ES2045114T3 - Sensores de gas acido. - Google Patents
Sensores de gas acido.Info
- Publication number
- ES2045114T3 ES2045114T3 ES88304839T ES88304839T ES2045114T3 ES 2045114 T3 ES2045114 T3 ES 2045114T3 ES 88304839 T ES88304839 T ES 88304839T ES 88304839 T ES88304839 T ES 88304839T ES 2045114 T3 ES2045114 T3 ES 2045114T3
- Authority
- ES
- Spain
- Prior art keywords
- complex
- electrolyte
- acid gas
- gas sensors
- sensing electrode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/403—Cells and electrode assemblies
- G01N27/404—Cells with anode, cathode and cell electrolyte on the same side of a permeable membrane which separates them from the sample fluid, e.g. Clark-type oxygen sensors
- G01N27/4045—Cells with anode, cathode and cell electrolyte on the same side of a permeable membrane which separates them from the sample fluid, e.g. Clark-type oxygen sensors for gases other than oxygen
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- General Physics & Mathematics (AREA)
- Electrochemistry (AREA)
- Physics & Mathematics (AREA)
- Analytical Chemistry (AREA)
- Molecular Biology (AREA)
- General Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
- Investigating Or Analyzing Materials By The Use Of Fluid Adsorption Or Reactions (AREA)
- Investigating Or Analysing Materials By The Use Of Chemical Reactions (AREA)
- Measuring Oxygen Concentration In Cells (AREA)
- Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)
Abstract
LA PRESENTE INVENCION PROPORCIONA UN SENSOR, PREFERIBLEMENTE UN SENSOR ELECTROQUIMICO, PARA DETECTAR GASES ACIDOS, POR EJEMPLO DIOXIDO DE CARBONO. EL SENSOR ELECTROQUIMICO TIENE UN ELECTRODO SENSIBLE (20, 22), UN ELECTRODO CONTADOR (37) Y UN ELECTROLITO QUE CONTIENE UN COMPLEJO, POR EJEMPLO, BIS(PROPANODIAMINA) DE COBRE(II), QUE TIENE UNO O MAS LIGANDOS DESPLAZABLES POR LA PRESENCIA DEL GAS ACIDO EN EL ELECTROLITO PARA FORMAR UN COMPLEJO MODIFICADO QUE PUEDE SER ELECTROQUIMICAMENTE REACTIVO EN EL ELCETRODO SENSOR A UN POTENCIAL AL QUE EL COMPLEJO NO MODIFICADO NO ES REACTIVO. EL GAS ACIDO DIFUNDE EN EL ELECTROLITO A TRAVES DE UNA MEMBRANA PORORSA. EL COMPLEJO MODIFICADO TAMBIEN SE PUEDE DETECTAR COLORIMETRICAMENTE DEBIDO A QUE ABSORBE LUZ A UNA LONGITUD DE ONDA DIFERENTE QUE EL COMPLEJO NO MODIFICADO.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB878712582A GB8712582D0 (en) | 1987-05-28 | 1987-05-28 | Acidic gas sensors |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2045114T3 true ES2045114T3 (es) | 1994-01-16 |
Family
ID=10618059
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES88304839T Expired - Lifetime ES2045114T3 (es) | 1987-05-28 | 1988-05-27 | Sensores de gas acido. |
Country Status (10)
Country | Link |
---|---|
US (1) | US5071526A (es) |
EP (1) | EP0293230B1 (es) |
JP (1) | JP2648337B2 (es) |
AT (1) | ATE93319T1 (es) |
AU (1) | AU598932B2 (es) |
CA (1) | CA1307320C (es) |
DE (1) | DE3883289T2 (es) |
ES (1) | ES2045114T3 (es) |
GB (1) | GB8712582D0 (es) |
ZA (1) | ZA883816B (es) |
Families Citing this family (68)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3923717A1 (de) * | 1989-07-18 | 1991-01-24 | Draegerwerk Ag | Elektrochemische messzelle zum nachweis von blausaeure oder schwefeldioxid |
DE4133831A1 (de) * | 1991-09-14 | 1993-03-18 | Draegerwerk Ag | Elektrochemische messzelle zum nachweis und zur bestimmung von gasen und daempfen insbesondere von halogen-wasserstoffen |
JPH06229980A (ja) * | 1993-02-04 | 1994-08-19 | Gastec:Kk | 定電位電解式ガスセンサ |
US5338429A (en) * | 1993-03-05 | 1994-08-16 | Mine Safety Appliances Company | Electrochemical toxic gas sensor |
