ES2135628T3 - Composiciones de revestimiento que contienen polimeros microgelificados en dispersion acuosa y epoxi-reticulados. - Google Patents

Composiciones de revestimiento que contienen polimeros microgelificados en dispersion acuosa y epoxi-reticulados.

Info

Publication number
ES2135628T3
ES2135628T3 ES95107855T ES95107855T ES2135628T3 ES 2135628 T3 ES2135628 T3 ES 2135628T3 ES 95107855 T ES95107855 T ES 95107855T ES 95107855 T ES95107855 T ES 95107855T ES 2135628 T3 ES2135628 T3 ES 2135628T3
Authority
ES
Spain
Prior art keywords
weight
epoxy
microgelified
crosslined
polymers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES95107855T
Other languages
English (en)
Inventor
Gary Pierce Craun
Victor Kaminski
David James Telford
Henry John Degraff
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Akzo Nobel Paints LLC
Original Assignee
Glidden Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US08/274,804 external-priority patent/US5576360A/en
Priority claimed from US08/374,885 external-priority patent/US5508325A/en
Priority claimed from US08/407,664 external-priority patent/US5554671A/en
Priority claimed from US08/421,269 external-priority patent/US5576361A/en
Application filed by Glidden Co filed Critical Glidden Co
Application granted granted Critical
Publication of ES2135628T3 publication Critical patent/ES2135628T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • C09D133/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/062Copolymers with monomers not covered by C09D133/06
    • C09D133/064Copolymers with monomers not covered by C09D133/06 containing anhydride, COOH or COOM groups, with M being metal or onium-cation
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D151/08Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/18Spheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00Compositions of epoxy resins; Compositions of derivatives of epoxy resins

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paints Or Removers (AREA)
  • Epoxy Resins (AREA)

Abstract

UNA COMPOSICION COBERTORA PROTECTORA DEL TIPO EN QUE UN AGLOMERANTE POLIMERICO QUE CONTIENE MITADES DE CARBOXILO Y RESINA DE UNION MOLECULAR EPOXI ES DISPERSADO EN UN MEDIO ACUOSO EN DONDE LAS CANTIDADES DE COMPUESTO ORGANICO VOLATIL EN EL MEDIO ACUOSO HAN SIDO REDUCIDAS A UNA CANTIDAD MINIMA O CERO USANDO UN AGLOMERANTE QUE ES UN MICROGEL QUE TIENE UN TAMAÑO DE PARTICULA POR DEBAJO DE 2{MI}M Y UN NUMERO ACIDO ENTRE 30 Y 200 Y QUE CONTIENE ENTRE 60 Y 99 PESO% CARBOXILO FUNCIONAL SUMA COPOLIMERO DISPERSANTE DE MONOMEROS ETILENICAMENTE COPOLIMERIZADOS NO ACUOSOS COMPUESTOS DE AL MENOS 5 PESO% DE MONOMEROS FUNCIONALES DE CARBOXILO BASADOS EN EL PESO DE LOS MONOMEROS COPOLIMERIZADOS Y QUE TIENEN PESO MEDIO MOLECULAR ENTRE 1,000 Y 50,000 Y UN NO. ACIDO ENTRE 30 Y 300 CORREACCIONADO CON ENTRE 1 Y 40% DE UNA RESINA DE UNION MOLECULAR DIEPOXIDA QUE TIENE UN PESO EPOXIDO EQUIVALENTE ALREDEDOR DE 100 Y 500 Y UN NUMERO DE PESO MEDIO MOLECULAR ENTRE 200 Y 1,000. TAMBIEN UN PROCESO PARA FABRICAR LA COMPOSICION COBERTORA EN LA QUE EL DISPERSANTE COPOLIMERO CARBOXILO ES PRE-FORMADO Y DESPUES DISPERSADO DENTRO DEL AGUA CON EL DIEPOXIDO Y MAS ADELANTE CON LA COREACCION DE UNION MOLECULAR ES LLEVADA A CABO PERMITIENDO DE ESE MODO LA EVITACION DE SUPERFICIACTIVOS AÑADIDOS ESPECIALMENTE.
ES95107855T 1994-05-25 1995-05-23 Composiciones de revestimiento que contienen polimeros microgelificados en dispersion acuosa y epoxi-reticulados. Expired - Lifetime ES2135628T3 (es)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US24925194A 1994-05-25 1994-05-25
US08/274,804 US5576360A (en) 1994-07-14 1994-07-14 Low voc, aqueous dispersed, epoxy crosslinked polyester acrylic coatings
US08/374,885 US5508325A (en) 1995-01-19 1995-01-19 Aqueous dispersed, acrylic grafted epoxy microgel protective coatings
US08/407,664 US5554671A (en) 1994-05-25 1995-03-21 Low VOC, aqueous dispersed acrylic epoxy microgels
US08/421,269 US5576361A (en) 1995-04-20 1995-04-20 Zero VOC, aqueous dispersed, polyester modified acrylic-epoxy microgel polymers

Publications (1)

Publication Number Publication Date
ES2135628T3 true ES2135628T3 (es) 1999-11-01

Family

ID=27540272

Family Applications (1)

Application Number Title Priority Date Filing Date
ES95107855T Expired - Lifetime ES2135628T3 (es) 1994-05-25 1995-05-23 Composiciones de revestimiento que contienen polimeros microgelificados en dispersion acuosa y epoxi-reticulados.

