ES2016636B3 - Procedimiento de hidrogenacion asimetrica de compuestos carbonilados y compuestos obtenidos. - Google Patents

Procedimiento de hidrogenacion asimetrica de compuestos carbonilados y compuestos obtenidos.

Info

Publication number
ES2016636B3
ES2016636B3 ES87401404T ES87401404T ES2016636B3 ES 2016636 B3 ES2016636 B3 ES 2016636B3 ES 87401404 T ES87401404 T ES 87401404T ES 87401404 T ES87401404 T ES 87401404T ES 2016636 B3 ES2016636 B3 ES 2016636B3
Authority
ES
Spain
Prior art keywords
hydrocarbonated
pct
radicals
atoms
compounds
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES87401404T
Other languages
English (en)
Inventor
Andre Mortreux
Francis Petit
Abdallah Angle Yacoub El Mansour Karim
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Norsolor SA
Original Assignee
Norsolor SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Norsolor SA filed Critical Norsolor SA
Application granted granted Critical
Publication of ES2016636B3 publication Critical patent/ES2016636B3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C231/00—Preparation of carboxylic acid amides
    • C07C231/12—Preparation of carboxylic acid amides by reactions not involving the formation of carboxamide groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/189—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms containing both nitrogen and phosphorus as complexing atoms, including e.g. phosphino moieties, in one at least bidentate or bridging ligand
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B41/00—Formation or introduction of functional groups containing oxygen
    • C07B41/02—Formation or introduction of functional groups containing oxygen of hydroxy or O-metal groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B53/00—Asymmetric syntheses
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/26—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D307/30—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/32—Oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/26—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D307/30—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/32—Oxygen atoms
    • C07D307/33—Oxygen atoms in position 2, the oxygen atom being in its keto or unsubstituted enol form
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/643—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of R2C=O or R2C=NR (R= C, H)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
ES87401404T 1986-06-23 1987-06-22 Procedimiento de hidrogenacion asimetrica de compuestos carbonilados y compuestos obtenidos. Expired - Lifetime ES2016636B3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR8609024A FR2600330B1 (fr) 1986-06-23 1986-06-23 Procede d'hydrogenation asymetrique de composes carbonyles et composes obtenus

Publications (1)

Publication Number Publication Date
ES2016636B3 true ES2016636B3 (es) 1990-11-16

Family

ID=9336572

Family Applications (1)

Application Number Title Priority Date Filing Date
ES87401404T Expired - Lifetime ES2016636B3 (es) 1986-06-23 1987-06-22 Procedimiento de hidrogenacion asimetrica de compuestos carbonilados y compuestos obtenidos.

Country Status (10)

Country Link
US (1) US5128488A (es)
EP (1) EP0253700B1 (es)
JP (1) JPH0667856B2 (es)
AT (1) ATE55975T1 (es)
CA (1) CA1298846C (es)
DE (1) DE3764566D1 (es)
ES (1) ES2016636B3 (es)
FR (1) FR2600330B1 (es)
GR (1) GR3000839T3 (es)
WO (1) WO1987007889A1 (es)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2658515A1 (fr) * 1990-02-19 1991-08-23 Norsolor Sa Nouveaux aminophosphine-phosphinites, leur procede de fabrication et leur application a des reactions enantioselectives.
US5475151A (en) * 1994-11-28 1995-12-12 Liang; Shaowo Process for the preparatoin of cyclopropylmethanol
FR2753193B1 (fr) * 1996-09-11 1998-12-04 Sanofi Sa Procede de preparation de benzylalcools alpha-substitues optiquement actifs
EP2668177B1 (en) 2011-01-28 2014-10-22 Boehringer Ingelheim International GmbH Substituted pyridinyl-pyrimidines and their use as medicaments

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3968147A (en) * 1972-02-09 1976-07-06 Monsanto Company Asymmetric reduction of ketones to form optically active alcohols
US4539411A (en) * 1982-02-05 1985-09-03 Hoffmann-La Roche Inc. Rhodium complexes of chiral phosphines
DK350383A (da) * 1982-08-27 1984-02-28 Hoffmann La Roche Phosphorforbindelser
FR2550201B1 (fr) * 1983-08-05 1986-02-28 Charbonnages Ste Chimique Ligands phosphores chiraux, leur procede de fabrication a partir d'aminoacides naturels et leur application a la catalyse de reactions de synthese enantioselective

Also Published As

Publication number Publication date
DE3764566D1 (de) 1990-10-04
GR3000839T3 (en) 1991-11-15
EP0253700B1 (fr) 1990-08-29
WO1987007889A1 (fr) 1987-12-30
EP0253700A1 (fr) 1988-01-20
FR2600330A1 (fr) 1987-12-24
US5128488A (en) 1992-07-07
FR2600330B1 (fr) 1988-12-16
JPS63503543A (ja) 1988-12-22
CA1298846C (fr) 1992-04-14
JPH0667856B2 (ja) 1994-08-31
ATE55975T1 (de) 1990-09-15

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