US5419826A (en) * | 1994-03-25 | 1995-05-30 | The United States Of America As Represented By The Secretary Of The Navy | Ion-selective reference probe |
US5879526A (en) * | 1994-11-08 | 1999-03-09 | Robert Bosch Gmbh | Electrochemical measuring sensor for determining nitrogen oxides in gas mixtures |
AU5561796A (en) * | 1995-04-21 | 1996-11-07 | Mine Safety Appliances Company | Electrochemical gas sensor for the detection of nitrogen dio xide |
GB2302731B (en) * | 1995-06-16 | 1997-11-12 | Sun Electric Uk Ltd | Method and apparatus for gas monitoring |
JPH1071150A (ja) * | 1996-07-03 | 1998-03-17 | Nippon Koden Corp | 生体内ガスセンサ |
US6013459A (en) * | 1997-06-12 | 2000-01-11 | Clinical Micro Sensors, Inc. | Detection of analytes using reorganization energy |
CA2215108C (en) * | 1997-09-11 | 1999-10-26 | Senco Sensors Inc. | Electrochemical gas sensor |
CA2245050C (en) * | 1997-09-11 | 2000-09-05 | Kehoe Component Sales Inc. Dba Pace Electronic Products Inc. | Three-electrode electrochemical gas sensor |
US6284197B1 (en) | 1998-06-05 | 2001-09-04 | The Regents Of The University Of California | Optical amplification of molecular interactions using liquid crystals |
US6858423B1 (en) | 1998-06-05 | 2005-02-22 | The Regents Of The University Of California | Optical Amplification of molecular interactions using liquid crystals |
US6805788B1 (en) * | 1998-07-10 | 2004-10-19 | Lynntech, Inc. | Electrochemical impedance evaluation and inspection sensor |
US7109853B1 (en) | 1999-04-26 | 2006-09-19 | Cherry Corporation | System for detecting and releasing a person locked in the trunk of a vehicle |
US6623620B2 (en) | 1999-11-22 | 2003-09-23 | Hathaway Brown School | Method for detecting or monitoring sulfur dioxide with an electrochemical sensor |
DE10009467A1 (de) * | 2000-02-28 | 2001-09-20 | Bcs Bio Und Chemosensoren Gmbh | Enzymatisch-elektrochemische Durchflußmeßeinrichtung (EED) |
GB0214611D0 (en) * | 2002-06-25 | 2002-08-07 | Asthmo Alert | Electrochemical sensor for the analysis of carbon dioxide gas |
US7220387B2 (en) * | 2002-07-23 | 2007-05-22 | Apieron Biosystems Corp. | Disposable sensor for use in measuring an analyte in a gaseous sample |
JP2007523321A (ja) * | 2003-12-31 | 2007-08-16 | ユニヴァーシティー オブ サウスカロライナ | 気体及び他の流体のための薄層多孔光センサ |
GB2417083B (en) * | 2004-08-13 | 2006-08-16 | Mark Sinclair Varney | An electrochemical carbon dioxide gas sensor |
US20070201136A1 (en) | 2004-09-13 | 2007-08-30 | University Of South Carolina | Thin Film Interference Filter and Bootstrap Method for Interference Filter Thin Film Deposition Process Control |
US20060118416A1 (en) * | 2004-12-08 | 2006-06-08 | Honeywell International, Inc. | Electrochemical sensor system |
DE102004059280B4 (de) * | 2004-12-09 | 2007-08-16 | Dräger Safety AG & Co. KGaA | Elektrochemischer Gassensor |
US20060278536A1 (en) * | 2005-06-10 | 2006-12-14 | The Regents Of The University Of California | Sensor comprising supported aprotic ionic liquid |
US7664607B2 (en) | 2005-10-04 | 2010-02-16 | Teledyne Technologies Incorporated | Pre-calibrated gas sensor |
US7910382B2 (en) * | 2005-10-31 | 2011-03-22 | Wisconsin Alumni Research Foundation | Device and methods for liquid crystal-based bioagent detection |
US20070166245A1 (en) * | 2005-11-28 | 2007-07-19 | Leonard Mackles | Propellant free foamable toothpaste composition |
EP1974201A1 (en) * | 2005-11-28 | 2008-10-01 | University of South Carolina | Optical analysis system for dynamic, real-time detection and measurement |
