ES2102329B1 - PIPERIDIN TRIANZINIC COMPOUNDS CONTAINING GROUPS OF SILANE AS STABILIZERS FOR ORGANIC MATERIALS. - Google Patents

PIPERIDIN TRIANZINIC COMPOUNDS CONTAINING GROUPS OF SILANE AS STABILIZERS FOR ORGANIC MATERIALS.

Info

Publication number
ES2102329B1
ES2102329B1 ES09502353A ES9502353A ES2102329B1 ES 2102329 B1 ES2102329 B1 ES 2102329B1 ES 09502353 A ES09502353 A ES 09502353A ES 9502353 A ES9502353 A ES 9502353A ES 2102329 B1 ES2102329 B1 ES 2102329B1
Authority
ES
Spain
Prior art keywords
substituted
piperidin
silane
stabilizers
containing groups
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES09502353A
Other languages
Spanish (es)
Other versions
ES2102329A1 (en
Inventor
Valerio Borzatta
Primo Carrozza
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novartis AG
Original Assignee
Ciba Geigy AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Geigy AG filed Critical Ciba Geigy AG
Publication of ES2102329A1 publication Critical patent/ES2102329A1/en
Application granted granted Critical
Publication of ES2102329B1 publication Critical patent/ES2102329B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/38—Polysiloxanes modified by chemical after-treatment
    • C08G77/382—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon
    • C08G77/388—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
    • C08G77/26—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen nitrogen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098—Metal salts of carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/12—Applications used for fibers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Laminated Bodies (AREA)
  • Silicon Polymers (AREA)

Abstract

COMPUESTOS PIPERIDIN TRIAZINICOS CONTENIENDO GRUPOS DE SILANO COMO ESTABILIZADORES PARA MATERIALES ORGANICOS. LA INVENCION, SE REFIERE A COMPUESTOS DE FORMULA (I) EN DONDE M+N ES UN NUMERO DE 1 A 100 Y N VARIA DE CERO A 90% DE LA SUMA DE M+N; X ES -O- O -NH-; R1, ES HIDROGENO, ALQUILO DE C1-C18 ALQUILO DE C2-C4 SUSTITUIDO EN POSICION 2, 3 O 4 POR ALCOXILO DE C1-C8 O POR DI(ALQUILO DE C1-C4)AMINO; CICLOALQUILO DE C5-C12 INSUSTITUIDO O SUSTITUIDO POR 1, 2 O 3 ALQUILOS DE C1-C43; FENILALQUILO DE C7-C9 INSUSTITUIDO O SUSTITUIDO EN EL FENILO POR 1, 2 O 3 ALQUILOS DE C1-C4; O UN GRUPO DE FORMULA (II) EN DONDE R2 ES HIDROGENO, ALQUILO DE C1-C8, O, OH, NO, CH2 CN, ALCOXILO DE C1-C18, CICLOALCOXILO DE C5-C12, FENILALQUILO DE C7-C9 INSUSTITUIDO O SUSTITUIDO EN EL FENILO POR 1, 2 O 3 ALQUILOS DE C1-C4; ACILO DE C1-C8; Y A ES ALQUILO DE C6-C18. ESTOS COMPUESTOS SON UTILES PARA ESTABILIZAR UN MATERIAL ORGANICO FRENTE A LA LUZ, CALOR U OXIDACION.PIPERIDIN TRIAZINIC COMPOUNDS CONTAINING GROUPS OF SILANE AS STABILIZERS FOR ORGANIC MATERIALS. THE INVENTION REFERS TO COMPOUNDS OF FORMULA (I) WHERE M + N IS A NUMBER OF 1 TO 100 AND N VARIATIONS OF ZERO TO 90% OF THE SUM OF M + N; X IS -O- O -NH-; R1, IS HYDROGEN, C1-C18 ALKYL C2-C4 ALKYL SUBSTITUTED IN POSITION 2, 3 OR 4 BY C1-C8 ALCOXYL OR BY DI (C1-C4 ALKYL) AMINO; CYCLOALKYL OF C5-C12 SUBSTITUTED OR REPLACED BY 1, 2 OR 3 C1-C43 ALKYLS; C7-C9 PHENYLALKYL SUBSTITUTED OR SUBSTITUTED IN THE PHENYL BY 1, 2 OR 3 C1-C4 ALKYLS; OR A GROUP OF FORMULA (II) WHERE R2 IS HYDROGEN, C1-C8 ALKYL, O, OH, NO, CH2 CN, C1-C18 ALCOXYL, C5-C12 CYCLLOALCOXYL, INSTITUTED OR SUBSTITUTED IN THE PHENYL FOR 1, 2 OR 3 C1-C4 ALKYLS; C1-C8 ACIL; AND A IS RENT FROM C6-C18. THESE COMPOUNDS ARE USEFUL TO STABILIZE AN ORGANIC MATERIAL AGAINST LIGHT, HEAT OR OXIDATION.

