ES2054313T3 - Procedimiento para la obtencion de ciclopropanocarbaldehidos sustituidos. - Google Patents

Procedimiento para la obtencion de ciclopropanocarbaldehidos sustituidos.

Info

Publication number
ES2054313T3
ES2054313T3 ES90810057T ES90810057T ES2054313T3 ES 2054313 T3 ES2054313 T3 ES 2054313T3 ES 90810057 T ES90810057 T ES 90810057T ES 90810057 T ES90810057 T ES 90810057T ES 2054313 T3 ES2054313 T3 ES 2054313T3
Authority
ES
Spain
Prior art keywords
halogen
formula
c4alkyl
unsubstituted
substituted
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES90810057T
Other languages
English (en)
Inventor
Hans-Ruedi Dr Kanel
John Grey Dr Dingwall
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novartis AG
Original Assignee
Ciba Geigy AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Geigy AG filed Critical Ciba Geigy AG
Application granted granted Critical
Publication of ES2054313T3 publication Critical patent/ES2054313T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/22—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and doubly-bound oxygen atoms bound to the same carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
    • C07C43/04—Saturated ethers
    • C07C43/12—Saturated ethers containing halogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
    • C07C303/02—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof
    • C07C303/22—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof from sulfonic acids, by reactions not involving the formation of sulfo or halosulfonyl groups; from sulfonic halides by reactions not involving the formation of halosulfonyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/14—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C325/00—Thioaldehydes; Thioketones; Thioquinones; Oxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D307/18—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/20—Oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/02—Systems containing only non-condensed rings with a three-membered ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Furan Compounds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

EL INVENTO SE REFIERE A UN PROCEDIMIENTO PARA PRODUCIR CICLOPROPANOCARBALDEHIDO DE FORMULA (I) QUE CONSISTE EN: A) HALOGENAR UN TETRAHIDROFURANO DE FORMULA (II) PARA OBTENER UN 1, 2, 4 TRIHALOGENOBUTILETER DE FORMULA (III); B) TRATAR AL COMPUESTO DE FORMULA (III) CON UNA SOLUCION DE BISULFITO PARA PRODUCIR UN ADUCTO DE BISULFITO DE FORMULA (IV) Y C) HACER REACCIONAR AL COMPUESTO DE FORMULA (IV) CON UN TIOLATO DE FORMULA (V), EN PRESENCIA DE UNA BASE PARA CICLIZAR EL COMPUESTO DE FORMULA (IV) Y OBTENER UN CICLOPROPANOCARBALDEHIDO DE FORMULA (I); DESCRIBE LAS ETAPAS DE PROCEDIMIENTO A), B) Y C) Y LAS COMBINACIONES DE LAS ETAPAS A) + B) Y B) + C) Y TRATA DE LOS NUEVOS COMPUESTOS INTERMEDIOS DE FORMULA (III) Y (IV). SIENDO; R1 ALQUILO DE C1 A 4 O BENCILO; R (AL CUADRADO) ALQUILO DE C1 A 10, CICLOALCOXI DE C3 A 6 SUBSTITUIDO A TRAVES DE HALOGENO, ALQUILO DE C1 A 4 O ALCOXI DE C1 A 4 O FENILO O BENCILO, SUBTITUIDOS A TRAVES DE HALOGENO, ALQUILO DE C1 A 4 ALCOXI DE C1 A 4, NITRO, CIANO; X HALOGENO; Y UN EQUIVALENTE DE UN CATION DE IONES ALCALINOS O ALCALINOTERREOS Y Z IV.
ES90810057T 1989-02-02 1990-01-24 Procedimiento para la obtencion de ciclopropanocarbaldehidos sustituidos. Expired - Lifetime ES2054313T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH36589 1989-02-02

Publications (1)

Publication Number Publication Date
ES2054313T3 true ES2054313T3 (es) 1994-08-01

Family

ID=4185369

Family Applications (1)

Application Number Title Priority Date Filing Date
ES90810057T Expired - Lifetime ES2054313T3 (es) 1989-02-02 1990-01-24 Procedimiento para la obtencion de ciclopropanocarbaldehidos sustituidos.

Country Status (13)

Country Link
US (1) US4968836A (es)
EP (1) EP0381623B1 (es)
JP (1) JPH0637415B2 (es)
KR (1) KR900012900A (es)
AT (1) ATE87617T1 (es)
BR (1) BR9000447A (es)
CA (1) CA2009008A1 (es)
DE (1) DE59001086D1 (es)
DK (1) DK0381623T3 (es)
ES (1) ES2054313T3 (es)
GR (1) GR3007854T3 (es)
IL (1) IL93228A (es)
ZA (1) ZA90757B (es)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0381624B1 (de) * 1989-02-02 1993-05-12 Ciba-Geigy Ag Verfahren zur Herstellung von 1-Alkylthio- und 1-Benzylthio-1-formylcyclopropanen
US5189227A (en) * 1989-02-02 1993-02-23 Ciba-Geigy Corporation 1,2,4-trihalobutyl ethers

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3239560A (en) * 1962-03-05 1966-03-08 Procter & Gamble Method for preparation of halide hydroxysulfonate
US3721711A (en) * 1970-04-29 1973-03-20 Exxon Research Engineering Co Cycloalkane carboxaldoxime carbamates
ES2014493B3 (es) * 1986-04-24 1990-07-16 Ciba-Geigy Ag Acil-ciclohexandionas y sus eteres de oximas con efecto herbicida y regulador del crecimiento de las plantas.

Also Published As

Publication number Publication date
EP0381623B1 (de) 1993-03-31
CA2009008A1 (en) 1990-08-02
GR3007854T3 (es) 1993-08-31
JPH02240038A (ja) 1990-09-25
BR9000447A (pt) 1991-01-15
ZA90757B (en) 1990-10-31
DE59001086D1 (de) 1993-05-06
IL93228A (en) 1995-01-24
US4968836A (en) 1990-11-06
JPH0637415B2 (ja) 1994-05-18
EP0381623A1 (de) 1990-08-08
IL93228A0 (en) 1990-11-05
ATE87617T1 (de) 1993-04-15
KR900012900A (ko) 1990-09-03
DK0381623T3 (da) 1993-08-02

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