ES2045114T3 - Sensores de gas acido. - Google Patents
Sensores de gas acido.Info
- Publication number
- ES2045114T3 ES2045114T3 ES88304839T ES88304839T ES2045114T3 ES 2045114 T3 ES2045114 T3 ES 2045114T3 ES 88304839 T ES88304839 T ES 88304839T ES 88304839 T ES88304839 T ES 88304839T ES 2045114 T3 ES2045114 T3 ES 2045114T3
- Authority
- ES
- Spain
- Prior art keywords
- complex
- electrolyte
- acid gas
- gas sensors
- sensing electrode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002253 acid Substances 0.000 title 1
- 230000002378 acidificating effect Effects 0.000 abstract 3
- 239000003792 electrolyte Substances 0.000 abstract 3
- 239000007789 gas Substances 0.000 abstract 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 2
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 1
- 239000001569 carbon dioxide Substances 0.000 abstract 1
- FHONLRKRMAJPLG-UHFFFAOYSA-N copper propane-1,1-diamine Chemical compound C(CC)(N)N.C(CC)(N)N.[Cu+2] FHONLRKRMAJPLG-UHFFFAOYSA-N 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 239000012528 membrane Substances 0.000 abstract 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/403—Cells and electrode assemblies
- G01N27/404—Cells with anode, cathode and cell electrolyte on the same side of a permeable membrane which separates them from the sample fluid, e.g. Clark-type oxygen sensors
- G01N27/4045—Cells with anode, cathode and cell electrolyte on the same side of a permeable membrane which separates them from the sample fluid, e.g. Clark-type oxygen sensors for gases other than oxygen
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- General Physics & Mathematics (AREA)
- Electrochemistry (AREA)
- Physics & Mathematics (AREA)
- Analytical Chemistry (AREA)
- Molecular Biology (AREA)
- General Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
- Investigating Or Analyzing Materials By The Use Of Fluid Adsorption Or Reactions (AREA)
- Investigating Or Analysing Materials By The Use Of Chemical Reactions (AREA)
- Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)
- Measuring Oxygen Concentration In Cells (AREA)
Abstract
LA PRESENTE INVENCION PROPORCIONA UN SENSOR, PREFERIBLEMENTE UN SENSOR ELECTROQUIMICO, PARA DETECTAR GASES ACIDOS, POR EJEMPLO DIOXIDO DE CARBONO. EL SENSOR ELECTROQUIMICO TIENE UN ELECTRODO SENSIBLE (20, 22), UN ELECTRODO CONTADOR (37) Y UN ELECTROLITO QUE CONTIENE UN COMPLEJO, POR EJEMPLO, BIS(PROPANODIAMINA) DE COBRE(II), QUE TIENE UNO O MAS LIGANDOS DESPLAZABLES POR LA PRESENCIA DEL GAS ACIDO EN EL ELECTROLITO PARA FORMAR UN COMPLEJO MODIFICADO QUE PUEDE SER ELECTROQUIMICAMENTE REACTIVO EN EL ELCETRODO SENSOR A UN POTENCIAL AL QUE EL COMPLEJO NO MODIFICADO NO ES REACTIVO. EL GAS ACIDO DIFUNDE EN EL ELECTROLITO A TRAVES DE UNA MEMBRANA PORORSA. EL COMPLEJO MODIFICADO TAMBIEN SE PUEDE DETECTAR COLORIMETRICAMENTE DEBIDO A QUE ABSORBE LUZ A UNA LONGITUD DE ONDA DIFERENTE QUE EL COMPLEJO NO MODIFICADO.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB878712582A GB8712582D0 (en) | 1987-05-28 | 1987-05-28 | Acidic gas sensors |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2045114T3 true ES2045114T3 (es) | 1994-01-16 |
Family
ID=10618059
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES88304839T Expired - Lifetime ES2045114T3 (es) | 1987-05-28 | 1988-05-27 | Sensores de gas acido. |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US5071526A (es) |
| EP (1) | EP0293230B1 (es) |
| JP (1) | JP2648337B2 (es) |
| AT (1) | ATE93319T1 (es) |
| AU (1) | AU598932B2 (es) |
| CA (1) | CA1307320C (es) |
| DE (1) | DE3883289T2 (es) |
| ES (1) | ES2045114T3 (es) |
| GB (1) | GB8712582D0 (es) |
| ZA (1) | ZA883816B (es) |