WO2007061436A1 (en) | 2005-11-28 | 2007-05-31 | University Of South Carolina | Self calibration methods for optical analysis system |
US8154726B2 (en) | 2005-11-28 | 2012-04-10 | Halliburton Energy Services, Inc. | Optical analysis system and method for real time multivariate optical computing |
EP2033196A2 (en) | 2006-06-26 | 2009-03-11 | University of South Carolina | Data validation and classification in optical analysis systems |
AU2007274795A1 (en) | 2006-07-21 | 2008-01-24 | Anaxsys Technology Limited | Gas sensor |
GB2443023A (en) * | 2006-10-18 | 2008-04-23 | Anaxsys Technology Ltd | Determining the carbon dioxide content of an exhaled gas stream |
US8449473B2 (en) | 2006-10-18 | 2013-05-28 | Anaxsys Technology Limited | Gas sensor |
EP2078187A2 (en) | 2006-11-02 | 2009-07-15 | University of South Carolina | Multi-analyte optical computing system |
WO2008121715A1 (en) | 2007-03-30 | 2008-10-09 | Ometric Corporation | In-line process measurement systems and methods |
WO2008121692A1 (en) | 2007-03-30 | 2008-10-09 | University Of South Carolina | Tablet analysis and measurement system |
US8213006B2 (en) * | 2007-03-30 | 2012-07-03 | Halliburton Energy Services, Inc. | Multi-analyte optical computing system |
US7722816B2 (en) * | 2007-05-24 | 2010-05-25 | Wisconsin Alumni Research Foundation | Detection device and method |
GB0714788D0 (en) * | 2007-07-30 | 2007-09-12 | Alphasense Ltd | Flue gas analyser |
US8283633B2 (en) | 2007-11-30 | 2012-10-09 | Halliburton Energy Services, Inc. | Tuning D* with modified thermal detectors |
US8212213B2 (en) | 2008-04-07 | 2012-07-03 | Halliburton Energy Services, Inc. | Chemically-selective detector and methods relating thereto |
EP2436310A1 (en) | 2008-04-10 | 2012-04-04 | Anaxsys Technology Limited | Gas sensor |
WO2010024076A1 (ja) * | 2008-08-25 | 2010-03-04 | 理研計器株式会社 | 定電位電解式酸素センサ |
WO2010093803A2 (en) * | 2009-02-12 | 2010-08-19 | Keimar, Inc. | Physiological parameter sensors |
US20110237830A1 (en) * | 2010-03-26 | 2011-09-29 | Dioxide Materials Inc | Novel catalyst mixtures |
US9957624B2 (en) | 2010-03-26 | 2018-05-01 | Dioxide Materials, Inc. | Electrochemical devices comprising novel catalyst mixtures |
US20130015064A1 (en) * | 2011-06-29 | 2013-01-17 | Masel Richard I | Sensors For Carbon Dioxide And Other End Uses |
US9790161B2 (en) | 2010-03-26 | 2017-10-17 | Dioxide Materials, Inc | Process for the sustainable production of acrylic acid |
US9193593B2 (en) | 2010-03-26 | 2015-11-24 | Dioxide Materials, Inc. | Hydrogenation of formic acid to formaldehyde |
US9566574B2 (en) | 2010-07-04 | 2017-02-14 | Dioxide Materials, Inc. | Catalyst mixtures |
US10173169B2 (en) | 2010-03-26 | 2019-01-08 | Dioxide Materials, Inc | Devices for electrocatalytic conversion of carbon dioxide |
US9815021B2 (en) | 2010-03-26 | 2017-11-14 | Dioxide Materials, Inc. | Electrocatalytic process for carbon dioxide conversion |
US9012345B2 (en) | 2010-03-26 | 2015-04-21 | Dioxide Materials, Inc. | Electrocatalysts for carbon dioxide conversion |
US8956990B2 (en) | 2010-03-26 | 2015-02-17 | Dioxide Materials, Inc. | Catalyst mixtures |
WO2014047661A2 (en) | 2012-09-24 | 2014-03-27 | Dioxide Materials, Inc. | Devices and processes for carbon dioxide conversion into useful fuels and chemicals |
US10647652B2 (en) | 2013-02-24 | 2020-05-12 | Dioxide Materials, Inc. | Process for the sustainable production of acrylic acid |
EP2972282A1 (en) | 2013-03-15 | 2016-01-20 | The Cleveland Clinic Foundation | Miniaturized gas sensor device and method |
