ES2073609T3 - Polimero de injerto en forma de particulas y masa de moldeo termoplastica, obtenida con el mismo, de tenacidad mejorada. - Google Patents

Polimero de injerto en forma de particulas y masa de moldeo termoplastica, obtenida con el mismo, de tenacidad mejorada.

Info

Publication number
ES2073609T3
ES2073609T3 ES91104981T ES91104981T ES2073609T3 ES 2073609 T3 ES2073609 T3 ES 2073609T3 ES 91104981 T ES91104981 T ES 91104981T ES 91104981 T ES91104981 T ES 91104981T ES 2073609 T3 ES2073609 T3 ES 2073609T3
Authority
ES
Spain
Prior art keywords
weight
monomer
particles
same
thermoplastic molding
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES91104981T
Other languages
English (en)
Inventor
Friedrich Dr Seitz
Karl Ruppmich
Norbert Dr Guentherberg
Norbert Dr Niessner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Application granted granted Critical
Publication of ES2073609T3 publication Critical patent/ES2073609T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02Homopolymers or copolymers of hydrocarbons
    • C08L25/04Homopolymers or copolymers of styrene
    • C08L25/08Copolymers of styrene
    • C08L25/12Copolymers of styrene with unsaturated nitriles
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

POLIMERIZADO DE INJERTO EN FORMA DE PARTICULAS COMPUESTO POR A: 30-80% EN PESO DE, AL MENOS, UN POLIMERIZADO ELASTOMERO A CON UNA GRANULOMETRIA MEDIA DE 30 A 1000 NM, A BASE DE (REFERIDO A A): A1: 85-99,8% EN PESO DE UN ACRILATO DE ALQUILO A1 CON 1 A 8 ATOMOS DE CARBONO EN EL RESTO DE ALQUILO, A2: 0,1-5% EN PESO DE, AL MENOS, UN MONOMERO POLIFUNCIONAL A2, DE ACCION RETICULANTE Y A3: 0,1-10% EN PESO DE, AL MENOS, UN MONOMERO A3 QUE CONTIENE UNO O VARIOS GRUPOS ACIDOS, O A11: HASTA EL 100% EN PESO DE UN DIENO A11 A12: HASTA EL 50% EN PESO DE, AL MENOS, UN MONOMERO VINILAROMATICO A12 A13: HASTA UN 10% EN PESO DE, AL MENOS, DE UN MONOMERO A13 QUE CONTIENE UNO O VARIOS GRUPOS ACIDOS, COMO BASE DE INJERTO, Y B: 20-70% EN PESO DE UN RECUBRIMIENTO B INJERTADO SOBRE EL POLIMERIZADO ELASTOMERO A, A BASE DE (REFERIDO A B): B1: 50-89,9% EN PESO DE, AL MENOS, UN MONOMERO VINILAROMATICO B1 B2: 10-49,9% EN PESO DE, AL MENOS, UN MONOMERO B2 POLAR, COPOLIMERIZABLE, ETILENICO INSATURADO, Y B3: 0,1-10% EN PESO DE, AL MENOS, UN MONOMERO B3 QUE CONTIENE UNO O VARIOS GRUPOS BASICOS.
ES91104981T 1990-04-06 1991-03-28 Polimero de injerto en forma de particulas y masa de moldeo termoplastica, obtenida con el mismo, de tenacidad mejorada. Expired - Lifetime ES2073609T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4011163A DE4011163A1 (de) 1990-04-06 1990-04-06 Teilchenfoermiges pfropfpolymerisat und daraus hergestellte thermoplastische formmasse mit verbesserter zaehigkeit

Publications (1)

Publication Number Publication Date
ES2073609T3 true ES2073609T3 (es) 1995-08-16

Family

ID=6403901

Family Applications (1)

Application Number Title Priority Date Filing Date
ES91104981T Expired - Lifetime ES2073609T3 (es) 1990-04-06 1991-03-28 Polimero de injerto en forma de particulas y masa de moldeo termoplastica, obtenida con el mismo, de tenacidad mejorada.

Country Status (6)