Families Citing this family (69)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3923717A1 (de) * | 1989-07-18 | 1991-01-24 | Draegerwerk Ag | Elektrochemische messzelle zum nachweis von blausaeure oder schwefeldioxid |
| DE4133831A1 (de) * | 1991-09-14 | 1993-03-18 | Draegerwerk Ag | Elektrochemische messzelle zum nachweis und zur bestimmung von gasen und daempfen insbesondere von halogen-wasserstoffen |
| JPH06229980A (ja) * | 1993-02-04 | 1994-08-19 | Gastec:Kk | 定電位電解式ガスセンサ |
| US5338429A (en) * | 1993-03-05 | 1994-08-16 | Mine Safety Appliances Company | Electrochemical toxic gas sensor |
| US5419826A (en) * | 1994-03-25 | 1995-05-30 | The United States Of America As Represented By The Secretary Of The Navy | Ion-selective reference probe |
| US5879526A (en) * | 1994-11-08 | 1999-03-09 | Robert Bosch Gmbh | Electrochemical measuring sensor for determining nitrogen oxides in gas mixtures |
| AU5561796A (en) * | 1995-04-21 | 1996-11-07 | Mine Safety Appliances Company | Electrochemical gas sensor for the detection of nitrogen dio xide |
| GB2302731B (en) * | 1995-06-16 | 1997-11-12 | Sun Electric Uk Ltd | Method and apparatus for gas monitoring |
| JPH1071150A (ja) * | 1996-07-03 | 1998-03-17 | Nippon Koden Corp | 生体内ガスセンサ |
| US6013459A (en) * | 1997-06-12 | 2000-01-11 | Clinical Micro Sensors, Inc. | Detection of analytes using reorganization energy |
| CA2245050C (en) * | 1997-09-11 | 2000-09-05 | Kehoe Component Sales Inc. Dba Pace Electronic Products Inc. | Three-electrode electrochemical gas sensor |
| CA2215108C (en) * | 1997-09-11 | 1999-10-26 | Senco Sensors Inc. | Electrochemical gas sensor |
| US6858423B1 (en) | 1998-06-05 | 2005-02-22 | The Regents Of The University Of California | Optical Amplification of molecular interactions using liquid crystals |
| US6284197B1 (en) | 1998-06-05 | 2001-09-04 | The Regents Of The University Of California | Optical amplification of molecular interactions using liquid crystals |
| US6805788B1 (en) * | 1998-07-10 | 2004-10-19 | Lynntech, Inc. | Electrochemical impedance evaluation and inspection sensor |
| US7109853B1 (en) | 1999-04-26 | 2006-09-19 | Cherry Corporation | System for detecting and releasing a person locked in the trunk of a vehicle |
| US6623620B2 (en) | 1999-11-22 | 2003-09-23 | Hathaway Brown School | Method for detecting or monitoring sulfur dioxide with an electrochemical sensor |
| DE10009467A1 (de) * | 2000-02-28 | 2001-09-20 | Bcs Bio Und Chemosensoren Gmbh | Enzymatisch-elektrochemische Durchflußmeßeinrichtung (EED) |
| GB0214611D0 (en) * | 2002-06-25 | 2002-08-07 | Asthmo Alert | Electrochemical sensor for the analysis of carbon dioxide gas |
| US7220387B2 (en) * | 2002-07-23 | 2007-05-22 | Apieron Biosystems Corp. | Disposable sensor for use in measuring an analyte in a gaseous sample |
| US7889346B2 (en) * | 2003-12-31 | 2011-02-15 | University Of South Carolina | Thin-layer porous optical sensors for gases and other fluids |
| GB2417083B (en) * | 2004-08-13 | 2006-08-16 | Mark Sinclair Varney | An electrochemical carbon dioxide gas sensor |
| US20070201136A1 (en) | 2004-09-13 | 2007-08-30 | University Of South Carolina | Thin Film Interference Filter and Bootstrap Method for Interference Filter Thin Film Deposition Process Control |
| US20060118416A1 (en) * | 2004-12-08 | 2006-06-08 | Honeywell International, Inc. | Electrochemical sensor system |
| DE102004059280B4 (de) * | 2004-12-09 | 2007-08-16 | Dräger Safety AG & Co. KGaA | Elektrochemischer Gassensor |
| US20060278536A1 (en) * | 2005-06-10 | 2006-12-14 | The Regents Of The University Of California | Sensor comprising supported aprotic ionic liquid |
| US7664607B2 (en) | 2005-10-04 | 2010-02-16 | Teledyne Technologies Incorporated | Pre-calibrated gas sensor |
