing the same |
US6960626B2 (en) * | 2000-01-21 | 2005-11-01 | Cyclics Corporation | Intimate physical mixtures containing macrocyclic polyester oligomer and filler |
US6906147B2 (en) * | 2002-03-20 | 2005-06-14 | Cyclics Corporation | Catalytic systems |
US7151143B2 (en) * | 2000-01-21 | 2006-12-19 | Cyclics Corporation | Blends containing macrocyclic polyester oligomer and high molecular weight polymer |
US7256241B2 (en) * | 2000-01-21 | 2007-08-14 | Cyclics Corporation | Methods for polymerizing macrocyclic polyester oligomers using catalyst promoters |
US20050282952A1 (en) * | 2000-01-21 | 2005-12-22 | Cyclics Corporation | Graphite-polyester composites made from macrocyclic polyester oligomers |
US6369157B1 (en) | 2000-01-21 | 2002-04-09 | Cyclics Corporation | Blend material including macrocyclic polyester oligomers and processes for polymerizing the same |
CN100436508C (en) * | 2000-08-22 | 2008-11-26 | 三井化学株式会社 | Catalysts for polyester production, process for producing polyester, and polyester |
US6525164B2 (en) * | 2000-09-01 | 2003-02-25 | Cyclics Corporation | Methods for converting linear polyesters to macrocyclic oligoester compositions and macrocyclic oligoesters |
US7767781B2 (en) | 2000-09-01 | 2010-08-03 | Cyclics Corporation | Preparation of low-acid polyalkylene terephthalate and preparation of macrocyclic polyester oligomer therefrom |
US7750109B2 (en) | 2000-09-01 | 2010-07-06 | Cyclics Corporation | Use of a residual oligomer recyclate in the production of macrocyclic polyester oligomer |
US6436548B1 (en) | 2000-09-12 | 2002-08-20 | Cyclics Corporation | Species modification in macrocyclic polyester oligomers, and compositions prepared thereby |
MXPA03004433A (en) * | 2000-11-21 | 2005-01-25 | Ici Plc | Esterification catalyst, polyester process and polyester article. |
US6420048B1 (en) | 2001-06-05 | 2002-07-16 | Cyclics Corporation | High molecular weight copolyesters from macrocyclic oligoesters and cyclic esters |
JP2002363301A (en) * | 2001-06-11 | 2002-12-18 | Toyobo Co Ltd | Polyester molding |
US7304123B2 (en) * | 2001-06-27 | 2007-12-04 | Cyclics Corporation | Processes for shaping macrocyclic oligoesters |
DE60226789D1 (en) | 2001-06-27 | 2008-07-03 | Cyclics Corp | Shaping processing of macrocyclic oligoesters |
US6436549B1 (en) | 2001-07-16 | 2002-08-20 | Cyclics Corporation | Block copolymers from macrocyclic oligoesters and dihydroxyl-functionalized polymers |
US6787632B2 (en) | 2001-10-09 | 2004-09-07 | Cyclics Corporation | Organo-titanate catalysts for preparing pure macrocyclic oligoesters |
US6831138B2 (en) | 2002-01-07 | 2004-12-14 | Cyclics Corporation | Polymer-containing organo-metal catalysts |
US6806346B2 (en) * | 2002-07-12 | 2004-10-19 | E. I. Du Pont De Nemours And Company | Copolymerization of cyclic ester oligomers |
GB0226408D0 (en) * | 2002-11-13 | 2002-12-18 | Johnson Matthey Plc | Catalyst and process |
US20040106713A1 (en) * | 2002-12-03 | 2004-06-03 | Avakian Roger W. | Use of additives in compounds containing macrocyclic poly(alkylene dicarboxylate) oligomers |
GB0228267D0 (en) * | 2002-12-04 | 2003-01-08 | Johnson Matthey Plc | Catalyst and process |
WO2004050734A1 (en) * | 2002-12-04 | 2004-06-17 | Johnson Matthey Plc | Organometallic catalyst composition and process for polyurethane manufacture using said catalyst |
US6962968B2 (en) * | 2002-12-20 | 2005-11-08 | Cyclics Corporation | Purification of macrocyclic oligoesters |
CA2510156A1 (en) * | 2002-12-20 | 2004-07-15 | Dow Global Technologies Inc. | Polymerized macrocyclic oligomer nanocomposite compositions |
EP1694771B1 (en) * | 2003-12-19 | 2010-03-10 | Cyclics Corporation | Processes for dispersing an impact modifier in a macrocyclic polyester oligomer |
EP1794223A1 (en) * | 2004-09-30 | 2007-06-13 | Honeywell International Inc. | Thermally conductive composite and uses for microelectronic packaging |
US20060067055A1 (en) * | 2004-09-30 | 2006-03-30 | Heffner Kenneth H | Thermally conductive composite and uses for microelectronic packaging |
US7488772B2 (en) * | 2004-11-09 | 2009-02-10 | E.I. Du Pont De Nemours And Company | Polymerization of macrocyclic polyester oligomers using N-heterocyclic carbene and metal amide or metal alkoxide catalyst |
EP1833875A1 (en) * | 2004-11-09 | 2007-09-19 | E.I. Dupont De Nemours And Company | Polymerization of macrocyclic polyester oligomers using n-heterocyclic carbene catalysts |