ES09502353A 1994-11-30 1995-11-29 PIPERIDIN TRIANZINIC COMPOUNDS CONTAINING GROUPS OF SILANE AS STABILIZERS FOR ORGANIC MATERIALS. Expired - Lifetime ES2102329B1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ITMI942429A IT1271133B (en) 1994-11-30 1994-11-30 TRIAZINIC PIPERIDINE COMPOUNDS CONTAINING SILANIC GROUPS AS STABILIZERS FOR ORGANIC MATERIALS

Publications (2)

Publication Number Publication Date
ES2102329A1 ES2102329A1 (en) 1997-07-16
ES2102329B1 true ES2102329B1 (en) 1998-04-01

Family

ID=11369940

Family Applications (1)

Application Number Title Priority Date Filing Date
ES09502353A Expired - Lifetime ES2102329B1 (en) 1994-11-30 1995-11-29 PIPERIDIN TRIANZINIC COMPOUNDS CONTAINING GROUPS OF SILANE AS STABILIZERS FOR ORGANIC MATERIALS.

Country Status (11)

Country Link
JP (1) JPH08225650A (en)
KR (1) KR960017676A (en)
BE (1) BE1009749A3 (en)
CA (1) CA2163956A1 (en)
DE (1) DE19544114A1 (en)
ES (1) ES2102329B1 (en)
FR (1) FR2727419B1 (en)
GB (1) GB2295619B (en)
IT (1) IT1271133B (en)
NL (1) NL1001781C2 (en)
TW (1) TW303380B (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE240982T1 (en) 1999-04-27 2003-06-15 Ciba Sc Holding Ag POLYSILANE STABILIZERS WITH STERICALLY HINDERED AMINO GROUPS
NO325797B1 (en) * 2005-10-14 2008-07-21 Nor X Ind As Light preservative based on organic / inorganic hybrid polymer, process for preparation and use of same
FR2921663A1 (en) * 2007-10-02 2009-04-03 Bluestar Silicones France Soc POLYORGANOSILOXANES WITH PIPERIDINE FUNCTION WITHOUT CUTANE CONTACT TOXICITY AND USE OF THE SAME IN COSMETIC COMPOSITIONS
JP5640471B2 (en) * 2010-06-02 2014-12-17 Jsr株式会社 Liquid crystal alignment agent, liquid crystal alignment film, method for forming liquid crystal alignment film, and liquid crystal display element
JP5781511B2 (en) 2011-02-04 2015-09-24 株式会社Adeka Compound having hindered amine skeleton and resin composition
CN114854023A (en) * 2022-05-07 2022-08-05 宿迁联宏新材料有限公司 Light stabilizer for polyolefin resin and preparation method and application thereof

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1248698B (en) * 1990-06-06 1995-01-26 Ciba Geigy Spa PIEPRIDIN TRIAZIN COMPOUNDS CONTAINING SILOXANE GROUPS, SUITABLE FOR USE AS STABILIZERS FOR ORGANIC MATERIALS
DE59205197D1 (en) * 1991-03-05 1996-03-14 Ciba Geigy Ag Silylated 2- (2-hydroxyphenyl) -4,6-diaryl-1,3,5-triazines
FR2714402B1 (en) * 1993-12-27 1996-02-02 Rhone Poulenc Chimie Non-yellowing textile softening process in which a composition comprising a polyorganosiloxane is used.

Also Published As

Publication number Publication date
NL1001781C2 (en) 1997-03-25
NL1001781A1 (en) 1996-05-30
DE19544114A1 (en) 1996-06-05
ES2102329A1 (en) 1997-07-16
ITMI942429A1 (en) 1996-05-30
GB2295619B (en) 1997-02-19
TW303380B (en) 1997-04-21
CA2163956A1 (en) 1996-05-31
ITMI942429A0 (en) 1994-11-30
JPH08225650A (en) 1996-09-03
BE1009749A3 (en) 1997-07-01
FR2727419A1 (en) 1996-05-31
FR2727419B1 (en) 1997-12-12
GB9524075D0 (en) 1996-01-24
GB2295619A (en) 1996-06-05
IT1271133B (en) 1997-05-26
KR960017676A (en) 1996-06-17

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