ES2099891T3 - Masas de moldeo termoplasticas con una elevada resiliencia con entalla. - Google Patents

Masas de moldeo termoplasticas con una elevada resiliencia con entalla.

Info

Publication number
ES2099891T3
ES2099891T3 ES93119951T ES93119951T ES2099891T3 ES 2099891 T3 ES2099891 T3 ES 2099891T3 ES 93119951 T ES93119951 T ES 93119951T ES 93119951 T ES93119951 T ES 93119951T ES 2099891 T3 ES2099891 T3 ES 2099891T3
Authority
ES
Spain
Prior art keywords
weight
polymerisation
acrylic acid
alkyl
monomer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES93119951T
Other languages
English (en)
Inventor
Norbert Dr Niessner
Karl Ruppmich
Norbert Mosbach
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Application granted granted Critical
Publication of ES2099891T3 publication Critical patent/ES2099891T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04Homopolymers or copolymers of esters
    • C08L33/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10Homopolymers or copolymers of methacrylic acid esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02Homopolymers or copolymers of hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04Homopolymers or copolymers of esters
    • C08L33/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/06Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Graft Or Block Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

MASAS DE MOLDEO TERMOPLASTICAS CONTENIENDO A) 10 A 80% EN PESO DE UN POLIMERIZADO OBTENIDO A TRAVES DE POLIMERIZACION DE UN ESTER ALQUILO DE C 1 A 20 DEL ACIDO METACRILICO O ACRILICO O MEZCLAS DEL ESTER B) 10 A 80% EN PESO DE UN COPOLIMERIZADO, OBTENIDO A TRAVES DE POLIMERIZACION DE UNA MEZCLA DE MONOMEROS DE B1) 73 A 90% EN PESO DE UN MONOMERO VINILAROMATICO Y B2) 27 A 10% EN PESO DE UN COMONOMERO, SELECCIONADO DEL GRUPO CONSISTEN EN ACRILONITRILO, METACRILONITRILO, ETER ALQUILO DE C1 A 8 DEL ACIDO METACRILICO Y/O ACRILICO, ANHIDRIDO DEL ACIDO MALEICO E IMIDA DEL ACIDO MALEICO, QUE SON SUSTITUIDOS EN EL NITROGENO DE IMIDA CON UN GRUPO ALQUILO DE C1 A 6, UN ARILO DE C6 A 10 O UN GRUPO ARILO DE C6 A 10-GRUPO ALQUILO DE C1 A 4, POR LO QUE EL RESTO ARILO PUEDE ESTAR SUBSTITUIDO HASTA TRES VECES CON ALQUILO DE C1 A 4; C) 5 A 50% EN PESO DE UN COPOLIMERIZADO DE MEZCLA DE INJERTO. OBTENIDO A TRAVES DE POLIMERIZACION DE (1) 20 A 45% EN PESO DE UNA MEZCLA DE MONOMEROS VINILOAROMATICOS Y UN MONOMEROINSATURADO ETILENICAMENTE, COPOLIMERIZABLES, POLAR EN PRESENCIA DE C2) 55 A 80% EN PESO DE UNA BASE DE INJERTO, OBTENIBLE A TRAVES DE POLIMERIZACION POR LO MENOS DE UN ESTER ALQUILO DE C1 A 20 ELASTOMERO RETICULADO DEL ACIDO ACRILICO CON UN DIAMETRO DE PARTICULAS MEDIO DE 50 A 150 NM Y D) 5 A 50% EN PESO DE OTRO POLIMERIZADO MEZCLA DE INJERTO, OBTENIDO A TRAVES DE POLIMERIZACION DE D1) 20 A 80% EN PESO DE UNA MEZCLA DE MONOMEROS DE UN MONOMERO VINILOAROMATICO Y UN MONOMERO INSATURADO ETILENICAMENTE COPOLIMERIZABLES POLAR EN PRESENCIA DE D2) 40 A 80% EN PESO DE UN ESTER ALQUILO DE C1 A 20 ELASTOMERO, RETICULADO DEL CICLO ACRILICO COMO BASE DE INJERTO CON UN DIAMETRO DE PARTICULAS MEDIO DE 200 A 700 NM, ASI COMO UN PROCEDIMIENTO PARA PRODUCIR ESTAS MASAS DE MOLDEO TERMOPLASTICAS, SU UTILIZACION PARA LA PRODUCCION DE MOLDES, MOLDE CONTENIENDO ESTAS MASAS DEL MOLDEO TERMOPLASTICAS.
ES93119951T 1992-12-18 1993-12-10 Masas de moldeo termoplasticas con una elevada resiliencia con entalla. Expired - Lifetime ES2099891T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4242974A DE4242974A1 (de) 1992-12-18 1992-12-18 Thermoplastische Formmasse mit erhöhter Kerbschlagzähigkeit

Publications (1)

Publication Number Publication Date
ES2099891T3 true ES2099891T3 (es) 1997-06-01

Family

ID=6475775

Family Applications (1)

Application Number Title Priority Date Filing Date
ES93119951T Expired - Lifetime ES2099891T3 (es) 1992-12-18 1993-12-10 Masas de moldeo termoplasticas con una elevada resiliencia con entalla.

Country Status (5)

Country Link
EP (1) EP0603674B1 (es)
JP (1) JPH06220289A (es)
AT (1) ATE151446T1 (es)
DE (2) DE4242974A1 (es)
ES (1) ES2099891T3 (es)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19527579A1 (de) * 1995-07-28 1997-01-30 Basf Ag Transparente spannungsrißbeständige Formmassen mit einem verbesserten Zähigkeits-Steifigkeits-Verhältnis
DE19536892A1 (de) * 1995-10-04 1997-04-10 Basf Ag Formteile aus thermoplastischen Formmassen
MX347761B (es) * 2010-05-07 2017-05-12 Styrolution Europe Gmbh Composicion de moldeo con difusion de luz reducida.

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4011162A1 (de) * 1990-04-06 1991-10-10 Basf Ag Thermoplastische formmasse

Also Published As

Publication number Publication date
JPH06220289A (ja) 1994-08-09
EP0603674A1 (de) 1994-06-29
DE4242974A1 (de) 1994-06-23
DE59306110D1 (de) 1997-05-15
ATE151446T1 (de) 1997-04-15
EP0603674B1 (de) 1997-04-09

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