ES2115153T3 - Metodo para la fabricacion de catodos para celulas energeticas. - Google Patents

Metodo para la fabricacion de catodos para celulas energeticas.

Info

Publication number
ES2115153T3
ES2115153T3 ES94203403T ES94203403T ES2115153T3 ES 2115153 T3 ES2115153 T3 ES 2115153T3 ES 94203403 T ES94203403 T ES 94203403T ES 94203403 T ES94203403 T ES 94203403T ES 2115153 T3 ES2115153 T3 ES 2115153T3
Authority
ES
Spain
Prior art keywords
manufacture
catode
itself
catodes
lithium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES94203403T
Other languages
English (en)
Inventor
Ermete Antolini
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Leonardo SpA
Original Assignee
Finmeccanica SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Finmeccanica SpA filed Critical Finmeccanica SpA
Application granted granted Critical
Publication of ES2115153T3 publication Critical patent/ES2115153T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88—Processes of manufacture
    • H01M4/8825—Methods for deposition of the catalytic active composition
    • H01M4/8857—Casting, e.g. tape casting, vacuum slip casting
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/22—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces for producing castings from a slip
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F5/00—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
    • B22F5/006—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product of flat products, e.g. sheets
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8605—Porous electrodes
    • H01M4/8621—Porous electrodes containing only metallic or ceramic material, e.g. made by sintering or sputtering
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88—Processes of manufacture
    • H01M4/8878—Treatment steps after deposition of the catalytic active composition or after shaping of the electrode being free-standing body
    • H01M4/8882—Heat treatment, e.g. drying, baking
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88—Processes of manufacture
    • H01M4/8878—Treatment steps after deposition of the catalytic active composition or after shaping of the electrode being free-standing body
    • H01M4/8882—Heat treatment, e.g. drying, baking
    • H01M4/8885—Sintering or firing
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00853—Uses not provided for elsewhere in C04B2111/00 in electrochemical cells or batteries, e.g. fuel cells
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M2004/8678—Inert electrodes with catalytic activity, e.g. for fuel cells characterised by the polarity
    • H01M2004/8689—Positive electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/14—Fuel cells with fused electrolytes
    • H01M2008/147—Fuel cells with molten carbonates
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0048—Molten electrolytes used at high temperature
    • H01M2300/0051—Carbonates
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Ceramic Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inert Electrodes (AREA)
  • Fuel Cell (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Abstract

UN METODO PARA LA FABRICACION DE CATODOS POR FUSION DE CELULAS DE COMBUSTIBLE CARBONADAS QUE CONTIENEN COBALTITA DE LITIO, INCLUYE UN PASO EN EL QUE UNA MEZCLA QUE CONTIENE COBALTO EN POLVO, CARBONATO DE LITIO, UN ADHESIVO, UN AGENTE ANTIESPUMANTE Y UN DISOLVENTE, SE EXPANDE SOBRE UNA SUPERFICIE PLANA EMPLEANDO UNA TECNICA DE COLADA EN BANDAS, Y UNA FASE DE TRATAMIENTO TERMICO SUBSECUENTE QUE PROVOCA LA FORMACION DE COBALTITA DE LITIO Y LA SINTERIZACION PARCIAL DEL CATODO, PRODUCIENDO UNA POROSIDAD COMPATIBLE CON LA CORRECTA OPERACION DEL CATODO EN SI MISMO EN LAS CELULAS DE COMBUSTIBLE DE CARBONATO FUNDIDO.
ES94203403T 1994-01-04 1994-11-23 Metodo para la fabricacion de catodos para celulas energeticas. Expired - Lifetime ES2115153T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ITMI940004A IT1269173B (it) 1994-01-04 1994-01-04 Metodo per la fabbricazione di catodi per celle a combustibile

Publications (1)

Publication Number Publication Date
ES2115153T3 true ES2115153T3 (es) 1998-06-16

Family

ID=11367446

Family Applications (1)

Application Number Title Priority Date Filing Date
ES94203403T Expired - Lifetime ES2115153T3 (es) 1994-01-04 1994-11-23 Metodo para la fabricacion de catodos para celulas energeticas.

Country Status (6)

Country Link
EP (1) EP0661767B1 (es)
JP (1) JPH07240206A (es)
DE (1) DE69409348T2 (es)
DK (1) DK0661767T3 (es)
ES (1) ES2115153T3 (es)
IT (1) IT1269173B (es)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19603918C2 (de) * 1996-02-03 2000-10-05 Mtu Friedrichshafen Gmbh Verfahren zur Herstellung einer Elektrode für eine Schmelzkarbonat-Brennstoffzelle und deren Verwendung
NL1003238C2 (nl) * 1996-05-30 1997-12-03 Stichting Energie Werkwijze voor het vervaardigen van plaatvormige componenten danwel combinaties van componenten.
US20030170539A1 (en) * 2002-02-05 2003-09-11 Gencell Corporation Aqueous electrode binder and electrodes and fuel cells including same
CN113363511B (zh) * 2021-05-28 2022-12-16 华能国际电力股份有限公司 一种熔融碳酸盐燃料电池阴极材料及制备方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60117566A (ja) * 1983-11-29 1985-06-25 Matsushita Electric Ind Co Ltd 溶融炭酸塩燃料電池
IT1241857B (it) * 1990-06-01 1994-02-01 Ansaldo Spa Procedimento per la fabbricazione di catodi per celle a carbonati fusi
NL9001916A (nl) * 1990-08-30 1992-03-16 Stichting Energie Tape geschikt voor toepassing in brandstofcellen, elektrode geschikt voor toepassing in een brandstofcel, werkwijze voor het sinteren van een dergelijke elektrode, alsmede een brandstofcel voorzien van een dergelijke elektrode.

Also Published As

Publication number Publication date
JPH07240206A (ja) 1995-09-12
DK0661767T3 (da) 1998-10-19
IT1269173B (it) 1997-03-21
EP0661767A1 (en) 1995-07-05
DE69409348T2 (de) 1998-07-23
ITMI940004A0 (it) 1994-01-04
DE69409348D1 (de) 1998-05-07
EP0661767B1 (en) 1998-04-01
ITMI940004A1 (it) 1995-07-04

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