Country Status (7)

Country Link
EP (1) EP0684294B1 (es)
CN (1) CN1069674C (es)
AU (1) AU691590B2 (es)
CA (1) CA2150051C (es)
DE (1) DE69511169T2 (es)
ES (1) ES2135628T3 (es)
NZ (1) NZ272202A (es)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1060233A (ja) * 1996-08-22 1998-03-03 Nippon Paint Co Ltd 水性防錆剤、防錆方法及び防錆処理金属材料
ES2205499T3 (es) * 1997-05-01 2004-05-01 Imperial Chemical Industries Plc Procedimiento para la produccion de una composicion de revestimiento.
GB9708825D0 (en) * 1997-05-01 1997-06-25 Ici Plc Process for producing a coating composition
US5942563A (en) * 1997-07-18 1999-08-24 The Glidden Company Aqueous dispersed acrylic-epoxy, branched epoxy protective coatings
US6849682B2 (en) 2002-09-30 2005-02-01 Omnova Solutions Inc. VOC containment coating, methods and articles
AU2002953359A0 (en) * 2002-11-27 2003-01-09 The University Of Melbourne Microgel composition
GB0501854D0 (en) * 2005-01-31 2005-03-09 Ici Plc Improved low VOC coating composition
WO2009018264A2 (en) 2007-07-30 2009-02-05 Basf Corporation Water-based dispersions of highly-branched polymers
US8288453B2 (en) * 2008-06-26 2012-10-16 Ccp Composites Us Process to disperse organic microparticles/nanoparticles into non-aqueous resin medium
JP2013539804A (ja) * 2010-09-30 2013-10-28 ダウ グローバル テクノロジーズ エルエルシー アドバンストエポキシ樹脂組成物
EP2621998A1 (en) * 2010-09-30 2013-08-07 Dow Global Technologies LLC Coating compositions
MY183532A (en) 2013-03-14 2021-02-25 Akzo Nobel Coatings Int Bv Microgels prepared using hybrid crosslinker systems and coating compositions having microgels prepared therefrom
CN104164052B (zh) * 2014-07-18 2018-01-12 广东新秀新材料股份有限公司 改性环氧树脂基体材料和改性环氧树脂基碳纤维复合材料及它们的制备方法
WO2020018690A1 (en) * 2018-07-19 2020-01-23 Dow Global Technologies Llc Weatherable and durable coating compositions
CN113896862A (zh) * 2021-11-29 2022-01-07 国网山东省电力公司电力科学研究院 一种聚合物环氧树脂、制备方法及其应用

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4399241A (en) 1980-03-21 1983-08-16 Scm Corporation Base for a graft polymer, novel graft polymer compositions, solvents and water-reducible coatings incorporating the novel graft polymers, and processes for making them
US4482671A (en) 1980-03-21 1984-11-13 Scm Corporation Base for a graft polymer, novel graft polymer compositions, solvent and water-reducible coatings incorporating the novel graft polymers, and processes for making them
AU563372B2 (en) * 1982-12-16 1987-07-09 Celanese Corporation Crosslinked microgel particles
JPH0672216B2 (ja) 1987-07-24 1994-09-14 大日本インキ化学工業株式会社 水性被覆用樹脂組成物とその製造方法
US5157078A (en) 1990-05-25 1992-10-20 The Glidden Company Glycidyl-epoxy-acrylic copolymers
US5290828A (en) 1993-06-11 1994-03-01 The Glidden Company Aqueous dispersed acrylic grafted epoxy polyester protective coatings

Also Published As

Publication number Publication date
MX9502297A (es) 1998-07-31
EP0684294B1 (en) 1999-08-04
EP0684294A1 (en) 1995-11-29
AU691590B2 (en) 1998-05-21
DE69511169D1 (de) 1999-09-09
AU2031095A (en) 1995-11-30
NZ272202A (en) 1996-07-26
CA2150051C (en) 2007-07-10
DE69511169T2 (de) 1999-11-25
CA2150051A1 (en) 1995-11-26
CN1069674C (zh) 2001-08-15
CN1121522A (zh) 1996-05-01

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