ES2080117T3 - Procedimiento para la separacion por adsorcion de 2,6- o 3,5-dietiltolueno a partir de una mezcla de los mismos con otro isomero de dietiltolueno. - Google Patents

Procedimiento para la separacion por adsorcion de 2,6- o 3,5-dietiltolueno a partir de una mezcla de los mismos con otro isomero de dietiltolueno.

Info

Publication number
ES2080117T3
ES2080117T3 ES90307281T ES90307281T ES2080117T3 ES 2080117 T3 ES2080117 T3 ES 2080117T3 ES 90307281 T ES90307281 T ES 90307281T ES 90307281 T ES90307281 T ES 90307281T ES 2080117 T3 ES2080117 T3 ES 2080117T3
Authority
ES
Spain
Prior art keywords
det
diethyltoluene
isomer
mixture
zeolite exchanged
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES90307281T
Other languages
English (en)
Inventor
Herman A Zinnen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Honeywell UOP LLC
Original Assignee
UOP LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by UOP LLC filed Critical UOP LLC
Application granted granted Critical
Publication of ES2080117T3 publication Critical patent/ES2080117T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • B01D15/08—Selective adsorption, e.g. chromatography
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/12—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers
    • C07C7/13—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers by molecular-sieve technique
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • B01D15/08—Selective adsorption, e.g. chromatography
    • B01D15/10—Selective adsorption, e.g. chromatography characterised by constructional or operational features
    • B01D15/18—Selective adsorption, e.g. chromatography characterised by constructional or operational features relating to flow patterns
    • B01D15/1814—Selective adsorption, e.g. chromatography characterised by constructional or operational features relating to flow patterns recycling of the fraction to be distributed

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Treatment Of Liquids With Adsorbents In General (AREA)

Abstract

ES UN PROCESO PARA LA SEPARACION SELECTIVA POR ADSORCION DEL 3,5-DIETILTOLUENO (3,5-DET) O 2,6-DIETILTOLUENO (2,6-DET) DE UNA MEZCLA QUE CONSTA DE AL MENOS UN ISOMERO DEL GRUPO 3,5-DET O 2,6-DET Y AL MENOS UN ISOMERO DET, MEDIANTE LA PUESTA EN CONTACTO DE LA MEZCLA DE ALIMENTACION, EN CONDICIONES DE ADSORCION, CON UN ADSORBENTE SELECCIONADO DE LOS GRUPOS QUE CONSTAN DE A) UNA X ZEOLITA INTERCAMBIADA CON UN CATION DE POTASIO; B) UNA X ZEOLITA INTERCAMBIADA CON SODIO, COBRE O UNA Y ZEOLITA INTERCAMBIADA CON COBRE, SODIO, BARIO O CALCIO; C) UNA X ZEOLITA INTERCAMBIADA CON BARIO O LITIO O CON POTASIO O BARIO O UNA Y ZEOLITA INTERCAMBIADA CON POTASIO, SODIO, BARIO O CALCIO, POR LO QUE SELECTIVAMENTE SE ADSORBEN UNO DE LOS ISOMEROS DET CONTENIDOS EN LA MEZCLA; POR LO QUE SELECTIVAMENTE SE ADSORBEN UNO O MAS DE DICHOS ISOMEROS DET Y SE EXTRAE SELECTIVAMENTE UNO O MAS ISOMERO(S) RELATIVAMENTE NO-ADSORBIBLES EN CONTACTO CON EL ADSORBENTE PARA FORMAR UN REFINADO, SIN VAPOR, EN EL ISOMERO ADSORBIDO RELATIVO A LA MEZCLA DE ALIMENTACION Y POSTERIORMENTE CONTACTANDO EL ADSORBENTE ENRIQUECIDO CON UN DE-ABSORBENTE QUE COMPRENDE UN HIDROCARBURO AROMATICO ALQUILO-SUSTITUIDO MONOCICLICO EN CONDICIONES DE ADSORCION EFECTIVAS PARA FORMAR UN EXTRACTO DE VAPOR ENRIQUECIDO, CON RESPECTO A LA MEZCLA DE ALIMENTACION, EN EL ISOMERO ADSORBIDO.
ES90307281T 1989-04-17 1990-07-03 Procedimiento para la separacion por adsorcion de 2,6- o 3,5-dietiltolueno a partir de una mezcla de los mismos con otro isomero de dietiltolueno. Expired - Lifetime ES2080117T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/339,536 US4940548A (en) 1989-04-17 1989-04-17 Chromatographic separation process for recovering individual diethyltoluene isomers
EP90307281A EP0464277B1 (en) 1989-04-17 1990-07-03 Process for the separation by adsorption of 2,6- or 3,5-diethyltoluene from a mixture thereof with another diethyltoluene isomer

Publications (1)

Publication Number Publication Date
ES2080117T3 true ES2080117T3 (es) 1996-02-01

Family

ID=40139207

Family Applications (1)

Application Number Title Priority Date Filing Date
ES90307281T Expired - Lifetime ES2080117T3 (es) 1989-04-17 1990-07-03 Procedimiento para la separacion por adsorcion de 2,6- o 3,5-dietiltolueno a partir de una mezcla de los mismos con otro isomero de dietiltolueno.

