ES2062928A1 - Procedimiento para la obtencion selectiva de monoesteres de dioles y trioles empleando catalizadores zeoliticos. - Google Patents

Procedimiento para la obtencion selectiva de monoesteres de dioles y trioles empleando catalizadores zeoliticos.

Info

Publication number
ES2062928A1
ES2062928A1 ES09202555A ES9202555A ES2062928A1 ES 2062928 A1 ES2062928 A1 ES 2062928A1 ES 09202555 A ES09202555 A ES 09202555A ES 9202555 A ES9202555 A ES 9202555A ES 2062928 A1 ES2062928 A1 ES 2062928A1
Authority
ES
Spain
Prior art keywords
triols
diols
acid
monoesters
zeotypes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
ES09202555A
Other languages
English (en)
Other versions
ES2062928B1 (es
Inventor
Mira Jose Aracil
Canos Avelino Corma
Rodriguez Mercedes Martinez
Menendez Nieves Sanchez
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Consejo Superior de Investigaciones Cientificas CSIC
Universidad Politecnica de Valencia
Universitat de Valencia
Original Assignee
Consejo Superior de Investigaciones Cientificas CSIC
Universidad Politecnica de Valencia
Universitat de Valencia
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to ES09202555A priority Critical patent/ES2062928B1/es
Application filed by Consejo Superior de Investigaciones Cientificas CSIC, Universidad Politecnica de Valencia, Universitat de Valencia filed Critical Consejo Superior de Investigaciones Cientificas CSIC
Priority to EP94902781A priority patent/EP0627404B1/en
Priority to ES94902781T priority patent/ES2107173T3/es
Priority to PCT/ES1993/000100 priority patent/WO1994013617A1/es
Priority to DE69313265T priority patent/DE69313265T2/de
Priority to AT94902781T priority patent/ATE157078T1/de
Priority to DK94902781.7T priority patent/DK0627404T3/da
Publication of ES2062928A1 publication Critical patent/ES2062928A1/es
Application granted granted Critical
Publication of ES2062928B1 publication Critical patent/ES2062928B1/es
Priority to GR970403058T priority patent/GR3025413T3/el
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PROCEDIMIENTO PARA LA OBTENCION SELECTIVA DE MONOESTERES DE DIOLES Y TRIOLES EMPLEANDO CATALIZADORES ZEOLITICOS. LA ESTERIFICACION SELECTIVA DE UN ACIDO GRASO Y UN POLIALCOHOL SE REALIZA MEDIANTE EL EMPLEO, COMO CATALIZADOR, DE ZEOLITAS Y ZEOTIPOS DE PORO GRANDE, PREFERENTEMENTE CON ANILLOS DE DOCE MIEMBROS (FAUJASITA, MORDENITA, ETC.), CON CARACTERISTICAS ACIDAS O BASICAS; SE EMPLEAN ACIDOS GRASOS, SATURADOS O NO SATURADOS, CONTENIENDO DE 4 A 22 ATOMOS DE CARBONO, PREFERENTEMENTE ACIDO OLEICO, PALMITICO, ESTEARICO E ISOESTEARICO, Y DIOLES O TRIOLES, PREFERENTEMENTE GLICERINA, LA REACCION SE REALIZA A UNA TEMPERATURA COMPRENDIDA ENTRE 100 Y 190GC, A PRESIONES COMPRENDIDAS ENTRE 5 KPA Y 200 KPA. LAS ZEOLITAS Y ZEOTIPOS PUEDEN SER UTILIZADAS COMO CATALIZADOR DIRECTAMENTE O INCLUIDA EN UNA MATRIZ TAL COMO ALSI2 SCOSI3 SC, SILICE, CAOLIN, SILICE-ALUMINA AMORFA O CUALQUIER OTRA DE LAS CONOCIDAS.
ES09202555A 1992-12-17 1992-12-17 Procedimiento para la obtencion selectiva de monoesteres de dioles y trioles empleando catalizadores zeoliticos. Expired - Fee Related ES2062928B1 (es)

Priority Applications (8)

Application Number Priority Date Filing Date Title
ES09202555A ES2062928B1 (es) 1992-12-17 1992-12-17 Procedimiento para la obtencion selectiva de monoesteres de dioles y trioles empleando catalizadores zeoliticos.
ES94902781T ES2107173T3 (es) 1992-12-17 1993-12-16 Procedimiento para la produccion selectiva de monoesteres de dioles y trioles utilizando catalizadores zeoliticos.
PCT/ES1993/000100 WO1994013617A1 (es) 1992-12-17 1993-12-16 Procedimiento para la obtencion selectiva de monoesteres de dioles y trioles empleando catalizadores zeoliticos
DE69313265T DE69313265T2 (de) 1992-12-17 1993-12-16 Verfahren zur selektiven herstellung von diol- oder triol-monoestern unter verwendung von zeolithkatalysatoren
EP94902781A EP0627404B1 (en) 1992-12-17 1993-12-16 Process for the selective production of monoesters of diols and triols using zeolitic catalysts
AT94902781T ATE157078T1 (de) 1992-12-17 1993-12-16 Verfahren zur selektiven herstellung von diol- oder triol-monoestern unter verwendung von zeolithkatalysatoren
DK94902781.7T DK0627404T3 (da) 1992-12-17 1993-12-16 Fremgangsmåde til selektiv fremstilling af diol- eller triol-monoestere under anvendelse af zeolitkatalysatorer.
GR970403058T GR3025413T3 (en) 1992-12-17 1997-11-19 Process for the selective production of monoesters of diols and triols using zeolitic catalysts.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES09202555A ES2062928B1 (es) 1992-12-17 1992-12-17 Procedimiento para la obtencion selectiva de monoesteres de dioles y trioles empleando catalizadores zeoliticos.