WO2007070064A1 (en) * | 2005-12-15 | 2007-06-21 | Kimberly - Clark Worldwide, Inc. | Biodegradable multicomponent fibers |
MX2008012848A (en) | 2006-04-07 | 2008-10-13 | Kimberly Clark Co | Biodegradable nonwoven laminate. |
EP2041346B1 (en) * | 2006-07-14 | 2011-12-21 | Kimberly-Clark Worldwide, Inc. | Biodegradable polyactic acid for use in nonwoven webs |
EP2041341B1 (en) * | 2006-07-14 | 2010-11-03 | Kimberly-Clark Worldwide, Inc. | Biodegradable aliphatic-aromatic copolyester for use in nonwoven webs |
EP2044251B1 (en) | 2006-07-14 | 2019-10-02 | NatureWorks LLC | Biodegradable aliphatic polyester for use in nonwoven webs |
JP5135740B2 (en) * | 2006-09-04 | 2013-02-06 | 三菱化学株式会社 | Polyester and production method thereof, and polyester block copolymer |
US8470222B2 (en) | 2008-06-06 | 2013-06-25 | Kimberly-Clark Worldwide, Inc. | Fibers formed from a blend of a modified aliphatic-aromatic copolyester and thermoplastic starch |
US8841386B2 (en) | 2008-06-10 | 2014-09-23 | Kimberly-Clark Worldwide, Inc. | Fibers formed from aromatic polyester and polyether copolymer |
US8921487B2 (en) | 2009-06-19 | 2014-12-30 | Polyone Corporation | Oxygen scavenging terpolymers |
WO2013177266A1 (en) | 2012-05-25 | 2013-11-28 | Polyone Corporation | Oxygen scavenging copolymers made from cyclic aliphatic monomers |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB991020A (en) * | 1960-11-29 | 1965-05-05 | Martin Marietta Corp | Esterification of iso- and terephthalic acids |
US5039783A (en) * | 1990-11-05 | 1991-08-13 | General Electric Company | Method for preparing and polymerizing macrocyclic poly(alkylene discarboxylate) oligomers |
US5466744A (en) * | 1990-11-05 | 1995-11-14 | General Electric Company | Polymerization of macrocyclic poly(alkylene dicarboxylate) oligomers |
US5191013A (en) * | 1991-05-16 | 1993-03-02 | General Electric Company | Macrocyclic filled compositions convertible to polyester composites |
US5214158A (en) * | 1991-06-03 | 1993-05-25 | General Electric Company | Method for preparation of macrocyclic poly(alkylene dicarboxylate) oligomers |
JPH0621873A (en) * | 1992-07-02 | 1994-01-28 | Fujitsu Ltd | Phase adjustment device in mobile communication system |
US5231161A (en) * | 1992-10-22 | 1993-07-27 | General Electric Company | Method for preparation of macrocyclic poly(alkylene dicarboxylate) oligomers from bis(hydroxyalkyl) dicarboxylates |
US5321117A (en) * | 1992-11-19 | 1994-06-14 | General Electric Company | Macrocyclic polyester oligomer preparation with Lewis acid as catalyst |
US5300590A (en) * | 1992-11-30 | 1994-04-05 | General Electric Company | Macrocyclic polyester compositions convertible to linear polyesters of improved integrity |
US5389719A (en) * | 1994-06-20 | 1995-02-14 | General Electric Company | Method for polymerizing macrocyclic poly(alkylene dicarboxylate) oligomers |
US5387666A (en) * | 1994-06-20 | 1995-02-07 | General Electric Company | Branched polyesters prepared from macrocyclic poly(Alkylene Dicarboxylate) oligomers |
US5386037A (en) * | 1994-06-20 | 1995-01-31 | General Electric Company | Trisstannoxanes useful for polymerizing macrocyclic poly(alkylene dicarboxylate) oligomers |
-
1995
- 1995-01-12 US US08/371,715 patent/US5527976A/en not_active Expired - Lifetime
- 1995-10-26 DE DE69519624T patent/DE69519624T2/en not_active Expired - Lifetime
- 1995-10-26 ES ES95307616T patent/ES2153018T3/en not_active Expired - Lifetime
- 1995-10-26 EP EP95307616A patent/EP0725098B1/en not_active Expired - Lifetime
- 1995-11-09 JP JP29069695A patent/JP3441272B2/en not_active Expired - Fee Related
- 1995-11-30 US US08/565,366 patent/US5591800A/en not_active Expired - Lifetime
-
2003
- 2003-05-13 JP JP2003134837A patent/JP4073822B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
US5591800A (en) | 1997-01-07 |
US5527976A (en) | 1996-06-18 |
JPH08253573A (en) | 1996-10-01 |
JP3441272B2 (en) | 2003-08-25 |
JP2004002417A (en) | 2004-01-08 |
DE69519624D1 (en) | 2001-01-18 |
EP0725098B1 (en) | 2000-12-13 |
DE69519624T2 (en) | 2001-04-12 |
EP0725098A3 (en) | 1996-09-18 |
JP4073822B2 (en) | 2008-04-09 |
EP0725098A2 (en) | 1996-08-07 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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