| WO2007111681A2 (en) * | 2005-10-31 | 2007-10-04 | Wisconsin Alumni Research Foundation | Device and methods for liquid crystal-based bioagent detection |
| US8154726B2 (en) | 2005-11-28 | 2012-04-10 | Halliburton Energy Services, Inc. | Optical analysis system and method for real time multivariate optical computing |
| US8208147B2 (en) * | 2005-11-28 | 2012-06-26 | Halliburton Energy Services, Inc. | Method of high-speed monitoring based on the use of multivariate optical elements |
| US8345234B2 (en) | 2005-11-28 | 2013-01-01 | Halliburton Energy Services, Inc. | Self calibration methods for optical analysis system |
| US20070166245A1 (en) * | 2005-11-28 | 2007-07-19 | Leonard Mackles | Propellant free foamable toothpaste composition |
| EP2033196A2 (en) | 2006-06-26 | 2009-03-11 | University of South Carolina | Data validation and classification in optical analysis systems |
| AU2007274795A1 (en) | 2006-07-21 | 2008-01-24 | Anaxsys Technology Limited | Gas sensor |
| GB2443023A (en) * | 2006-10-18 | 2008-04-23 | Anaxsys Technology Ltd | Determining the carbon dioxide content of an exhaled gas stream |
| US8449473B2 (en) | 2006-10-18 | 2013-05-28 | Anaxsys Technology Limited | Gas sensor |
| EP2078187A2 (en) | 2006-11-02 | 2009-07-15 | University of South Carolina | Multi-analyte optical computing system |
| US8184295B2 (en) | 2007-03-30 | 2012-05-22 | Halliburton Energy Services, Inc. | Tablet analysis and measurement system |
| WO2008121684A1 (en) * | 2007-03-30 | 2008-10-09 | University Of South Carolina | Novel multi-analyte optical computing system |
| WO2008121715A1 (en) | 2007-03-30 | 2008-10-09 | Ometric Corporation | In-line process measurement systems and methods |
| US7722816B2 (en) * | 2007-05-24 | 2010-05-25 | Wisconsin Alumni Research Foundation | Detection device and method |
| GB0714788D0 (en) * | 2007-07-30 | 2007-09-12 | Alphasense Ltd | Flue gas analyser |
| US8283633B2 (en) | 2007-11-30 | 2012-10-09 | Halliburton Energy Services, Inc. | Tuning D* with modified thermal detectors |
| US8212213B2 (en) | 2008-04-07 | 2012-07-03 | Halliburton Energy Services, Inc. | Chemically-selective detector and methods relating thereto |
| JP2011516190A (ja) | 2008-04-10 | 2011-05-26 | アナクシス・テクノロジー・リミテッド | ガスセンサー |
| WO2010024076A1 (ja) * | 2008-08-25 | 2010-03-04 | 理研計器株式会社 | 定電位電解式酸素センサ |
| WO2010093803A2 (en) * | 2009-02-12 | 2010-08-19 | Keimar, Inc. | Physiological parameter sensors |
| US10173169B2 (en) | 2010-03-26 | 2019-01-08 | Dioxide Materials, Inc | Devices for electrocatalytic conversion of carbon dioxide |
| US9193593B2 (en) | 2010-03-26 | 2015-11-24 | Dioxide Materials, Inc. | Hydrogenation of formic acid to formaldehyde |
| US9012345B2 (en) | 2010-03-26 | 2015-04-21 | Dioxide Materials, Inc. | Electrocatalysts for carbon dioxide conversion |
| US8956990B2 (en) | 2010-03-26 | 2015-02-17 | Dioxide Materials, Inc. | Catalyst mixtures |
| US20110237830A1 (en) * | 2010-03-26 | 2011-09-29 | Dioxide Materials Inc | Novel catalyst mixtures |
| US9957624B2 (en) | 2010-03-26 | 2018-05-01 | Dioxide Materials, Inc. | Electrochemical devices comprising novel catalyst mixtures |
| US9790161B2 (en) | 2010-03-26 | 2017-10-17 | Dioxide Materials, Inc | Process for the sustainable production of acrylic acid |
| US9815021B2 (en) | 2010-03-26 | 2017-11-14 | Dioxide Materials, Inc. | Electrocatalytic process for carbon dioxide conversion |
| US9566574B2 (en) | 2010-07-04 | 2017-02-14 | Dioxide Materials, Inc. | Catalyst mixtures |
| US20130015064A1 (en) * | 2011-06-29 | 2013-01-17 | Masel Richard I | Sensors For Carbon Dioxide And Other End Uses |
| CN104822861B (zh) | 2012-09-24 | 2017-03-08 | 二氧化碳材料公司 | 用于将二氧化碳转化为有用燃料和化学品的装置和方法 |
| US10647652B2 (en) | 2013-02-24 | 2020-05-12 | Dioxide Materials, Inc. | Process for the sustainable production of acrylic acid |