Country Status (4)

Country Link
US (1) US4940548A (es)
EP (1) EP0464277B1 (es)
DE (1) DE69023764T2 (es)
ES (1) ES2080117T3 (es)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5019271A (en) * 1988-12-30 1991-05-28 Uop Extractive chromatographic separation process for recovering 3,5-diethyltoluene
US5174979A (en) * 1989-10-06 1992-12-29 Uop Mixed ion-exchanged zeolites and processes for the use thereof in gas separations
FI86440C (fi) 1990-01-15 1992-08-25 Cultor Oy Foerfarande foer samtidig framstaellning av xylitol och etanol.
US7109005B2 (en) 1990-01-15 2006-09-19 Danisco Sweeteners Oy Process for the simultaneous production of xylitol and ethanol
EP0467484B1 (en) * 1990-07-19 1993-11-18 Cindu Chemicals B.V. Process for separating polar and non-polar constituents from coal tar distillates
US5258058A (en) * 1992-10-05 1993-11-02 Air Products And Chemicals, Inc. Nitrogen adsorption with a divalent cation exchanged lithium X-zeolite
FI96225C (fi) 1993-01-26 1996-05-27 Cultor Oy Menetelmä melassin fraktioimiseksi
US6663780B2 (en) 1993-01-26 2003-12-16 Danisco Finland Oy Method for the fractionation of molasses
FI98791C (fi) * 1994-04-21 1997-08-25 Xyrofin Oy Menetelmä liuoksen fraktioimiseksi
US5795398A (en) 1994-09-30 1998-08-18 Cultor Ltd. Fractionation method of sucrose-containing solutions
DE19545024B4 (de) 1995-12-02 2005-02-17 Sig Corpoplast Gmbh & Co. Kg Verfahren zur Herstellung von Behältern
US6224776B1 (en) * 1996-05-24 2001-05-01 Cultor Corporation Method for fractionating a solution
AU6043598A (en) 1997-01-29 1998-08-18 Amalgamated Research, Inc. Method of displacement chromatography
FR2789914B1 (fr) 1999-02-22 2001-04-06 Ceca Sa Adsorbants zeolitiques agglomeres a faible taux de liant inerte, leur procede d'obtention et leurs utilisations
CN101497022B (zh) * 2008-01-31 2011-06-15 中国石油化工股份有限公司 聚结型沸石吸附剂及其制备方法

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2985589A (en) * 1957-05-22 1961-05-23 Universal Oil Prod Co Continuous sorption process employing fixed bed of sorbent and moving inlets and outlets
US3040777A (en) * 1959-04-10 1962-06-26 Universal Oil Prod Co Rotary valve
US3422848A (en) * 1966-06-09 1969-01-21 Universal Oil Prod Co Multiport rotary disc valve with liner protection means
BE759902A (fr) * 1969-12-05 1971-06-04 Mobil Oil Corp Procede de separation selective par chromatographie
US3706812A (en) * 1970-12-07 1972-12-19 Universal Oil Prod Co Fluid-solid contacting apparatus
US4051192A (en) * 1971-04-21 1977-09-27 Uop Inc. Separation of bi-alkyl substituted monocyclic aromatic isomers
US3723302A (en) * 1971-04-30 1973-03-27 Universal Oil Prod Co Process for separating olefins from saturated hydrocarbons
US3878129A (en) * 1973-05-02 1975-04-15 Universal Oil Prod Co Method of manufacturing a zeolitic adsorbent useful for aromatic separation
US3894109A (en) * 1973-05-02 1975-07-08 Universal Oil Prod Co Aromatic hydrocarbon isomer separation by adsorption
US3943184A (en) * 1974-02-15 1976-03-09 Universal Oil Products Company Aromatic hydrocarbon isomer separation process
US3864416A (en) * 1974-03-18 1975-02-04 Universal Oil Prod Co Separation of tetra-alkyl substituted aromatic hydrocarbon isomers
GB1526065A (en) * 1974-10-16 1978-09-27 Asahi Chemical Ind Process for separation of hydrocarbon mixture
JPS5148620A (en) * 1974-10-17 1976-04-26 Teijin Yuka Kk 1*3*55 torimechirubenzenno seiseiho
JPS557216A (en) * 1978-06-30 1980-01-19 Mitsui Petrochem Ind Ltd Separation of trimethylbenzene isomer
US4213913A (en) * 1979-03-12 1980-07-22 Uop Inc. Two-stage process for separating mixed fatty-acid esters
US4313015A (en) * 1980-02-07 1982-01-26 Uop Inc. Separation process
US4423279A (en) * 1982-02-25 1983-12-27 Uop Inc. Separation of bi-alkyl substituted monocyclic aromatic isomers with pyrolyzed adsorbent
US4402832A (en) * 1982-08-12 1983-09-06 Uop Inc. High efficiency continuous separation process
US4467126A (en) * 1983-07-18 1984-08-21 Uop Inc. Process for the separation of di-substituted benzene
US4482777A (en) * 1984-04-02 1984-11-13 Uop Inc. Separation of ortho bi-alkyl substituted monocyclic aromatic isomers
US4584424A (en) * 1984-10-29 1986-04-22 Exxon Research & Engineering Company Process for separating ethylbenzene from xylenes by selective adsorption on a Beta zeolite
US4642397A (en) * 1985-10-01 1987-02-10 Uop Inc. Process for separating isomers of dinitrotoluene
US4717778A (en) * 1985-10-01 1988-01-05 Uop Inc. Process for separating the minor isomers of dinitrotoluene
US4886930A (en) * 1988-05-23 1989-12-12 Uop Zeolitic para-xylene separation with tetralin heavy desorbent

Also Published As

Publication number Publication date
EP0464277A1 (en) 1992-01-08
DE69023764T2 (de) 1996-04-11
EP0464277B1 (en) 1995-11-22
DE69023764D1 (de) 1996-01-04
US4940548A (en) 1990-07-10

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