Publications (2)

Publication Number Publication Date
ES2062928A1 true ES2062928A1 (es) 1994-12-16
ES2062928B1 ES2062928B1 (es) 1995-07-16

Family

ID=8279139

Family Applications (2)

Application Number Title Priority Date Filing Date
ES09202555A Expired - Fee Related ES2062928B1 (es) 1992-12-17 1992-12-17 Procedimiento para la obtencion selectiva de monoesteres de dioles y trioles empleando catalizadores zeoliticos.
ES94902781T Expired - Lifetime ES2107173T3 (es) 1992-12-17 1993-12-16 Procedimiento para la produccion selectiva de monoesteres de dioles y trioles utilizando catalizadores zeoliticos.

Family Applications After (1)

Application Number Title Priority Date Filing Date
ES94902781T Expired - Lifetime ES2107173T3 (es) 1992-12-17 1993-12-16 Procedimiento para la produccion selectiva de monoesteres de dioles y trioles utilizando catalizadores zeoliticos.

Country Status (7)

Country Link
EP (1) EP0627404B1 (es)
AT (1) ATE157078T1 (es)
DE (1) DE69313265T2 (es)
DK (1) DK0627404T3 (es)
ES (2) ES2062928B1 (es)
GR (1) GR3025413T3 (es)
WO (1) WO1994013617A1 (es)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2238017A1 (es) * 2004-01-21 2005-08-01 Universidad Politecnica De Valencia Procedimiento de preparacion de monoesteres de acidos grasos y alcoholes polihidroxilicos.

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2110366B1 (es) * 1995-11-08 1999-05-16 Univ Valencia Politecnica Procedimiento y catalizadores para la obtencion selectiva de acetales.
US6291409B1 (en) * 1998-07-02 2001-09-18 Cargill, Inc. Process for modifying unsaturated triacylglycerol oils; Resulting products and uses thereof
DE102007063507A1 (de) * 2007-12-28 2009-07-02 Biorefinery.De Gmbh Verfahren zur Herstellung von Carbonsäureestern

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2019823A6 (es) * 1989-04-18 1991-07-01 Kao Corp Procedimiento para la preparacion de monoesteres de acidos grasos con glicerol.
ES2029772A6 (es) * 1991-02-19 1992-09-01 Univ Politecnica De Valencia E Procedimiento para la preparacion de un aceite semejante al de jojoba utilizando zeolitas ultraestables como catalizador.

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3512497A1 (de) * 1985-04-06 1986-10-09 Hüls AG, 4370 Marl Verfahren zur herstellung von carbonsaeurealkylestern, insbesondere fettsaeurealkylestern, und deren verwendung als dieselkraftstoff
DE3921917A1 (de) * 1989-07-04 1991-01-17 Hoechst Ag Verfahren zur herstellung eines esters einer c(pfeil abwaerts)2(pfeil abwaerts)(pfeil abwaerts)2(pfeil abwaerts)-c(pfeil abwaerts)4(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-monocarbonsaeure

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2019823A6 (es) * 1989-04-18 1991-07-01 Kao Corp Procedimiento para la preparacion de monoesteres de acidos grasos con glicerol.
ES2029772A6 (es) * 1991-02-19 1992-09-01 Univ Politecnica De Valencia E Procedimiento para la preparacion de un aceite semejante al de jojoba utilizando zeolitas ultraestables como catalizador.

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2238017A1 (es) * 2004-01-21 2005-08-01 Universidad Politecnica De Valencia Procedimiento de preparacion de monoesteres de acidos grasos y alcoholes polihidroxilicos.
WO2005070865A1 (es) * 2004-01-21 2005-08-04 Consejo Superior De Investigaciones Científicas Procedimiento de preparación de monoésteres de alcoholes polihidroxílicos
EA012568B1 (ru) * 2004-01-21 2009-10-30 Консехо Супериор Де Инвестигасьонес Сьентификас Способ получения сложных моноэфиров многоатомных спиртов

Also Published As

Publication number Publication date
DK0627404T3 (da) 1997-10-13
ATE157078T1 (de) 1997-09-15
ES2062928B1 (es) 1995-07-16
EP0627404A1 (en) 1994-12-07
WO1994013617A1 (es) 1994-06-23
ES2107173T3 (es) 1997-11-16
EP0627404B1 (en) 1997-08-20
DE69313265D1 (de) 1997-09-25
GR3025413T3 (en) 1998-02-27
DE69313265T2 (de) 1998-03-05

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Legal Events

Date Code Title Description
FD1A Patent lapsed

Effective date: 19980422