| WO2014143782A1 (en) * | 2013-03-15 | 2014-09-18 | The Cleveland Clinic Foundation | Miniaturized gas sensor device and method |
| EP3022548B1 (en) | 2013-07-16 | 2025-04-23 | Freespira, Inc. | Methods and systems for quantitative colorimetric capnometry |
| US10386325B2 (en) | 2014-07-31 | 2019-08-20 | Life Safety Distribution Gmbh | Gas sensor with partitioned filter |
| US10774431B2 (en) | 2014-10-21 | 2020-09-15 | Dioxide Materials, Inc. | Ion-conducting membranes |
| US10975480B2 (en) | 2015-02-03 | 2021-04-13 | Dioxide Materials, Inc. | Electrocatalytic process for carbon dioxide conversion |
| JP6734162B2 (ja) * | 2016-09-23 | 2020-08-05 | 新コスモス電機株式会社 | 定電位電解式ガスセンサおよび定電位電解式ガスセンサの製造方法 |
| CN110947360A (zh) * | 2018-09-26 | 2020-04-03 | 中国石油天然气股份有限公司 | 一种pH响应超轻多孔碳材料及其制备方法与应用 |
| GB2581779A (en) * | 2019-02-21 | 2020-09-02 | Sensocure As | Sensor |
| US11536680B2 (en) | 2019-11-14 | 2022-12-27 | Analog Devices International Unlimited Company | Electrochemical sensor and method of forming thereof |
| WO2022226245A1 (en) * | 2021-04-23 | 2022-10-27 | Ventiva, Inc. | Heat transfer using ionic pumps |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE548523A (es) * | 1955-06-11 | |||
| US3227643A (en) * | 1962-11-13 | 1966-01-04 | Univ North Carolina | Oxygen detector |
| US3380905A (en) * | 1963-10-11 | 1968-04-30 | Leland C. Clark Jr. | Electrolytic sensor with anodic depolarization |
| US3795589A (en) * | 1970-11-30 | 1974-03-05 | H Dahms | Methods for electrochemical analysis |
| US3719576A (en) * | 1971-01-29 | 1973-03-06 | Gen Electric | Electrode for measuring co2 tension in blood and other liquid and gaseous environments |
| JPS5328496A (en) * | 1976-08-27 | 1978-03-16 | Mitsui Shipbuilding Eng | Gas analysis by electrolysis |
| US4263115A (en) * | 1978-07-03 | 1981-04-21 | Max Planck Gesellschaft Zur Forderung Der Wissenschaften | Ion-selective electrode device for polarographic measurement of oxygen |
| GB2052755B (en) * | 1979-05-18 | 1983-03-16 | Neotronics Ltd | Gas detecting and measuring apparatus |
| US4474648A (en) * | 1980-04-30 | 1984-10-02 | City Technology Limited | Gas sensor |
| GB2094005B (en) * | 1981-02-03 | 1985-05-30 | Coal Industry Patents Ltd | Electrochemical gas sensor |
| DD226655A1 (de) * | 1984-09-24 | 1985-08-28 | Univ Rostock | Verfahren zur bestimmung von schwefelwasserstoff |
-
1987
- 1987-05-28 GB GB878712582A patent/GB8712582D0/en active Pending
-
1988
- 1988-05-26 CA CA000567747A patent/CA1307320C/en not_active Expired - Fee Related
- 1988-05-27 JP JP63128546A patent/JP2648337B2/ja not_active Expired - Lifetime
- 1988-05-27 AT AT88304839T patent/ATE93319T1/de not_active IP Right Cessation
- 1988-05-27 EP EP88304839A patent/EP0293230B1/en not_active Expired - Lifetime
- 1988-05-27 DE DE88304839T patent/DE3883289T2/de not_active Expired - Lifetime
- 1988-05-27 ZA ZA883816A patent/ZA883816B/xx unknown
- 1988-05-27 US US07/199,426 patent/US5071526A/en not_active Expired - Lifetime
- 1988-05-27 AU AU16711/88A patent/AU598932B2/en not_active Ceased
- 1988-05-27 ES ES88304839T patent/ES2045114T3/es not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JP2648337B2 (ja) | 1997-08-27 |
| DE3883289T2 (de) | 1994-01-05 |
| CA1307320C (en) | 1992-09-08 |
| US5071526A (en) | 1991-12-10 |
| AU1671188A (en) | 1988-12-01 |
| EP0293230B1 (en) | 1993-08-18 |
| AU598932B2 (en) | 1990-07-05 |
| EP0293230A3 (en) | 1989-10-18 |
| EP0293230A2 (en) | 1988-11-30 |
| DE3883289D1 (de) | 1993-09-23 |
| GB8712582D0 (en) | 1987-07-01 |
| ATE93319T1 (de) | 1993-09-15 |
| JPS63311162A (ja) | 1988-12-19 |
| ZA883816B (en) | 1989-03-29 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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