Country Link
US (1) US5342898A (es)
EP (1) EP0450511B1 (es)
JP (1) JPH04225010A (es)
KR (1) KR0177810B1 (es)
DE (2) DE4011163A1 (es)
ES (1) ES2073609T3 (es)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4041186A1 (de) * 1990-12-21 1992-06-25 Basf Ag Zweistufiges emulsionscopolymerisat
DE4131729A1 (de) * 1991-09-24 1993-03-25 Basf Ag Pfropfkautschuk-mischung und seine verwendung zur herstellung von formmassen
DE4142910A1 (de) * 1991-12-24 1993-07-01 Basf Ag Schlagzaehmodifier und diesen enthaltende formmasse
DE4216549A1 (de) * 1992-05-19 1993-11-25 Basf Ag Teilchenförmiges Pfropfpolymerisat
DE4221293A1 (de) * 1992-06-29 1994-01-05 Basf Ag Formmasse mit matter Oberfläche
DE4230257A1 (de) * 1992-09-10 1994-03-17 Basf Ag Formmasse
DE4234296A1 (de) * 1992-10-12 1994-04-14 Basf Ag Thermoplastische Formmasse
DE4235976A1 (de) * 1992-10-24 1994-04-28 Basf Ag Thermoplastische Formmasse
DE4237640A1 (de) * 1992-11-07 1994-05-11 Basf Ag Thermoplastische Formmasse
DE4242485A1 (de) * 1992-12-16 1994-06-23 Basf Ag Teilchenförmiges Pfropfpolymerisat und hieraus erhaltene thermoplastische Formmasse
DE4315881A1 (de) * 1993-05-12 1994-11-17 Basf Ag Zweistufig aufgebautes Copolymerisat
DE4331805A1 (de) * 1993-09-18 1995-03-23 Basf Ag Matte, transparente Thermoplastharze
DE4331804A1 (de) * 1993-09-18 1995-03-23 Basf Ag Teilchenförmiges Pfropfcopolymerisat
DE4342045A1 (de) * 1993-12-09 1995-06-14 Basf Ag Dreistufige Pfropfcopolymerisate und solche enthaltende witterungsbeständige, matte thermoplastische Formmassen mit hoher Kältezähigkeit
DE4407069A1 (de) * 1994-03-03 1995-09-07 Basf Ag Formmasse
DE4437501A1 (de) * 1994-10-20 1996-04-25 Basf Ag Thermoplastische Formmassen
DE4439969A1 (de) * 1994-11-09 1996-05-15 Basf Ag Matte thermoplastische Formmassen
JP3723576B2 (ja) * 1995-08-31 2005-12-07 ビーエーエスエフ アクチェンゲゼルシャフト 低いヘイズ値を有する熱可塑性の成形用材料
DE19536892A1 (de) * 1995-10-04 1997-04-10 Basf Ag Formteile aus thermoplastischen Formmassen
US5777036A (en) * 1996-02-01 1998-07-07 Basf Aktiengesellschaft Particulate graft copolymers and thermoplastic molding materials containing them and having improved colorability
DE19623416A1 (de) * 1996-06-12 1997-12-18 Basf Ag Teilchenförmige Pfropfcopolymerisate und diese enthaltende thermoplastische Formmassen mit verbesserter Einfärbbarkeit
GB9702241D0 (en) * 1997-02-04 1997-03-26 Dow Deutschland Inc Emulsion polymers which provide scrub resistance and blocking resistance in high and low pvc paint formulations
DE60043874D1 (de) 1999-09-16 2010-04-08 Rohm & Haas Modifizierte SAN-Harzzusammensetzungen und daraus hergestellte Gegenstände
ATE506383T1 (de) 2006-02-23 2011-05-15 Mitsubishi Rayon Co (meth)acrylpolymerteilchen, methode zur ihren herstellung, plastisol und gegenstand
JP7086563B2 (ja) * 2017-11-02 2022-06-20 株式会社Eneosマテリアル 金属めっき成形品用組成物に用いるための重合体及びその製造方法、金属めっき成形品用組成物、並びに金属めっき成形品

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL99388C (es) * 1956-09-28
DE1260135B (de) * 1965-01-05 1968-02-01 Basf Ag Schlagfeste thermoplastische Formmassen
US3639216A (en) * 1967-11-11 1972-02-01 Sumitomo Naugatuck Improving adhesion of electroplated metal on graft copolymers
US3632683A (en) * 1968-06-26 1972-01-04 Texaco Inc Synthetic resin containing vinylpyridine
DE3113627A1 (de) * 1981-04-04 1982-10-21 Basf Ag, 6700 Ludwigshafen Transparente, schlagzaehe formmasse
DE3149358A1 (de) * 1981-12-12 1983-06-16 Basf Ag, 6700 Ludwigshafen Thermoplastische formmasse
CA1315906C (en) * 1985-11-04 1993-04-06 Lewis Ellis Ferguson, Iii Clear impact modifier for pvc
JPS62181312A (ja) * 1986-02-06 1987-08-08 Mitsubishi Rayon Co Ltd 耐衝撃性、耐候性および成形性に優れるグラフト共重合体樹脂の製造方法
DE4005210A1 (de) * 1990-02-20 1991-08-22 Basf Ag Thermoplastische formmasse mit verbesserter zaehigkeit

Also Published As

Publication number Publication date
EP0450511A3 (en) 1992-04-29
JPH04225010A (ja) 1992-08-14
KR910018428A (ko) 1991-11-30
US5342898A (en) 1994-08-30
KR0177810B1 (ko) 1999-05-15
DE59105819D1 (de) 1995-08-03
EP0450511B1 (de) 1995-06-28
EP0450511A2 (de) 1991-10-09
DE4011163A1 (de) 1991-10-10

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