US10175254B2 (en) | 2013-07-16 | 2019-01-08 | Palo Alto Health Sciences, Inc. | Methods and systems for quantitative colorimetric capnometry |
US10386325B2 (en) * | 2014-07-31 | 2019-08-20 | Life Safety Distribution Gmbh | Gas sensor with partitioned filter |
US10774431B2 (en) | 2014-10-21 | 2020-09-15 | Dioxide Materials, Inc. | Ion-conducting membranes |
US10975480B2 (en) | 2015-02-03 | 2021-04-13 | Dioxide Materials, Inc. | Electrocatalytic process for carbon dioxide conversion |
JP6734162B2 (ja) * | 2016-09-23 | 2020-08-05 | 新コスモス電機株式会社 | 定電位電解式ガスセンサおよび定電位電解式ガスセンサの製造方法 |
CN110947360A (zh) * | 2018-09-26 | 2020-04-03 | 中国石油天然气股份有限公司 | 一种pH响应超轻多孔碳材料及其制备方法与应用 |
US11536680B2 (en) | 2019-11-14 | 2022-12-27 | Analog Devices International Unlimited Company | Electrochemical sensor and method of forming thereof |
WO2022226245A1 (en) * | 2021-04-23 | 2022-10-27 | Ventiva, Inc. | Heat transfer using ionic pumps |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE548523A (es) * | 1955-06-11 | |||
US3227643A (en) * | 1962-11-13 | 1966-01-04 | Univ North Carolina | Oxygen detector |
US3380905A (en) * | 1963-10-11 | 1968-04-30 | Leland C. Clark Jr. | Electrolytic sensor with anodic depolarization |
US3795589A (en) * | 1970-11-30 | 1974-03-05 | H Dahms | Methods for electrochemical analysis |
US3719576A (en) * | 1971-01-29 | 1973-03-06 | Gen Electric | Electrode for measuring co2 tension in blood and other liquid and gaseous environments |
JPS5328496A (en) * | 1976-08-27 | 1978-03-16 | Mitsui Shipbuilding Eng | Gas analysis by electrolysis |
US4263115A (en) * | 1978-07-03 | 1981-04-21 | Max Planck Gesellschaft Zur Forderung Der Wissenschaften | Ion-selective electrode device for polarographic measurement of oxygen |
GB2052755B (en) * | 1979-05-18 | 1983-03-16 | Neotronics Ltd | Gas detecting and measuring apparatus |
US4474648A (en) * | 1980-04-30 | 1984-10-02 | City Technology Limited | Gas sensor |
GB2094005B (en) * | 1981-02-03 | 1985-05-30 | Coal Industry Patents Ltd | Electrochemical gas sensor |
JPS5879141A (ja) * | 1981-11-05 | 1983-05-12 | Hochiki Corp | 光学式ガス検知器 |
DD226655A1 (de) * | 1984-09-24 | 1985-08-28 | Univ Rostock | Verfahren zur bestimmung von schwefelwasserstoff |
-
1987
- 1987-05-28 GB GB878712582A patent/GB8712582D0/en active Pending
-
1988
- 1988-05-26 CA CA000567747A patent/CA1307320C/en not_active Expired - Fee Related
- 1988-05-27 ZA ZA883816A patent/ZA883816B/xx unknown
- 1988-05-27 DE DE88304839T patent/DE3883289T2/de not_active Expired - Lifetime
- 1988-05-27 ES ES88304839T patent/ES2045114T3/es not_active Expired - Lifetime
- 1988-05-27 US US07/199,426 patent/US5071526A/en not_active Expired - Lifetime
- 1988-05-27 EP EP88304839A patent/EP0293230B1/en not_active Expired - Lifetime
- 1988-05-27 JP JP63128546A patent/JP2648337B2/ja not_active Expired - Lifetime
- 1988-05-27 AU AU16711/88A patent/AU598932B2/en not_active Ceased
- 1988-05-27 AT AT88304839T patent/ATE93319T1/de not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
JPS63311162A (ja) | 1988-12-19 |
DE3883289D1 (de) | 1993-09-23 |
CA1307320C (en) | 1992-09-08 |
EP0293230B1 (en) | 1993-08-18 |
DE3883289T2 (de) | 1994-01-05 |
EP0293230A2 (en) | 1988-11-30 |
EP0293230A3 (en) | 1989-10-18 |
AU1671188A (en) | 1988-12-01 |
ZA883816B (en) | 1989-03-29 |
AU598932B2 (en) | 1990-07-05 |
GB8712582D0 (en) | 1987-07-01 |
JP2648337B2 (ja) | 1997-08-27 |
US5071526A (en) | 1991-12-10 |
ATE93319T1 (de) | 1993-09-15 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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